Guanidinium-based ionic liquids in absorption chillers
US-2017343251-A1 · Nov 30, 2017 · US
US10465950B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10465950-B2 |
| Application number | US-201715607240-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 26, 2017 |
| Priority date | May 26, 2016 |
| Publication date | Nov 5, 2019 |
| Grant date | Nov 5, 2019 |
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This invention relates to using a guanidinium-based ionic liquid as an absorbent material in an absorption chiller. The invention provides an absorption chiller comprising a mixture of a refrigerant and an absorbent, and the absorbent is a guanidinium-based ionic liquid. A preferred refrigerant is water. This invention also provides a method for synthesizing N,N,N′,N′,N″,N″-hexamethylguanidinium acetate.
Opening claim text (preview).
What is claimed is: 1. An absorption chiller comprising an absorber compartment and a generator compartment, wherein both compartments comprise a mixture of a refrigerant and an absorbent, and the absorbent is a guanidinium-based ionic liquid, wherein the ionic liquid has an acetate anion. 2. The absorption chiller of claim 1 , wherein the refrigerant is water. 3. The absorption chiller of claim 1 , wherein the ionic liquid has a melting point of 400K or less. 4. The absorption chiller of claim 1 , wherein the ionic liquid has a kinematic viscosity lower than 25 centistokes. 5. An absorption chiller comprising an absorber compartment and a generator compartment, wherein both compartments comprise a mixture of a refrigerant and an absorbent, and the absorbent is a guanidinium-based ionic liquid, wherein the ionic liquid has a hexamethylguanidinium cation. 6. The absorption chiller of claim 5 , wherein the ionic liquid is hexamethylguanidinium acetate. 7. An absorption chiller comprising an absorber compartment and a generator compartment, wherein both compartments comprise a mixture of a refrigerant and an absorbent, and the absorbent is a guanidinium-based ionic liquid, wherein the ionic liquid has a hexaethylguanidinium cation. 8. The absorption chiller of claim 7 , wherein the ionic liquid is hexaethylguanidinium acetate. 9. The absorption chiller of claim 5 , wherein the refrigerant is water. 10. The absorption chiller of claim 5 , wherein the ionic liquid has a melting point of 400K or less. 11. The absorption chiller of claim 5 , wherein the ionic liquid has a kinematic viscosity lower than 25 centistokes. 12. The absorption chiller of claim 7 , wherein the refrigerant is water. 13. The absorption chiller of claim 7 , wherein the ionic liquid has a melting point of 400K or less. 14. The absorption chiller of claim 7 , wherein the ionic liquid has a kinematic viscosity lower than 25 centistokes.
the refrigerant being water vapour evaporated from a salt solution, e.g. lithium bromide {(F25B15/025 takes precedence)} · CPC title
of substituted guanidines · CPC title
using the endothermic solution of salt · CPC title
Guanidine; Salts, complexes or addition compounds thereof · CPC title
Absorption based systems · CPC title
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