Polyphenyl ether resin composition and prepreg, laminated board and printed circuit board containing same

Patent metadata

Field	Value
Publication number	US-10465069-B2
Application number	US-201615744579-A
Country	US
Kind code	B2
Filing date	Apr 8, 2016
Priority date	Oct 22, 2015
Publication date	Nov 5, 2019
Grant date	Nov 5, 2019

Abstract

Provided are a polyphenyl ether resin composition and a prepreg and a laminated board containing same. The polyphenyl ether resin composition comprises the following components: (1) a tetrafunctional or higher multifunctional acrylate-modified thermosetting polyphenyl ether resin; and (2) a vinyl resin cross-linking agent, the weight of the vinyl resin cross-linking agent being 40-100 parts by weight based on 100 parts by weight of the tetrafunctional or higher multifunctional acrylate-modified thermosetting polyphenyl ether resin. The modified thermosetting polyphenyl ether resin, due to containing a tetrafunctional or higher multifunctional acrylate active group, can cross-link more vinyl resin cross-linking agents. Not only the prepared high-speed electronic circuit substrate has low dielectric constant and dielectric loss, but also double bonds in side chains of the vinyl resin cross-linking agent are reacted completely in a resin curing system, so that the high-speed electronic circuit substrate has a better thermo-oxidative aging resistance.

First claim

The invention claimed is:

1. A polyphenyl ether resin composition, it comprises the following components:
(1) a tetrafunctional or higher multifunctional acrylate group-modified thermosetting polyphenyl ether resin; and
(2) a vinyl resin crosslinking agent, the weight of which is 40 to 100 parts by weight, based on 100 parts by weight of the tetrafunctional or higher multifunctional acrylate group-modified thermosetting polyphenyl ether resin;
wherein the tetrafunctional or higher multifunctional acrylate group-modified thermosetting polyphenyl ether resin has a structure shown by formula (1):

in formula (1), R 1 , R 2 , R 3 and R 4 are the same or different and are each independently a hydrogen atom, a halogen atom, a substituted or unsubstituted C1-C8 alkyl group or a substituted or unsubstituted aryl group;
a and c are each independently an integer from 1 to 15 and b is an integer from 2 to 10;
Z has a structure shown by formula (2):

in formula (2), R 5 , R 6 , and R 7 are the same or different and are each independently a hydrogen atom or a substituted or unsubstituted C1-C10 alkyl group;
X has a structure shown by formula (3), formula (4), formula (5), or formula (6):

R 8 , R 9 , R 10 , R 11 , R 12 , R 13 , R 14 , R 15 , R 16 , R 17 , R 18 , R 19 , R 20 , R 21 , R 22 , R 23 , R 24 , R 25 , R 26 and R 27 are the same or different and are each independently a hydrogen atom, a halogen atom, a substituted or unsubstituted C1-C8 alkyl group or a substituted or unsubstituted aryl group; and n is an integer from 1 to 10;
B is an alkylene group, —O—, —CO—, —SO—, —SC—, —SO 2 — or —C(CH 3 ) 2 —;
Y has a structure shown by formula (7) or formula (8):

R 28 , R 29 , R 30 , R 31 , R 32 , R 33 and R 34 are the same or different and are each independently a hydrogen atom, a halogen atom, a substituted or unsubstituted C1-C8 alkyl group or a substituted or unsubstituted aryl group.

2. The polyphenyl ether resin composition according to claim 1 , wherein b is an integer from 4 to 6.

3. The polyphenyl ether resin composition according to claim 1 , wherein the weight of the vinyl resin crosslinking agent is 50 to 80 parts by weight, based on 100 parts by weight of the tetrafunctional or higher multifunctional acrylate group-modified thermosetting polyphenyl ether resin.

4. The polyphenyl ether resin composition according to claim 1 , wherein the number average molecular weight of the tetrafunctional or higher multifunctional acrylate group-modified thermosetting polyphenyl ether resin is 500 to 10000 g/mol.

5. The polyphenyl ether resin composition according to claim 4 , the vinyl resin crosslinking agent is at least one member selected from a group consisting of a styrene-butadiene copolymer, a polybutadiene and a styrene-butadiene-divinylbenzene copolymer.

6. The polyphenyl ether resin composition according to claim 5 , the styrene-butadiene copolymer, the polybutadiene or the styrene-butadiene-divinylbenzene copolymer are independently amino-modified, maleic anhydride-modified, epoxy-modified, acrylate-modified, hydroxyl-modified or carboxyl-modified.

7. The polyphenyl ether resin composition according to claim 1 , wherein the polyphenyl ether resin composition further comprises an initiator, and the initiator is a radical initiator.

8. The polyphenyl ether resin composition according to claim 7 , the radical initiator is an organic peroxide initiator.

9. The polyphenyl ether resin composition according to claim 8 , the radical initiator is at least one member selected from a group consisting of dilauroyl peroxide, dibenzoyl peroxide, cumyl peroxyneodecanoate, t-butyl peroxyneodecanoate, t-amyl peroxypivalate, t-butyl peroxypivalate, t-butyl peroxyisobutyrate, t-butyl peroxy-3,5,5-trimethylhexanoate, t-butyl peroxyacetate, t-butyl peroxybenzoate, 1,1-di-t-butylperoxy-3,5,5-trimethylcyclohexane, 1,1-di-t-butylperoxycyclohexane, 2,2-bis (t-butylperoxy)butane, bis(4-tert-butylcyclohexyl) peroxydicarbonate, hexadecyl peroxodicarbonate, tetradecyl peroxydicarbonate, di-t-amyl peroxide, dicumyl peroxide, bis(t-butylperoxyisopropyl)benzene, 2,5-dimethyl-2,5-di-t-butylperoxyhexane, 2,5-dimethyl-2,5-di-t-butylperoxyhexyne, dicumyl hydroperoxide, cumyl hydroperoxide, t-amyl hydroperoxide, t-butyl hydroperoxide, t-butyl cumyl peroxide, dicumyl hydroperoxide, t-butyl peroxycarbonate 2-ethylhexanoate, 2-ethylhexyl-t-butylperoxycarbonate, n-butyl 4,4-di(t-butylperoxy)pentanoate, methyl ethyl ketone peroxide and cyclohexane peroxide.

10. The polyphenyl ether resin composition according to claim 7 , the weight of the initiator is 1 to 3 parts by weight, based on 100 parts by weight of a sum of the weight of the tetrafunctional or higher multifunctional acrylate group-modified thermosetting polyphenyl ether resin and the vinyl resin crosslinking agent.

11. The polyphenyl ether resin composition according to claim 1 , wherein the polyphenyl ether resin composition further comprises a flame retardant.

12. The polyphenyl ether resin composition according to claim 11 , the flame retardant comprises at least one member selected from the group consisting of a bromine-containing flame retardant and a phosphorus-containing flame retardant.

13. The polyphenyl ether resin composition according to claim 11 , the weight of the flame retardant is 0 to 40 parts by weight, based on 100 parts by weight of a sum of the weight of the tetrafunctional or higher multifunctional acrylate group-modified thermosetting polyphenyl ether resin, the vinyl resin crosslinking agent and the initiator.

14. The polyphenyl ether resin composition according to claim 11 , the polyphenyl ether resin composition further comprises a powder filler.

15. The polyphenyl ether resin composition according to claim 14 , the powder filler comprises at least one member selected from the group consisting of an organic filler and an inorganic filler.

16. The polyphenyl ether resin composition according to claim 15 , wherein the inorganic filler is at least one member selected from a group consisting of crystalline silica, fused silica, spherical silica, hollow silica, glass frit, aluminum nitride, boron nitride, silicon carbide, aluminum silicon carbide, aluminum hydroxide, magnesium hydroxide, titanium dioxide, strontium titanate, barium titanate, zinc oxide, zirconium oxide, aluminum oxide, beryllium oxide, magnesium oxide, barium sulfate, talcum powder, clay, calcium silicate, calcium carbonate and mica.

17. The polyphenyl ether resin composition according to claim 15 , the organic filler is at least one member selected from a group consisting of polytetrafluoroethylene powder, polyphenylene sulfide, polyetherimide, polyphenyl ether and polyether sulfone powder.

18. The polyphenyl ether resin composition according to claim 14 , the weight of the powder filler is 0 to 150 parts by weight, based on 100 parts by weight of a sum of the weight of the tetrafunctional or higher multifunctional acrylate group-modified thermosetting polyphenyl ether resin, the vinyl resin crosslinking agent, the initiator and the flame retardant.

19. A pr

Assignees

• Shengyi Technology Co Ltd

Inventors

• Chen Guangbing
• Zeng Xianping

Classifications

• B32B2264/0257

  Polyolefin particles, e.g. polyethylene or polypropylene homopolymers or ethylene-propylene copolymers · CPC title

• B32B2307/204

  Di-electric · CPC title

• B32B2262/101

  Glass fibres · CPC title

• B32B2260/046

  Synthetic resin · CPC title

• B32B2260/021

  Fibrous or filamentary layer · CPC title