Process for the manufacture of thermoplastic polymer particles with improved process yield

Patent metadata

Field	Value
Publication number	US-10465049-B2
Application number	US-201615757160-A
Country	US
Kind code	B2
Filing date	Sep 2, 2016
Priority date	Sep 4, 2015
Publication date	Nov 5, 2019
Grant date	Nov 5, 2019

Abstract

A process for the manufacture of thermoplastic polymer particles, including combining a first solution including a thermoplastic polymer and an organic solvent with a second solution including an aqueous solvent and a surfactant to provide an emulsion. The emulsion is transferred into a receiving water to remove the organic solvent and form an aqueous dispersion including a plurality of thermoplastic polymer particles dispersed in the aqueous solvent. The thermoplastic polymer particles having a D50 of 20 to 100 μm are recovered in a yield of greater than 85%. Thermoplastic polymer particles prepared according to the method are also disclosed.

First claim

What is claimed is:

1. A process for the manufacture of thermoplastic polymer particles, the process comprising
combining a first solution comprising a thermoplastic polymer and an organic solvent with a second solution comprising an aqueous solvent and a surfactant comprising gelatin to provide an emulsion;
transferring the emulsion into a receiving water at a temperature of greater than or equal to 50° C. to remove the organic solvent and form an aqueous dispersion comprising a plurality of thermoplastic polymer particles dispersed in the aqueous solvent; and
recovering thermoplastic polymer particles having a D50 of 20 to 100 μm;
wherein the particles having a diameter less than 150 micrometers are recovered in a yield greater than 85%.

2. The process of claim 1 , wherein the combining comprises agitating the first and second solutions at a speed of greater than 3,000 rotations per minute.

3. The process of claim 1 , wherein
the emulsion comprises the thermoplastic polymer in an amount of 10 to 30 weight percent, based on the total weight of thermoplastic polymer and organic solvent;
the emulsion comprises water in a water-to-organic solvent weight ratio of greater than or equal to 0.4;
the emulsion comprises the surfactant in a surfactant-to-thermoplastic polymer weight ratio of greater than or equal to 0.005.

4. The process of claim 1 , wherein the transferring comprises adding the emulsion dropwise to the receiving water or spraying the emulsion into the receiving water.

5. The process of claim 1 , wherein the recovering comprises filtering the aqueous dispersion to form a wet cake.

6. The process of claim 5 , further comprising washing the wet cake with water.

7. The process of claim 5 , further comprising drying the wet cake.

8. The process of claim 1 , further comprising mixing the thermoplastic polymer particles with a flow promoter in an amount of 0.001 to 1 weight percent, based on the weight of the thermoplastic polymer particles, to provide particles having a flowability of greater than or equal to 4.

9. The process of claim 8 , wherein the flow promoter comprises an unmodified fumed metal oxide, a hydrophobic fumed metal oxide, a hydrophilic fumed metal oxide, hydrated silica, amorphous alumina, glassy silica, glassy phosphate, glassy borate, glassy oxide, titania, talc, mica, kaolin, attapulgite, calcium silicate, magnesium silicate, or a combination comprising at least one of the foregoing.

10. The process of claim 1 , wherein the particles have one or both of the following properties:
a particle size distribution span of less than 2; and
a bulk density of greater than 0.5 grams per cubic centimeter.

11. The process of claim 1 , wherein the thermoplastic polymer is a polyarylate, a polycarbonate, a polyetherimide, a polyimide, a polysulfone, a polyethersulfone, a polyphenylene sulfone, a polyarylene ether, a polyestercarbonate, or a combination comprising at least one of the foregoing.

12. The process of claim 1 , wherein the organic solvent has a boiling point that is less than 100° C., and is immiscible with water.

13. The process of claim 1 , wherein
the first solution further comprises an additive comprising a particulate filler, antioxidant, heat stabilizer, light stabilizer, ultraviolet light stabilizer, UV absorbing additive, NIR absorbing additive, IR absorbing additive, plasticizer, lubricant, release agent, antistatic agent, anti-fog agent, antimicrobial agent, colorant, laser marking additive, surface effect additive, radiation stabilizer, flame retardant, anti-drip agent, a fragrance, a fiber, or a combination comprising at least one of the foregoing; and
the recovered particles comprise the additive.

14. The process of claim 1 comprising
combining a first solution comprising a polycarbonate and an organic solvent with a second solution comprising an aqueous solvent and a surfactant comprising gelatin to provide an emulsion, wherein the emulsion comprises
water in a water-to-organic solvent weight ratio of 0.5 to 1,
the thermoplastic polymer in an amount of 15 to 25 weight percent, based on the total weight of polycarbonate and organic solvent, and
the surfactant in a surfactant-to-polycarbonate weight ratio of 0.01 to 0.04;

transferring the emulsion into a receiving water at a temperature of 50 to 100° C. to remove the organic solvent and form an aqueous dispersion comprising a plurality of polycarbonate particles dispersed in water; and
recovering polycarbonate particles having a diameter less than 150 micrometers and having a D50 of 20 to 80 μm, in a yield greater than or equal to 90%.

15. The process of claim 1 comprising
combining a first solution comprising a polyetherimide and an organic solvent with a second solution comprising an aqueous solvent and a surfactant comprising gelatin to provide an emulsion, wherein the emulsion comprises
water in a water-to-organic solvent weight ratio of 0.5 to 1,
the thermoplastic polymer in an amount of 15 to 25 weight percent, based on the total weight of polyetherimide and organic solvent, and
the surfactant in a surfactant-to-polyetherimide weight ratio of 0.01 to 0.04; and

transferring the emulsion into a receiving water at a temperature of 50 to 100° C. to remove the organic solvent and form an aqueous dispersion comprising a plurality of polyetherimide particles dispersed in water; and
recovering polyetherimide particles having a diameter less than 150 micrometers and having a D50 of 20 to 80 μm, in a yield greater than or equal to 90%.

Assignees

• Sabic Global Technologies Bv

Inventors

• Kalyanaraman Viswanathan

Classifications

• C08J3/14 Primary

  by precipitation from solutions {(C08J3/122 takes precedence)} · CPC title

• C08J2369/00

  Characterised by the use of polycarbonates; Derivatives of polycarbonates · CPC title

• C08J3/124

  Treatment for improving the free-flowing characteristics · CPC title

• C08J2379/08

  Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors · CPC title