Polymerizable composition, transparent resin, optical material, plastic lens, and method for manufacturing transparent resin

Patent metadata

Field	Value
Publication number	US-10465036-B2
Application number	US-201515515167-A
Country	US
Kind code	B2
Filing date	Sep 9, 2015
Priority date	Sep 30, 2014
Publication date	Nov 5, 2019
Grant date	Nov 5, 2019

Abstract

A polymerizable composition which can suppress generation of turbidity, optical distortion, and striae in a transparent resin obtained therefrom, a transparent resin obtained from the polymerizable composition, an optical material containing the transparent resin, a plastic lens containing the optical material, and a method for manufacturing the transparent resin. The present disclosure is a polymerizable composition containing a polythiol compound having at least three mercapto groups and a polyiso(thio)cyanate compound. The polyiso(thio)cyanate compound contains only a polyiso(thio)cyanate compound having no aromatic ring, and a thiol equivalent ratio which is a measured value of a thiol equivalent of the polythiol compound with respect to a theoretical value of the thiol equivalent is 0.900 or more and less than 1.000.

First claim

The invention claimed is:

1. A polymerizable composition comprising a polythiol compound having at least three mercapto groups and a polyiso(thio)cyanate compound, wherein
the polyiso(thio)cyanate compound contains only a polyiso(thio)cyanate compound having no aromatic ring, and
a thiol equivalent ratio which is a measured value of a thiol equivalent of the polythiol compound with respect to a theoretical value of the thiol equivalent is 0.940 or more and less than 0.977.

2. The polymerizable composition according to claim 1 , wherein the polythiol compound having at least three mercapto groups is an ester compound of a polyol compound and at least one selected from a group consisting of thioglycolic acid, mercaptopropionic acid, thiolactic acid, and thiosalicylic acid.

3. The polymerizable composition according to claim 2 , wherein the polyol compound is at least one selected from a group consisting of pentaerythritol, glycerin, and trimethylol propane.

4. The polymerizable composition according to claim 1 , wherein the polyiso(thio)cyanate compound is at least one selected from a group consisting of hexamethylene diisocyanate, trimethylhexamethylene diisocyanate, isophorone diisocyanate, norbornene methane diisocyanate, bis(isocyanatemethyl) cyclohexane, bis(isocyanatemethyl) bicycloheptane, dicyclohexylmethane diisocyanate, and cyclohexane diisocyanate.

5. A transparent resin obtained by polymerizing the polymerizable composition according to claim 1 .

6. The transparent resin according to claim 5 , wherein a ratio of the total number of urethane bonds with respect to the total number of thiourethane bonds contained in the transparent resin is 0.111 or less.

7. An optical material comprising the transparent resin according to claim 5 .

8. A plastic lens comprising the optical material according to claim 7 .

9. A method for manufacturing a transparent resin, comprising a step of subjecting the polymerizable composition according to claim 1 to casting polymerization.

Assignees

• Hoya Lens Thailand Ltd

Inventors

• Iijima Takayuki
• Kousaka Masahisa

Classifications

• C08G18/753

  containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group · CPC title

• C08G18/722

  Combination of two or more aliphatic and/or cycloaliphatic polyisocyanates · CPC title

• C08G18/758

  containing two or more cycloaliphatic rings · CPC title

• C08G18/246 Primary

  containing also tin-carbon bonds · CPC title

• C08G18/755

  and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate · CPC title