Aerogel blanket for ultra-high temperature, production method thereof, and construction method thereof

Patent metadata

Field	Value
Publication number	US-10464816-B2
Application number	US-201715766318-A
Country	US
Kind code	B2
Filing date	Oct 10, 2017
Priority date	Oct 12, 2016
Publication date	Nov 5, 2019
Grant date	Nov 5, 2019

Abstract

The present invention relates to a hydrophilic silica aerogel blanket for ultra-high temperature insulation, a production method thereof, and a construction method thereof. More specifically, the present invention provides a production method a hydrophilic silica aerogel blanket, the method capable of strengthening the structure of a silica gel by adding a basic catalyst in an aging step, reducing processing time and cost by omitting a surface modification step, thereby reducing manufacturing cost, and suppressing the generation of a bad odor during construction by fundamentally blocking a volatile organic compound (VOC), a hydrophilic silica aerogel blanket produced thereby, and a construction method of a hydrophilic silica aerogel blanket, the method capable of suppressing the generation of a bad odor when constructing the hydrophilic aerogel blanket on an ultra-high temperature piping equipment, and at the same time, preventing the loss of heat insulation performance due to moisture in the air.

First claim

The invention claimed is:

1. A method for producing a hydrophilic aerogel blanket, comprising:
1) preparing a silica sol by mixing a silica precursor, alcohol, and an acidic aqueous solution;
2) adding a basic catalyst to the silica sol, and then depositing the silica sol containing the basic catalyst in a base material for a blanket;
3) subjecting the silica sol to a gelation reaction while being in a state of being deposited in the base material for the blanket to form a silica gel;
4) adding a mixed solution of a basic catalyst and an alcohol to the silica gel produced upon completion of the gelation reaction and aging the silica gel added with the mixed solution, wherein the basic catalyst of Step 4) comprises ammonium hydroxide or potassium hydroxide, wherein the ammonium hydroxide is added in an amount of 10 to 20 vol % based on the alcohol, or the potassium hydroxide is added in an amount of 0.05 to 0.15 g/L based on the alcohol; and
5) drying the aged silica gel.

2. The method of claim 1 , wherein the basic catalyst of Step 2) comprises one or more selected from the group consisting of sodium hydroxide (NaOH), potassium hydroxide (KOH), calcium hydroxide (Ca(OH) 2 ), ammonium hydroxide (NH 4 OH), tetramethylammonium hydroxide (TMAH), tetraethylammonium hydroxide (TEAH), tetrapropylammonium hydroxide (TPAH), tetrabutylammonium hydroxide (TBAH), methylamine, ethylamine, isopropylamine, monoisopropylamine, diethylamine, diisopropylamine, dibutylamine, trimethylamine, triethylamine, triisopropylamine, tributylamine, choline, monoethanolamine, diethanolamine, 2-aminoethanol, 2-(ethylamino) ethanol, 2-(methylamino) ethanol, N-methyldiethanolamine, dimethylaminoethanol, diethylaminoethanol, nitrilotriethanol, 2-(2-aminoethoxy) ethanol, 1-amino-2-propanol, triethanolamine, monopropanolamine, dibutanolamine and pyridine.

3. The method of claim 1 , wherein the aging of Step 4) is performed at a temperature of 30 to 70° C.

4. The method of claim 1 , wherein a surface modification step is not performed in the production method of a hydrophilic aerogel blanket.

5. The method of claim 1 , wherein the base material for the blanket comprises one or more materials selected from a film, a sheet, a net, a fiber, a porous body, a foam, and a non-woven body.

6. The method of claim 1 , wherein the drying is performed by a supercritical drying process, or an ambient drying process.

7. The method of claim 1 , wherein the hydrophilic aerogel blanket is for ultra-high temperature heat insulation of 500° C. or higher.

8. A hydrophilic silica aerogel blanket produced by the method of claim 1 .

9. A construction method of an aerogel blanket, the method comprising:
1) constructing at least one layer of the hydrophilic aerogel blanket of claim 8 on the surface of a piping equipment; and
2) constructing at least one layer of a hydrophobic aerogel blanket on the hydrophilic aerogel blanket.

10. The method of claim 9 , wherein the piping equipment is a piping equipment for ultra-temperature of 500° C. or higher.

Assignees

• Lg Chemical Ltd

Inventors

• Oh Kyoung Shil
• Lee Je Kyun

Classifications

• F16L59/02

  Shape or form of insulating materials, with or without coverings integral with the insulating materials · CPC title

• C01B33/154

  by acidic treatment of aqueous silicate solutions · CPC title

• C01B33/143

  of aqueous solutions of silicates · CPC title

• C01B33/158

  Purification; Drying; Dehydrating · CPC title

• C01B33/1585 Primary

  Dehydration into aerogels · CPC title