Conductive material and manufacturing method and purification method for same, and non aqueous electrolyte solution and antistatic agent using said conductive material

Patent metadata

Field	Value
Publication number	US-10461365-B2
Application number	US-201615565759-A
Country	US
Kind code	B2
Filing date	Jun 22, 2016
Priority date	Jun 23, 2015
Publication date	Oct 29, 2019
Grant date	Oct 29, 2019

Abstract

The objective of the present invention is to provide a clear conductive material with less turbidity, methods for producing and purifying the conductive material, and a nonaqueous electrolyte solution and an antistatic agent which contain the conductive material. The conductive material of the present invention comprises a fluorosulfonylimide salt represented by the following formula (1):

wherein X is F of a C 1-6 fluoroalkyl group,

and at least one organic solvent selected from the group consisting of a carbonate solvent, an ester solvent, a ketone solvent and an alcohol solvent, wherein a concentration of the fluorosulfonylimide salt is 0.1 mol/L or more, and a turbidity is 50 NTU/mol-LiFSI or less; and the production method of the present invention comprises the step of filtering a solution comprising the fluorosulfonylimide salt and the organic solvent by using a filter medium comprising the specific material.

First claim

The invention claimed is:

1. A method for producing a conductive material, wherein the conductive material comprises a fluorosulfonylimide salt represented by
the following formula (1)

wherein X is F or a C 1 -C 6 fluoroalkyl group, and at least one organic solvent selected from the group consisting of a carbonate solvent, an ester solvent, a ketone solvent and an alcohol solvent, and
wherein the conductive material has an ion conductivity, comprising the step of filtering a solution comprising the fluorosulfonylimide salt by using a filter medium comprising at least one material selected from the group consisting of a cellulose resin, a polyester resin, a silicon dioxide material and activated carbon,
wherein the conductive material is characterized in that it is filtered using a filter medium having a retained particle diameter of 0.05 μm or more or 200 μm or less and, after filtration, the turbidity is 50 NFU/mol-LiFSI or less when measured at 25° C. by a scattering light measuring method using a formazan standard solution.

2. A method for purifying a conductive material, wherein the conductive material comprises a fluorosulfonylimide salt represented by
the following formula (1)

wherein X is F or a C 1 -C 6 fluoroalkyl group, and at least one organic solvent selected from the group consisting of a carbonate solvent, an ester solvent, a ketone solvent and an alcohol solvent, and
wherein the conductive material has an ion conductivity, comprising the step of filtering a solution comprising the fluorosulfonylimide salt by using a filter medium comprising at least one material selected from the group consisting of a cellulose resin, a polyester resin, a silicon dioxide material and activated carbon,
wherein the conductive material is characterized in that it is filtered using a filter medium having a retained particle diameter of 0.05 μm or more or 200 μm or less and, after filtration, the turbidity is 50 NTU/mol-LiFSI or less when measured at 25° C. by a scattering light measuring method using a formazin standard solution.

3. The method according to claim 1 , wherein the conductive material is a nonaqueous electrolyte solution.

4. The method according to claim 2 , wherein the conductive material is a nonaqueous electrolyte solution.

5. The method according to claim 1 , wherein the ion conductivity of the conductive material at 25° C. is 1×10 −6 S/cm or more.

6. The method according to claim 2 , wherein the ion conductivity of the conductive material at 25° C. is 1×10 −6 S/cm or more.

7. The method according to claim 2 , wherein a concentration of the fluorosulfonylimide salt in the conductive material is 0.1 mol/L or more.

8. The method according to claim 2 , wherein a concentration of the fluorosulfonylimide salt in the conductive material is 0.1 mol/L or more.

9. The method according to claim 1 , wherein the X is F.

10. The method according to claim 2 , wherein the X is F.

11. A conductive material comprising:
a fluorosulfonylimide salt represented by the following formula (1):

wherein X is F or a C 1-6 fluoroalkyl group,
and at least one organic solvent selected from the group consisting of a carbonate solvent, an ester solvent, a ketone solvent and an alcohol solvent,
wherein the conductive material has an ion conductivity, and
wherein the conductive material is obtained by the method according to claim 1 .

12. A conductive material comprising:
a fluorosulfonylimide salt represented by the following formula (1):

wherein X is F or a C 1-6 fluoroalkyl group,
and at least one organic solvent selected from the group consisting of a carbonate solvent, an ester solvent, a ketone solvent and an alcohol solvent,
wherein the conductive material has an ion conductivity, and
wherein the conductive material is obtained by the method according to claim 2 .

13. The method according to claim 1 , wherein the filter medium comprises at least one material selected from the group consisting of a cellulose resin, a polyester resin and activated carbon.

14. The method according to claim 2 , wherein the filter medium comprises at least one material selected from the group consisting of a cellulose resin, a polyester resin and activated carbon.

15. The conductive material according to claim 11 , wherein the filter medium comprises at least one material selected from the group consisting of a cellulose resin, a polyester resin and activated carbon.

16. The conductive material according to claim 12 , wherein the filter medium comprises at least one material selected from the group consisting of a cellulose resin, a polyester resin and activated carbon.

Assignees

• Nippon Catalytic Chem Ind

Inventors

• Katsuyama Hiromoto

Classifications

• H01M6/164

  by the solvent · CPC title

• H01G11/60

  characterised by the solvent · CPC title

• H01M10/0568 Primary

  characterised by the solutes · CPC title

• C01B21/086

  containing one or more sulfur atoms · CPC title

• H01G11/62

  characterised by the solute, e.g. salts, anions or cations therein · CPC title