Cathode active material used for lithium ion secondary battery and lithium ion secondary battery using same

Patent metadata

Field	Value
Publication number	US-10461328-B2
Application number	US-201715780026-A
Country	US
Kind code	B2
Filing date	May 23, 2017
Priority date	May 30, 2016
Publication date	Oct 29, 2019
Grant date	Oct 29, 2019

Abstract

Provided are a cathode active material used for a lithium ion secondary battery capable of sufficiently realizing both high charge/discharge capacities and excellent cycle properties, and a lithium ion secondary battery using the cathode active material. The cathode active material contains a plurality of secondary particles formed via agglomeration of a plurality of primary particles of a lithium transition metal composite oxide. Spreading resistance distributions of the secondary particles respectively observed in cross-sections at optional three positions of the cathode active material are measured so as to afford average values of spreading resistance of the secondary particles in the respective cross-sections. The average values of spreading resistance of the secondary particles are further averaged. The resultant averaged value of spreading resistance is made to enter the range of 1.0×106 Ω/cm or more and 1.0×1010 Ω/cm or less.

First claim

The invention claimed is:

1. A cathode active material used for a lithium ion secondary battery, comprising a plurality of secondary particles formed via agglomeration of a plurality of primary particles of a lithium transition metal composite oxide, wherein
spreading resistance distributions of the secondary particles observed in cross-sections at three selected positions of the cathode active material are measured, and average values of spreading resistance of the secondary particles observed in the cross sections are calculated;
the calculated three average values of spreading resistance are further averaged; and
when an averaged value thus obtained is defined as a value of spreading resistance of the cathode active material, the averaged value thus defined is 1.0×10 6 Ω/cm or more and 1.0×10 10 Ω/cm or less.

2. The cathode active material used for a lithium ion secondary battery according to claim 1 , wherein the secondary particles comprise solid secondary particles.

3. The cathode active material used for a lithium ion secondary battery according to claim 1 , wherein porosity measured by mercury intrusion porosimetry is 1% or more and 20% or less.

4. The cathode active material used for a lithium ion secondary battery according to claim 1 , wherein the averaged value of spreading resistance is 0.90×10 9 Q/cm or less.

5. The cathode active material used for a lithium ion secondary battery according to claim 1 , wherein porosity measured by mercury intrusion porosimetry is 3% or more and 15% or less.

6. The cathode active material used for a lithium ion secondary battery according to claim 1 , wherein the lithium transition metal composite oxide is represented by the following Formula (1):
Li 1+a Ni b Co c Mn d M 1 e O 2+α   Formula (1)

where is a metal element other than Li, Ni, Mn and Co; “a”, “b”, “c”, “d”, “e” and “α” are respectively numerals satisfying the following conditions: −0.03≤a≤0.11, 0.7≤b≤1.0, 0<c<0.3, 0≤d<0.3, 0≤e<0.1, b+c+d+e=1, −0.2<α<0.2.

7. A lithium ion secondary battery, comprising a cathode active material according to claim 1 .

8. The lithium ion secondary battery according to claim 7 , comprising a cathode active material included in a cathode of a lithium ion secondary battery subjected to 100 charge/discharge cycles, wherein
a charge/discharge cycle is carried out via charging the secondary battery to an upper limit potential of 4.3 V, and subsequently discharging the secondary battery down to a lower limit potential of 2.7 V under 25° C. environment with charge/discharge rate of 1 C.

Assignees

• Hitachi Metals Ltd

Inventors

• Toyama Tatsuya
• Tokoro Hisato
• Takahashi Shin
• Gunji Akira
• Takano Shuichi
• Nakabayashi Takashi

Classifications

• C01P2004/04

  obtained by TEM, STEM, STM or AFM · CPC title

• C01P2006/16

  Pore diameter · CPC title

• C01P2002/52

  containing elements as dopants · CPC title

• C01P2002/54

  one element only · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title