Methods and apparatus for liquid crystal photoalignment

Patent metadata

Field	Value
Publication number	US-10459293-B2
Application number	US-201816117468-A
Country	US
Kind code	B2
Filing date	Aug 30, 2018
Priority date	Sep 5, 2014
Publication date	Oct 29, 2019
Grant date	Oct 29, 2019

Abstract

Liquid crystal photonic devices and microcavities filled with liquid crystal materials are becoming increasingly popular. These devices often present a challenge when it comes to creating a robust alignment layer in pre-assembled cells. Previous research on photo-definable alignment layers has shown that they have limited stability, particularly against subsequent light exposure. A method of infusing a dye into a microcavity to produce an effective photo-definable alignment layer is described, along with a method of utilizing a pre-polymer infused into the microcavity mixed with the liquid crystal to provide photostability. In this method, the polymer layer, formed under optical irradiation of liquid crystal cells, is effectively localized to a thin region near the substrate surface and thus provides a significant improvement in the photostability of the liquid crystal alignment. This versatile alignment layer method, which can be used in microcavities to displays, offers significant promise for new photonics applications.

First claim

The invention claimed is:

1. A method of aligning liquid crystal material to an inner surface of a microcavity, the method comprising:
forming the microcavity with a fill hole with a diameter smaller than a lateral dimension of the microcavity;
infusing an anisotropic dye dissolved in a solvent into the microcavity via the fill hole;
evaporating the solvent so as to coat the interior surface of the microcavity with the anisotropic dye;
illuminating the anisotropic dye with linearly polarized light so as to form an anisotropic dye layer on the interior surface of the microcavity aligned perpendicular to a polarization axis of the linearly polarized light;
infusing reactive mesogen, liquid crystal material, and photoinitiator into the microcavity; and
illuminating the reactive mesogen at a wavelength selected to cause polymerization of the layer of reactive mesogen material so as to form a polymerized reactive mesogen layer aligning the liquid crystal material with respect to the anisotropic dye layer.

2. The method of claim 1 , wherein infusing the anisotropic dye comprises infusing at least one of an azo dye or a dye substantially similar to an azo compound.

3. The method of claim 1 , wherein infusing the anisotropic dye comprises:
disposing the microcavity in a dye solution comprising the anisotropic dye dissolved in the solvent; and wherein evaporating the solvent comprises:
heating the microcavity so as to evaporate the solvent.

4. The method of claim 1 , wherein infusing the reactive mesogen, the liquid crystal material, and the photoinitiator comprises infusing RM257.

5. The method of claim 1 , wherein the reactive mesogen, the liquid crystal material, and the photoinitiator form a mixture having a weight ratio of reactive mesogen to liquid crystal material to photoinitiator of about 1.35 to 98.50 to 0.15.

6. The method of claim 1 , further comprising:
heating and mixing the reactive mesogen, the liquid crystal material, and the photoinitiator prior to infusing the reactive mesogen, the liquid crystal material, and the photoinitiator into the microcavity.

7. The method of claim 1 , further comprising:
allowing the reactive mesogen to separate from the liquid crystal material before illuminating the reactive mesogen.

8. The method of claim 1 , wherein illuminating the reactive mesogen further comprises:
applying at least one voltage across at least a portion of the microcavity while illuminating the reactive mesogen so as to lock in alignment of the polymerized reactive mesogen layer with respect to the anisotropic dye layer.

9. The method of claim 8 , wherein applying the at least one voltage comprises:
applying a first voltage across a first portion of the microcavity and a second voltage across a second portion of the microcavity so as to create spatially varying alignment of the anisotropic dye to the liquid crystal material.

10. The method of claim 1 , wherein the polymerized reactive mesogen layer has a thickness of less than approximately 100 nanometers.

11. The method of claim 1 , further comprising:
wherein illuminating the reactive mesogen comprises illuminating the reactive mesogen with ultraviolet light.

12. The method of claim 1 , wherein infusing the reactive mesogen, the liquid crystal material, and the photoinitiator comprises infusing Irgacure 651.

Assignees

• Massachusetts Inst Technology

Inventors

• Finnemeyer Valerie A
• Reich Robert K
• Clark Harry R
• Bozler Carl O
• Berry Shaun R
• Bos Philip J
• Bryant Douglas R

Classifications

• G02F1/133377

  Cells with plural compartments or having plurality of liquid crystal microcells partitioned by walls, e.g. one microcell per pixel · CPC title

• C09K19/56

  Aligning agents · CPC title

• G02F2202/043

  pleochroic · CPC title

• G02F1/133711 Primary

  by organic films, e.g. polymeric films · CPC title

• G02F1/133788

  by light irradiation, e.g. linearly polarised light photo-polymerisation · CPC title