Separation of components from a fluid by solids production

Patent metadata

Field	Value
Publication number	US-10458704-B2
Application number	US-201715692506-A
Country	US
Kind code	B2
Filing date	Aug 31, 2017
Priority date	Aug 31, 2017
Publication date	Oct 29, 2019
Grant date	Oct 29, 2019

Abstract

A method for separating components from a fluid is disclosed. A cooling element is provided and is disposed in contact with a distal side of one or more thermally-conductive surfaces. One or more resistive heating elements are provided and are disposed in contact with or embedded in a proximal side of the one or more thermally-conductive surfaces. A fluid comprising one or more secondary components is provided. The fluid is passed across the one or more thermally conductive surfaces, the one or more secondary components freezing, crystallizing, desublimating, depositing, condensing, or combinations thereof, out of the fluid. The one or more resistive heating elements engage such that the one or more solid secondary components detach and pass out the solids outlet. The one or more resistive heating elements disengage, restarting production of the one or more solid secondary components.

First claim

We claim:

1. A method for separating components from a fluid comprising:
providing a cooling element, one or more resistive heating elements, a fluid inlet, one or more thermally-conductive surfaces, a fluid outlet, and a solids outlet;
providing the cooling element disposed in contact with a distal side of the one or more thermally-conductive surfaces, the cooling element cooling the one or more thermally-conductive surfaces;
providing the one or more resistive heating elements disposed in contact with or embedded in a proximal side of the one or more thermally-conductive surfaces;
providing a fluid comprising one or more secondary components dissolved, entrained, suspended, absorbed, condensed, or combinations thereof, wherein the fluid freezes at a lower temperature than the one or more secondary components, wherein the fluid is passed across the one or more thermally conductive surfaces, at least a portion of the one or more secondary components freezing, crystalizing, desublimating, depositing, condensing, or combinations thereof, out of the fluid as one or more solid secondary components, while the fluid passes out the fluid outlet;
detecting that the one or more solid secondary components reach a pre-determined thickness by an instrument that measures thicknesses of the one or more solid secondary components on the one or more thermally-conductive surfaces, wherein the instrument comprises one or more pistons that probe the one or more thermally-conductive surfaces, determining the thicknesses by how close the one or more pistons come to the one or more thermally-conductive surfaces without resistance;
engaging the one or more resistive heating elements such that the one or more solid secondary components detach from the one or more thermally-conductive surfaces and pass out the solids outlet; and,
disengaging the one or more resistive heating elements, restarting production of the one or more solid secondary components.

2. The method of claim 1 , wherein the fluid comprises a gas, a liquid, a slurry, or combinations thereof.

3. The method of claim 1 , further comprising the instrument providing a signal to a controller.

4. The method of claim 1 , wherein the one or more thermally conductive surfaces comprise slanted shelves attached to a vertical support.

5. The method of claim 4 , further comprising providing one or more of the resistive heating elements adjacent to the vertical support and a top portion of the one or more shelves.

6. The method of claim 1 , wherein the one or more secondary components further comprise soot, dust, minerals, microbes, solid hydrocarbons, precipitated salts, or combinations thereof.

7. The method of claim 1 , wherein the fluid comprises water, hydrocarbons, liquid ammonia, liquid carbon dioxide, cryogenic liquids, flue gas, syngas, producer gas, natural gas, steam reforming gas, hydrocarbons, light gases, refinery off-gases, organic solvents, steam, ammonia, or combinations thereof.

8. The method of claim 1 , wherein the one or more secondary components comprise carbon dioxide, nitrogen oxide, sulfur dioxide, nitrogen dioxide, sulfur trioxide, hydrogen sulfide, hydrogen cyanide, water, mercury, hydrocarbons, or combinations thereof.

9. The method of claim 1 , further comprising providing a screen, the fluid passing through the screen to the fluid outlet and the one or more solid secondary components crossing the screen and being removed through the solids outlet.

10. The method of claim 9 , further comprising vibrating the screen to cause the one or more solid secondary components to move out the solids outlet.

11. The method of claim 1 , wherein the cooling element comprises vapor-compression refrigeration systems, Peltier coolers, or indirect-contact heat exchangers.

12. The method of claim 1 , wherein the one or more thermally-conductive surfaces comprise metals, diamond, graphite, graphene, thermally-conductive ceramics, thermally-conductive resins, thermally-conductive adhesives, or combinations thereof.

13. A method for separating components from a fluid comprising:
providing a cooling element, one or more resistive heating elements, a fluid inlet, one or more thermally-conductive surfaces, a fluid outlet, and a solids outlet, wherein the one or more thermally conductive surfaces comprise a cylindrical surface of a cylindrical cooling heat exchanger;
providing the cooling element disposed in contact with a distal side of the one or more thermally-conductive surfaces, the cooling element cooling the one or more thermally-conductive surfaces;
providing the one or more resistive heating elements disposed in contact with or embedded in a proximal side of the one or more thermally-conductive surfaces;
providing a fluid comprising one or more secondary components dissolved, entrained, suspended, absorbed, condensed, or combinations thereof, wherein the fluid freezes at a lower temperature than the one or more secondary components, wherein the fluid is passed across the one or more thermally conductive surfaces, at least a portion of the one or more secondary components freezing, crystalizing, desublimating, depositing, condensing, or combinations thereof, out of the fluid as one or more solid secondary components, while the fluid passes out the fluid outlet;
engaging the one or more resistive heating elements such that the one or more solid secondary components detach from the one or more thermally-conductive surfaces and pass out the solids outlet; and,
disengaging the one or more resistive heating elements, restarting production of the one or more solid secondary components;
wherein the one or more resistive heating elements comprise a ring of a conductive material, the ring embedded in an end of a piston which descends when the heating element is engaged, warming the one or more solid secondary components and slicing the one or more solid secondary components off the cylindrical surface, and returns to a top portion when the heating element is disengaged.

14. The method of claim 13 , wherein the one or more thermally conductive surfaces comprise slanted shelves attached to a vertical support.

15. The method of claim 14 , further comprising providing one or more of the resistive heating elements adjacent to the vertical support and a top portion of the one or more shelves.

16. The method of claim 13 , wherein the one or more secondary components further comprise soot, dust, minerals, microbes, solid hydrocarbons, precipitated salts, or combinations thereof.

17. The method of claim 13 , wherein the fluid comprises water, hydrocarbons, liquid ammonia, liquid carbon dioxide, cryogenic liquids, flue gas, syngas, producer gas, natural gas, steam reforming gas, hydrocarbons, light gases, refinery off-gases, organic solvents, steam, ammonia, or combinations thereof.

18. The method of claim 13 , wherein the one or more secondary components comprise carbon dioxide, nitrogen oxide, sulfur dioxide, nitrogen dioxide, sulfur trioxide, hydrogen sulfide, hydrogen cyanide, water, mercury, hydrocarbons, or combinations thereof.

19. The method of claim 13 , further comprising providing a screen, the fluid passing through the screen to the fluid outlet and the one or more solid secondary components crossing the screen and being removed through the solids outlet.

20. The method of claim 19 , further comprising vibrating the screen to cause the one or more solid secondary components to move out the solids outlet.

Assignees

• Baxter Larry
• Mansfield Eric
• Hoeger Christopher
• Stitt Kyler
• Chamberlain Skyler
• Davis Nathan
• Hall Labs Llc

Inventors

• Baxter Larry
• Mansfield Eric
• Hoeger Christopher
• Stitt Kyler
• Chamberlain Skyler
• Davis Nathan

Classifications

• B01D2258/0283

  Flue gases · CPC title

• B01D2257/504

  Carbon dioxide · CPC title

• F25J2205/40

  using hybrid system, i.e. combining cryogenic and non-cryogenic separation techniques · CPC title

• B01D53/002

  by condensation · CPC title

• B01D46/0053

  with vibrating filtering elements · CPC title