Continuous boron nitride nanotube yarns and methods of production

Patent metadata

Field	Value
Publication number	US-10458049-B2
Application number	US-201414447433-A
Country	US
Kind code	B2
Filing date	Jul 30, 2014
Priority date	Jul 30, 2013
Publication date	Oct 29, 2019
Grant date	Oct 29, 2019

Abstract

A method and apparatus for producing boron nitride nanotubes and continuous boron nitride nanotube yarn or tapes is provided. The apparatus includes rotating reaction tubes that allow for continuous chemical vapor deposition of boron nitride nanotubes. The rotation of the reaction tubes allows the boron nitride nanotubes to be spun into yarns or made into tapes, without post process or external rotation or spinning of the gathered nanotubes. Boron nitride nanotube yarns or tapes of great length can be produced as a result, thereby providing industry with a readily useable format for this type of material. Dopants such as carbon can be added to engineer the band gap of the nanotubes. Catalysts may be formed outside or inside the reactor.

First claim

What is claimed is:

1. A continuous boron nitride nanotube yarn comprising:
a plurality of boron-nitride nanotubes made using a continuous process, the plurality of boron-nitride nanotubes including a first boron-nitride nanotube and a second boron-nitride nanotube, the first and second boron-nitride nanotubes each have an aspect ratio of greater than 100,000:1 and each forming a helix around a common axis wherein the first and second boron-nitride nanotubes each have a pitch angle between 5° and 50°, thereby forming a continuous boron nitride nanotube yarn having a length greater than 1 m.

2. The boron nitride nanotube yarn of claim 1 wherein the first and second nanotubes each have an aspect ratio of greater than 1,000,000:1.

3. A high temperature composite comprising the boron nitride nanotube yarn of claim 1 .

4. Body armor comprising the boron nitride nanotube yarn of claim 1 .

5. A boron nitride composite comprising cubic boron nitride and the boron nitride nanotube yarn of claim 1 .

Assignees

• Univ New Hampshire

Inventors

• Lashmore David S
• Bennett Tyler

Classifications

• C01P2004/54

  Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension · CPC title

• C04B2235/524

  Non-oxidic, e.g. borides, carbides, silicides or nitrides · CPC title

• C04B2235/526

  characterised by the length of the fibers · CPC title

• D02G3/16

  Yarns or threads made from mineral substances · CPC title

• D10B2101/14

  Carbides; Nitrides; Silicides; Borides · CPC title