Electrically conducting assemblies

Patent metadata

Field	Value
Publication number	US-10455696-B2
Application number	US-201414917172-A
Country	US
Kind code	B2
Filing date	Sep 5, 2014
Priority date	Sep 6, 2013
Publication date	Oct 22, 2019
Grant date	Oct 22, 2019

Abstract

The present invention pertains to a process for the manufacture of a multilayer assembly comprising applying at least one patterned substrate onto at least one surface of at least one non-patterned substrate. The present invention also pertains to the multilayer assembly obtainable by said process and to uses of said multilayer assembly in various applications.

First claim

The invention claimed is:

1. A process for the manufacture of a multilayer assembly, said process comprising:
applying a patterned layer (LMP) of at least one patterned substrate directly onto a non-patterned layer (LMT) of at least one non-patterned substrate, thereby providing a multilayer assembly, wherein:
(1) the at least one patterned substrate is obtained by a process comprising:
printing a liquid composition (L1) comprising at least one first metal compound (M1) onto at least one surface of an optically transparent substrate layer (LT-1) having an outer surface and an inner surface to form a patterned layer (LMP), thus providing a patterned substrate,
optionally, contacting the patterned layer (LMP) with a liquid composition (L2) comprising at least one second metal compound (M2), said compound (M2) being equal to or different from the compound (M1), and
drying the patterned substrate, optionally contacted with composition (L2), at a temperature of at least 50° C.; and wherein

(2) the at least one non-patterned substrate is obtained by a process comprising:
optionally, treating by a radio-frequency glow discharge process in the presence of an etching gas, at least one surface of an optically transparent substrate layer (LT-2) having an outer surface and an inner surface, said layer (LT-2) being equal to or different from layer (LT-1),
contacting optionally treated layer (LT-2) with a liquid composition (L3) comprising at least one optically transparent metal compound (M ot ), to form an optically transparent non-patterned layer (LMT), thus providing a non-patterned substrate, and
drying the non-patterned substrate at a temperature of at least 50° C.

2. The process according to claim 1 , wherein compound (M ot ) is a metal oxide selected from the group consisting of:
impurity-doped ZnO, In 2 O 3 , SnO 2 and CdO,
ternary metal oxide compounds, and
multi-component metal oxides consisting of combinations of ZnO, In 2 O 3 and SnO 2 .

3. The process according to claim 2 , wherein compound (M ot ) is a metal oxide selected from the group consisting of Sn-doped ZnO, Sn-doped In 2 O 3 , Sn-doped CdO, Zn 2 SnO 4 , ZnSnO 3 , Zn 2 In 2 O 5 , Zn 3 In 2 O 6 , In 2 SnO 4 , and CdSnO 3.

4. The process according to claim 1 , wherein layer (LT-2) is contacted with composition (L3) by electroless plating techniques.

5. The process according to claim 1 , wherein compound (M1) is selected from the group consisting of Rh, Ir, Ru, Ti, Re, Os, Cd, Tl, Pb, Bi, In, Sb, Al, Ti, Cu, Ni, Pd, V, Fe, Cr, Mn, Co, Zn, Mo, W, Ag, Au, Pt, Ir, Ru, Pd, Sn, Ge, Ga, alloys thereof and derivatives thereof.

6. The process according to claim 1 , wherein composition (L1) is printed by screen, gravure, flexo or ink-jet printing techniques.

7. The process according to claim 1 , wherein compound (M2) is selected from the group consisting of Rh, Ir, Ru, Ti, Re, Os, Cd, Tl, Pb, Bi, In, Sb, Al, Ti, Cu, Ni, Pd, V, Fe, Cr, Mn, Co, Zn, Mo, W, Ag, Au, Pt, Ir, Ru, Pd, Sn, Ge, Ga, alloys thereof and derivatives thereof.

8. The process according to claim 1 , wherein layer (LMP) is contacted with composition (L2) by electroplating or electroless plating techniques.

9. A process for the manufacture of a multilayer assembly, said process comprising:
printing a liquid composition (L1) comprising at least one first metal compound (M1) onto an optically transparent substrate layer (LT-1) having an outer surface and an inner surface,
wherein layer (LT-1) is a non-patterned substrate comprising:
an optically transparent substrate layer (LT-2) having an outer surface and an inner surface, and
an optically transparent non-patterned layer (LMT) made of at least one optically transparent metal compound (M ot ) directly adhered onto at least one surface of layer (LT-2), and
wherein said at least one surface of layer (LT-2) is optionally treated by a radio-frequency glow discharge process in the presence of an etching gas,

wherein the liquid composition (L1) is printed directly on the surface of layer (LMT) that is opposite to layer (LT-2), to form a patterned layer (LMP),
optionally, contacting patterned layer (LMP) with a liquid composition (L2) comprising at least one second metal compound (M2), said compound (M2) being equal to or different from the compound (M1), and
drying the patterned substrate, optionally contacted with composition (L2), at a temperature of at least 50° C.

10. The process according to claim 9 , wherein the non-patterned substrate is obtained by a process comprising:
optionally, treating by a radio-frequency glow discharge process in the presence of an etching gas, at least one surface of an optically transparent substrate layer (LT-2) having an outer surface and an inner surface,
contacting optionally treated layer (LT-2) with a liquid composition (L3) comprising at least one optically transparent metal compound (M ot ), to form an optically transparent non-patterned layer (LMT), thus providing a non-patterned substrate, and
drying the non-patterned substrate at a temperature of at least 50° C.

Assignees

• Solvay Specialty Polymers It

Inventors

• Cojocaru Paula
• Apostolo Marco
• Marrani Alessio
• Falco Ivan

Classifications

• C08J2367/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds; (C08J2367/06 takes precedence) · CPC title

• C08J7/06 Primary

  with compositions not containing macromolecular substances · CPC title

• C03C17/38

  at least one coating being a coating of an organic material · CPC title

• H05K3/0041

  by plasma etching · CPC title

• H05K3/1225

  Screens or stencils; Holders therefor · CPC title