Method for making high-temperature superconducting film
US-2015380130-A1 · Dec 31, 2015 · US
US10453590B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10453590-B2 |
| Application number | US-201313907356-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 31, 2013 |
| Priority date | Jun 1, 2012 |
| Publication date | Oct 22, 2019 |
| Grant date | Oct 22, 2019 |
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Disclosed is a superconducting article comprising a silver overlayer consisting of no more than about 20% of grains over about 1 μm, having a minimum Vickers micro-hardness value of about 100, and a porosity of less than about 1%. A method of manufacturing a superconducting tape is disclosed as comprising, deposition of silver, oxygenation at about 400° C. for about 30 minutes, slitting, deposition of silver at a temperature of less than about 250° C., and application of copper.
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I claim: 1. A superconducting tape comprising: a substrate; a biaxially-textured buffer layer overlying the substrate; a superconducting film on the buffer layer; and a silver layer deposited on the superconducting film, comprising: an oxygenated first silver layer comprising a porosity of less than about 1%, and a second silver layer formed on the first silver layer, wherein the second silver layer is not oxygenated, wherein the silver layer comprises less than about 20% of silver grains over about 1 μm in size. 2. The tape of claim 1 , wherein the silver layer has a minimum Vickers micro-hardness value of about 100. 3. The tape of claim 1 , further comprising a copper layer overlying the silver layer. 4. A superconducting tape comprising: a substrate; a biaxially-textured buffer layer overlying the substrate; a superconducting film on the buffer layer; and a silver layer deposited on the superconducting film, comprising: an oxygenated first silver layer, and a final silver layer disposed above the first silver layer, wherein the final silver layer is not oxygenated. 5. The tape of claim 4 , wherein the silver layer comprises less than about 20% of silver grains over about 1 μm in size. 6. A superconducting tape comprising: a substrate; a biaxially-textured buffer layer overlying the substrate; a superconducting film on the buffer layer; and a silver layer deposited on the superconducting film, comprising: a first silver layer comprising a porosity of less than about 1%, and a second silver layer deposited on the first silver layer, wherein the second silver layer is not oxygenated, and wherein the silver layer comprises less than about 20% of silver grains over about 1 μm in size. 7. The tape of claim 6 , wherein the silver layer has a minimum Vickers micro-hardness value of about 100. 8. A superconducting tape comprising: a substrate; a biaxially-textured buffer layer overlying the substrate; a superconducting film on the buffer layer; and a silver layer deposited on the superconducting film, comprising: a first silver layer, and a final silver layer disposed above the first silver layer, wherein the final silver layer is not oxygenated; wherein the first silver layer comprises a porosity of less than about 1%. 9. A superconducting tape comprising: a substrate; a biaxially-textured buffer layer overlying the substrate; a superconducting film on the buffer layer; and a silver layer deposited on the superconducting film, comprising: a first silver layer, and a final silver layer disposed above the first silver layer, wherein the final silver layer is not oxygenated; wherein the silver layer has a minimum Vickers micro-hardness value of about 100. 10. A superconducting tape comprising: a substrate; a biaxially-textured buffer layer overlying the substrate; a superconducting film on the buffer layer; and a silver layer deposited on the superconducting film, comprising: an oxygenated first silver layer; and a second silver layer deposited on the first silver layer, wherein the second silver layer is not oxygenated. 11. The tape of claim 10 , wherein the silver layer comprises less than about 20% of silver grains over about 1 μm in size. 12. A superconducting tape comprising: a substrate; a biaxially-textured buffer layer overlying the substrate; a superconducting film on the buffer layer; and a silver layer deposited on the superconducting film, comprising: a first silver layer; and a second silver layer deposited on the first silver layer, wherein the second silver layer is not oxygenated; wherein the first silver layer comprises a porosity of less than about 1%. 13. A superconducting tape comprising: a substrate; a biaxially-textured buffer layer overlying the substrate; a superconducting film on the buffer layer; and a silver layer deposited on the superconducting film, comprising: a first silver layer; and a second silver layer deposited on the first silver layer, wherein the second silver layer is not oxygenated; wherein the silver layer has a minimum Vickers micro-hardness value of about 100. 14. A superconducting tape comprising: a substrate; a biaxially-textured buffer layer overlying the substrate; a superconducting film on the buffer layer; and a silver layer deposited on the superconducting film, comprising: an oxygenated first silver layer and a final silver layer, wherein the final silver layer is not oxygenated. 15. The tape of claim 14 , wherein the silver layer comprises less than about 20% of silver grains over about 1 μm in size. 16. A superconducting tape comprising: a substrate; a biaxially-textured buffer layer overlying the substrate; a superconducting film on the buffer layer; and a silver layer deposited on the superconducting film, comprising: a first silver layer and a final silver layer, wherein the final silver layer is not oxygenated; and wherein the first silver layer comprises a porosity of less than about 1%. 17. A superconducting tape comprising: a substrate; a biaxially-textured buffer layer overlying the substrate; a superconducting film on the buffer layer; and a silver layer deposited on the superconducting film, comprising: a first silver layer and a final silver layer, wherein the final silver layer is not oxygenated; and wherein the silver layer has a minimum Vickers micro-hardness value of about 100.
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