Device and method for conversion of carbon dioxide to organic compounds

Patent metadata

Field	Value
Publication number	US-10450662-B2
Application number	US-201615242439-A
Country	US
Kind code	B2
Filing date	Aug 19, 2016
Priority date	Aug 25, 2015
Publication date	Oct 22, 2019
Grant date	Oct 22, 2019

Abstract

The present invention relates to a device for bioassisted conversion of carbon dioxide to organic compounds that can be used a fuels and chemicals. The present invention also relates to a bioassisted process of converting carbon dioxide to organic compounds.

First claim

The invention claimed is:

1. A device for bioassisted conversion of carbon dioxide (CO 2 ) to organic compounds selected from the group consisting of methanol, butanol and butanoic acid, said device consisting of:
(a) a means of introducing gas stream containing CO 2 [ 1 ] directly or through a microbubble generator [ 1 A] in cathode chamber [ 2 ];
(b) a cathode electrode [ 3 ];
(c) cathode aqueous medium [ 14 ] comprising chemicals selected from 4-hydroxyphenethyl alcohol; furanosyl borate ester; oxylipins; N-butyryl-DL-homocysteine thiolactone; 2-heptyl-3-hydroxy-4(1H)-quinolone; N-hexanoyl-DL-homoserine lactone; and N—[(RS)-3-hydroxybutyryl]-L-homoserine lactone in the range of 0.2-2 ppm for the formation of electroactive microbes biofilm;
(d) biofilm of electroactive microbes [ 4 ] consist of consortia of electroactive microbes selected from Enterobacter aerogenes MTCC 25016, Serratia sp. MTCC 25017, Shewanella sp. MTCC 25020 and Alicaligens sp. MTCC 25022;
(e) an anode chamber [ 5 ] comprising an anode electrode [ 6 ] and anode medium [ 7 ];
(f) a light source [ 8 ];
(g) an electrically conductive wire [ 9 ];
(h) optionally with:
(i) an ion-exchange membrane [ 10 ];
(ii) a CO 2 improving column [ 11 ], wherein CO 2 solubility improving column [ 11 ] consist of element [ 13 ], wherein the element [ 13 ] either consist of a biofilm of microbe selected from Pseudomonas fragi MTCC 25025 or a pure carbonic anhydrase immobilized on a matrix that enhances the solubility of CO 2 ; wherein the matrix is selected from the group consisting of carbon nanotubes, metal organic framework, zeolites, zinc-ferrite, nickel ferrite and zincnickel (ZnNi) ferrite;
(iii) in-situ product recovery column [ 12 ]; and
(iv) a connector element [ 12 A], which is means of recirculating aqueous medium or effluent or electrolyte medium from in-situ product recovery column [ 12 ] to CO 2 improving column [ 11 ] and back to cathode chamber [ 2 ].

2. The device as claimed in claim 1 , wherein cathode electrode [ 3 ] is made of material selected from graphite, graphite felt, porous graphite, graphite powder carbon paper, carbon cloth, carbon felt, carbon wool, carbon foam, stainless steel as such or modified or combinations thereof.

3. The device as claimed in claim 1 , wherein cathode electrode [ 3 ] is immersed in an aqueous medium [ 14 ] consisting of nitrogen compounds, phosphorus compounds and micronutrients having pH in the range of 5-12.

4. The device as claimed in claim 1 , wherein the microbes of microbial consortia are capable of producing carbonic anhydrase.

5. The device as claimed in claim 1 , wherein the light source [ 7 ] is sunlight, xenon lamp, etc.

6. The device as claimed in claim 1 , wherein in-situ product recovery column [ 12 ] is made of material selected from ion exchange resins, activated carbon, macroporous polystyrene anion-exchange, hollow fiber membrane, zeolites or activated charcoal.

7. The device as claimed in claim 1 , wherein the cathode [ 2 ] and anode chamber [ 5 ] consist of single or multiple cathode and anode electrodes.

8. The device as claimed in claim 1 , wherein the anode chamber [ 5 ] and cathode chamber [ 2 ] are optionally separated by an ion-exchange membrane [ 10 ].

9. A method for bioassisted conversion of CO 2 to organic compounds selected from the group consisting of methanol, butanol and butanoic acid employing the device as claimed in claim 1 , said method comprising the steps of:
(a) irradiating the anode electrode [ 6 ] with the light source at a wavelength in range of 380-780 nm;
(b) transferring electrons generated at the anode electrode [ 6 ] to the cathode chamber [ 2 ] via the electrically conductive wire [ 9 ];
(c) sparging gas stream [ 1 ] directly or through the microbubble generator [ 1 A] to the CO 2 improving column [ 11 ] to enhance the solubility of CO 2 ;
(d) passing the highly solubilized stream of CO 2 of step (c) to the cathode chamber [ 2 ] near the cathode electrode [ 3 ] enveloped by the biofilm of electroactive microbes [ 4 ];
(e) obtaining an organic compound;
(f) passing the organic compound of step (e) optionally to the in situ product recovery column [ 12 ] to separate the organic compound and aqueous medium or effluent; and
(g) recirculating the aqueous medium/effluent without the organic compound of step (f) to the CO 2 improving column [ 11 ] through a connector element [ 12 A].

10. The method as claimed in claim 9 , wherein the anode chamber [ 5 ] and the cathode chamber [ 2 ] are optionally separated by an ion-exchange membrane [ 10 ] to restrict flow of oxygen to the cathode chamber [ 2 ] from the anode chamber [ 5 ].

11. The method as claimed in claim 9 , wherein the electroactive microbes of the biofilm function at a temperature in the range of 10° C. to 52° C.

12. The method as claimed in claim 9 , wherein in step (c) the gas stream consists of N 2 and CO 2 in the ratio of 50:50.

13. The method as claimed in claim 9 , wherein the cathode chamber [ 2 ] and the anode chamber [ 5 ] may consist of single or multiple respective cathode and anode electrodes.

14. The biofilm of electroactive microbes as claimed in claim 9 , wherein the biofilm of electroactive microbes are stored in electrolyte solution in air tight conditions at a temperature of 4-5° C.

15. The biofilm of electroactive microbes as claimed in claim 9 , wherein the biofilm of electroactive microbes are stored at a temperature of 4-5° C. by encapsulating with an egg membrane or an onion cell membrane.

16. The biofilm of electroactive microbes as claimed in claim 9 , wherein biofilm of electroactive microbes along with the cathode electrode are lyophilized at a temperature of −80° C.

Assignees

• Indian Oil Corp Ltd

Inventors

• Kumar Manoj
• Singh Mahendra Pratap
• Srivastava Umish
• Gupta Anurag Ateet
• Das Biswapriya

Classifications

• C25B15/08

  Supplying or removing reactants or electrolytes; Regeneration of electrolytes · CPC title

• C25B3/04 Primary

  Chemistry & Metallurgy · mapped topic

• C25B9/10

  Chemistry & Metallurgy · mapped topic

• C25B11/0442

  Chemistry & Metallurgy · mapped topic

• C25B3/26

  of carbon dioxide · CPC title