Thermal switch based on polymer compound

Patent metadata

Field	Value
Publication number	US-10450490-B2
Application number	US-201615557420-A
Country	US
Kind code	B2
Filing date	Mar 11, 2016
Priority date	Mar 12, 2015
Publication date	Oct 22, 2019
Grant date	Oct 22, 2019

Abstract

The present invention relates to an article suitable to act as a thermal switch device, the article having a surface resistance of more than 105 ohms and formed from a polymer composition comprising from 50 to 99.9 wt % relative to the total weight of the polymer composition, of a polymer being selected from an amorphous polymer having a glass transition temperature Tg, a semi-crystalline polymer having a melting temperature Tm or a mixture thereof, and from 0.1 to 50 wt % relative to the total weight of the polymer composition, of a conductive material, wherein the surface resistance of the article is divided by at least 10, preferably by at least 100, when said article is submitted for a determined period of time of less than 5 minutes to a temperature of switch i) ranging from Tg+10° C. to Tg+250° C. if the polymer composition comprises an amorphous polymer, or ii) ranging from Tm−80° C. to Tm+250° C. if the polymer composition comprises a semi-crystalline polymer.

First claim

The invention claimed is:

1. An article suitable to act as a thermal switch device, the article having a surface resistance of more than 10 5 ohms as determined according to ASTM D257-07, and being formed from a polymer composition, said polymer composition comprising
from 50 to 99.9 wt % relative to the total weight of the polymer composition, of a polymer being selected from an amorphous polymer having a glass transition temperature Tg, a semi-crystalline polymer having a melting temperature Tm or a mixture thereof, and
from 0.1 to 50 wt % relative to the total weight of the polymer composition, of a conductive material;
wherein the surface resistance of the article is divided by at least 10, when said article is submitted for a determined period of time of less than 5 minutes to a temperature switch
i) ranging from Tg+10° C. to Tg+250° C. if the polymer composition comprises an amorphous polymer,
ii) ranging from Tm−80° C. to Tm+250° C. if the polymer composition comprises a semi-crystalline polymer,
iii) ranging from Tg+10° C. to Tg+250° C. if the polymer composition comprises a mixture of amorphous and semi-crystalline polymers and the amorphous polymer forming the continuous polymeric phase, or
iv) ranging from Tm−80° C. to Tm+250° C. if the polymer composition comprises a mixture of amorphous and semi-crystalline polymers and the semi-crystalline polymer forming the continuous polymeric phase.

2. The article according to claim 1 , wherein the conductive material of the polymer composition is selected from the group consisting of carbon nanotubes, carbon nanofibers, carbon black, metal fibers, metal powders and blends thereof.

3. The article according to claim 1 , wherein the polymer composition comprises an amorphous polymer, wherein the amorphous polymer is selected from polystyrene (PS), atactic polypropylene (aPP), acrylonitrile-butadiene-styrene (ABS), polycarbonate (PC), styrene acrylonitrile (SAN), poly(methyl methacrylate) (PMMA), poly(vinyl chloride) (PVC), polybutadiene (PBu), polybutylene terephthalate (PBt), poly(p-phenylene oxide) (PPO), polysulfone (PSU), polyethersulfone (PES), polyethylenimine (PEI), polyphenylsulfone (PPSU), acrylonitrile styrene acrylate (ASA) or any combination thereof.

4. The article according to claim 1 , wherein the polymer composition comprises an semi-crystalline polymer, and wherein the semi-crystalline polymer is selected from polyamide, homo- and co-polymer of ethylene (PE), homo- and co-polymer of propylene (PP), impact copolymer of propylene (IPP), Polylactide (PLA), polyether ether ketone (PEEK), polyoxymethylene (POM), syndiotactic polystyrene (sPS), polyphenylene sulfide (PPS), liquid crystalline polymers (LCP), homo- and co-polymer of butane, homo- and co-polymer of hexene, ethylene vinyl acetate (EVA), polyurethane or any combination thereof.

5. The article according to claim 1 , wherein the surface resistance of the article is divided by at least 10, when said article is submitted for a determined period of time of less than 5 minutes to temperature switch
i) ranging from Tg+75° C. to Tg+250° C. if the polymer composition comprises an amorphous polymer.

6. The article according to claim 5 wherein the surface resistance of the article is divided by at least 10, when said article is submitted for less than 2 minutes to the temperature switch.

7. The article according to claim 1 , wherein the polymer composition comprises at least 0.5 wt % relative to the total weight of the polymer composition, of the conductive material.

8. The article according to claim 1 having a thermal conductivity higher than 0.4 W/(m*K).

9. The article according to claim 1 , wherein the article is a film, a sheet, a formed sheet, a pipe or an injected article.

10. A process to produce an article suitable to act as a thermal switch device according to claim 1 , comprising the step of:
a) providing a polymer composition having a surface resistance of less than 10 4 ohms, said polymer composition comprising:
from 50 to 99.9 wt % relative to the total weight of the polymer composition, of a polymer being selected from an amorphous polymer having a glass transition temperature Tg, a semi-crystalline polymer having a melting temperature Tm or a mixture thereof, and
from 0.1 to 50 wt % relative to the total weight of the polymer composition, of a conductive material;
b) forming or pre-forming an article; and
c) cooling the article by contact with a cooling device system or medium using a temperature of at least Tg−20° C. if the polymer composition comprises an amorphous polymer or at least Tm−20° C. if the polymer composition comprises a semi-crystalline polymer.

11. A process according to claim 10 , wherein the step b) of forming or performing the article is made by extrusion or injection.

12. A process according to claim 10 , wherein the step c) comprises cooling the article by a cooling device system using a temperature ranging from Tg−20° C. to Tg−150° C. if the polymer composition comprises an amorphous polymer, ranging from Tm−20° C. to Tm−150° C. if the polymer composition comprises a semi-crystalline polymer, ranging from Tg+10° C. to Tg+250° C. if the polymer composition comprises a mixture of amorphous and semi-crystalline polymers and the amorphous polymer forming the continuous polymeric phase, or ranging from Tm−80° C. to Tm+250° C. if the polymer composition comprises a mixture of amorphous and semi-crystalline polymers and the semi-crystalline polymer forming the continuous polymeric phase.

13. A process according to claim 10 , the process comprising a step b) of pre-forming the article resulting in a pre-formed article wherein the process further comprises after step c), a step d) of forming the article from the preformed article at a temperature less than Tg when the polymer composition comprises an amorphous polymer, less than Tm when the polymer composition comprises a semi-crystalline polymer, at a temperature less than Tg when the polymer composition comprises a mixture of amorphous and semi-crystalline polymers and the amorphous polymer forming a continuos polymeric phase, or at a temperature less than Tm when the polymer composition comprises a mixture of amorphous and semi-crystalline polymers and the semi-crystalline polymer forming the continuous polymeric phase.

Assignees

• Total Res & Technology Feluy

Inventors

• Lhost Olivier
• Rousseaux Dimitri

Classifications

• H01C7/027 Primary

  consisting of conducting or semi-conducting material dispersed in a non-conductive organic material · CPC title

• C08K3/046

  Carbon nanorods, nanowires, nanoplatelets or nanofibres · CPC title

• C08K3/041

  Carbon nanotubes · CPC title

• H01C17/06586

  composed of organic material · CPC title

• H01C17/0652

  containing carbon or carbides · CPC title