Polyoxymethylene compositions

Patent metadata

Field	Value
Publication number	US-10450456-B2
Application number	US-201715789203-A
Country	US
Kind code	B2
Filing date	Oct 20, 2017
Priority date	Nov 22, 2016
Publication date	Oct 22, 2019
Grant date	Oct 22, 2019

Abstract

Polyoxymethylene compositions, articles comprising these compositions, and processes of making the compositions, comprising: a) at least one polyoxymethylene polymer; b) about 0.1 to about 5 wt. % of poly alpha-1,3-glucan having a d90 particle size of 50 microns or less; c) optionally, at least one additive selected from the group consisting of nucleating agents, waxes, ultraviolet stabilizers, colorants, antioxidants, formaldehyde scavengers, lubricants, and mixtures of these; wherein an article molded from said polyoxymethylene composition exhibits a formaldehyde emission of 1 weight percent or less when measured according to TEF test method.

First claim

What is claimed is:

1. A polyoxymethylene composition comprising:
a) at least one polyoxymethylene polymer;
b) about 0.1 to about 5 wt. % of poly alpha-1,3-glucan having a d90 particle size of 50 microns or less;
c) optionally, at least one additive selected from the group consisting of nucleating agents, waxes, ultraviolet stabilizers, colorants, antioxidants, formaldehyde scavengers, lubricants, and mixtures of these;

wherein said polyoxymethylene composition exhibits a formaldehyde emission of 1 weight percent or less when measured according to the TEF test method; and
wherein said particle size is measured according to ISO 13320:2009.

2. The polyoxymethylene composition of claim 1 , wherein the formaldehyde emission is 0.7 weight percent or less.

3. The polyoxymethylene composition of claim 1 , wherein the formaldehyde emission is 0.6 weight percent or less.

4. The polyoxymethylene composition of claim 1 , wherein the at least one additive is present.

5. The polyoxymethylene composition of claim 4 , wherein the additive comprises a nucleating agent selected from the group consisting of titanium oxides, boron compounds, silica, silicates, montmorillonite, valentinite, pyrophyllite, dolomite, melamine-formaldehyde condensates, phyllosilicates, talc, sulfates, carbonates, terpolymers of trioxane, and mixtures of these.

6. The polyoxymethylene composition of claim 5 , wherein said carbonates is calcium carbonate.

7. The polyoxymethylene composition of claim 4 , wherein the additive comprises a formaldehyde scavenger selected from the group consisting of hydantoin compounds, imidazole compounds, and mixtures of these.

8. The polyoxymethylene composition of claim 4 , wherein the additive comprises an antioxidant selected from hindered phenol antioxidants.

9. The polyoxymethylene composition of claim 4 , wherein the additive comprises a lubricant.

10. The polyoxymethylene composition of claim 1 , wherein:
the polyoxymethylene polymer has a melt flow rate of from about 0.5 g/10 min. to about 100 g/10 min. when measured according to ISO 1133.

11. The polyoxymethylene composition of claim 1 wherein the polyoxymethylene polymer is a copolymer.

12. The polyoxymethylene composition of claim 1 wherein the polyoxymethylene polymer is a homopolymer.

13. An article comprising the polyoxymethylene composition of claim 1 .

14. The article of claim 13 in the form of gears, toys, cigarette lighter bodies, writing pen bodies, conveyor belt parts, safety restraint parts, car interior parts, automotive fasteners, retractors, sliding members, snap-fit buckles, and zippers.

15. A process of making a polyoxymethylene composition comprising the step of mixing:
a) at least one polyoxymethylene polymer;
b) about 0.1 to about 5 wt. % of poly alpha-1,3-glucan having a d90 particle size of 50 microns or less measured according to ISO 13320:2009;

c) optionally, at least one additive selected from the group consisting of nucleating agents, waxes, ultraviolet stabilizers, colorants, antioxidants, formaldehyde scavengers, lubricants, and mixtures of these;

to prepare a polyoxymethylene composition,
wherein said polyoxymethylene composition exhibits a formaldehyde emission of 1 weight percent or less when measured according to the TEF test method.

Assignees

• Du Pont

Inventors

• Ratnagiri Ramabhadra

Classifications

• C08L2205/24

  Crystallisation aids · CPC title

• C08L2205/14

  containing polymeric additives characterised by shape · CPC title

• C08L59/04

  Copolyoxymethylenes · CPC title

• C08L59/02

  Polyacetals containing polyoxymethylene sequences only · CPC title

• C08L59/00 Primary

  Compositions of polyacetals; Compositions of derivatives of polyacetals (of polyvinyl acetals C08L29/14) · CPC title