Method for purifying reclaimed polypropylene

Patent metadata

Field	Value
Publication number	US-10450436-B2
Application number	US-201715839906-A
Country	US
Kind code	B2
Filing date	Dec 13, 2017
Priority date	Dec 20, 2016
Publication date	Oct 22, 2019
Grant date	Oct 22, 2019

Abstract

A method for purifying a reclaimed polypropylene is provided. The method involves obtaining reclaimed polypropylene, contacting it with a first fluid solvent to produce an extracted reclaimed polypropylene then dissolving the extracted reclaimed polypropylene in a solvent to produce a first solution comprising polypropylene and suspended contaminants. The first solution is settled to produce a second solution comprising polypropylene and remaining contaminants. The second solution is purified by contacting the second solution with solid media to produce a third solution comprising purer polypropylene. Finally, the purer polypropylene is separated from the third solution.

First claim

What is claimed is:

1. A method for purifying a reclaimed polypropylene comprising:
a. Obtaining the reclaimed polypropylene wherein said reclaimed polypropylene is selected from the group consisting of post-consumer use polymers, post-industrial use polymers, and combinations thereof;
b. Contacting the reclaimed polypropylene at a temperature from about 80° C. to about 220° C. and at a pressure from about 150 psig (1.03 MPa) to about 15,000 psig (103.42 MPa) with a first fluid solvent having a standard boiling point less than about 70° C., to produce an extracted reclaimed polypropylene;
c. Dissolving the extracted reclaimed polypropylene in a solvent selected from the group consisting of the first fluid solvent, a second fluid solvent, and mixtures thereof, at a temperature from about 90° C. to about 220° C. and a pressure from about 350 psig (2.41 MPa) to about 20,000 psig (137.90 MPa) to produce a first solution comprising polypropylene and suspended contaminants;
d. Settling said first solution comprising polypropylene and suspended contaminants at a temperature from about 90° C. to about 220° C. and at a pressure from about 350 psig (2.41 MPa) to about 20,000 psig (137.90 MPa) to produce a second solution comprising polypropylene and remaining contaminants;
e. Purifying said second solution at a temperature from about 90° C. to about 220° C. and at a pressure from about 350 psig (2.41 MPa) to about 20,000 psig (137.90 MPa) by contacting said second solution with solid media to produce a third solution comprising purer polypropylene; and
f. Separating said purer polypropylene from said third solution;

wherein said second fluid solvent has the same chemical composition or a different chemical composition as the first fluid solvent.

2. The method of claim 1 , wherein said polypropylene is separated from said third solution at a temperature from about 0° C. to about 220° C. and a pressure from about 0 psig (0 MPa) to 2,000 psig (13.79 MPa).

3. The method of claim 1 , wherein said reclaimed polypropylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration of at least 0.5%.

4. The method of claim 1 , wherein said reclaimed polypropylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration of at least 1%.

5. The method of claim 1 , wherein said reclaimed polypropylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration of at least 2%.

6. The method of claim 1 , wherein said reclaimed polypropylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration of at least 3%.

7. The method of claim 1 , wherein said reclaimed polypropylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration of at least 4%.

8. The method of claim 1 , wherein said reclaimed polypropylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration of at least 5%.

9. The method of claim 1 , wherein said reclaimed polypropylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration up to 20%.

10. The method of claim 1 , wherein said reclaimed polypropylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration up to 18%.

11. The method of claim 1 , wherein said reclaimed polypropylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration up to 16%.

12. The method of claim 1 , wherein said reclaimed polypropylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration up to 14%.

13. The method of claim 1 , wherein said reclaimed polypropylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration up to 12%.

14. The method of claim 1 , wherein said reclaimed polypropylene is post-consumer recycle derived polypropylene.

15. The method of claim 1 , wherein said reclaimed polypropylene is a polypropylene homopolymer or a primarily polypropylene copolymer.

16. The method of claim 1 , wherein said fluid solvent has a standard boiling point less than about 0° C. and greater than about −45° C. and a standard enthalpy change of vaporization of less than about +25 kJ/mol.

17. The method of claim 1 , wherein said fluid solvent is selected from the group consisting of olefinic hydrocarbons, aliphatic hydrocarbons, and mixtures thereof.

18. The method of claim 17 , wherein said aliphatic hydrocarbon is selected from the group consisting of C 1 -C 6 aliphatic hydrocarbons and mixtures thereof.

19. The method of claim 17 , wherein said aliphatic hydrocarbons and mixtures thereof is comprised of primarily C 4 aliphatic hydrocarbons.

20. The method of claim 17 , wherein said fluid solvent consists essentially of C 4 liquefied petroleum gas.

21. The method of claim 17 , wherein said fluid solvent is n-butane, butane isomers, or mixtures thereof.

22. The method of claim 1 , wherein said temperature in the contacting, dissolving, settling and purification steps is from about 110° C. to about 170° C.

23. The method of claim 1 , wherein said pressure in the contacting step is from about 1,100 psig (7.58 MPa) to about 2,100 psig (14.48 MPa).

24. The method of claim 1 , wherein said pressure in the contacting step is less than about 1,100 psig (7.58 MPa).

25. The method of claim 1 , wherein said pressure in the dissolving, settling, and purification steps is greater than about 1,100 psig (7.58 MPa).

26. The method of claim 1 , wherein said pressure in the dissolving, settling, and purification steps is greater than about 2,100 psig (14.48 MPa).

27. The method of claim 1 , wherein said solid media is selected from the group consisting of inorganic substances, carbon-based substances, and mixtures thereof.

28. The method of claim 27 , wherein said inorganic substances are selected from the group consisting of oxides of silicon, oxides of aluminum, oxides of iron, aluminum silicates, amorphous volcanic glasses, and mixtures thereof.

29. The method of claim 27 , wherein said inorganic substances are selected from the group consisting of silica gel, diatomite, sand, quartz, alumina, perlite, fuller's earth, bentonite, and mixtures thereof.

30. The method of claim 27 , wherein said carbon-based substances are selected from the group consisting of anthracite coal, carbon black, coke, activated carbon, cellulose, and mixtures thereof.

31. The method of claim 1 , wherein said contacting of the polypropylene solution with said solid media is done in a packed bed of said solid media.

32. The method of claim 31 , where said packed bed is greater than 20 cm in length.

Assignees

• Procter & Gamble

Inventors

• Layman John Moncrief
• Collias Dimitris Ioannis
• Schonemann Hans
• Williams Kara

Classifications

• C08J2323/12

  Polypropene · CPC title

• C08J11/08 Primary

  using selective solvents for polymer components · CPC title

• C08J11/06

  without chemical reactions · CPC title

• Y02W30/701

  Cross-Sectional Technologies · mapped topic

• B29K2023/12

  PP, i.e. polypropylene · CPC title