Poly(meth)acrylimide film, easy-adhesion film using same, and method for manufacturing such films

Patent metadata

Field	Value
Publication number	US-10450431-B2
Application number	US-201414904025-A
Country	US
Kind code	B2
Filing date	Jun 11, 2014
Priority date	Jul 10, 2013
Publication date	Oct 22, 2019
Grant date	Oct 22, 2019

Abstract

Embodiments of the invention relate to a poly(meth)acrylimide film and a method for manufacturing such a film. At least one embodiment provides a poly(meth)acrylimide film that has (i) a total light transmittance of over 90% and (ii) haze of 2.0% or less. This film preferably has retardation of less than 50 nm. The method for manufacturing this film includes the following steps: (A) using a device provided with an extruder and a T die, a poly(meth)acrylimide molten film is continuously extruded from the T die; and (B) the poly(meth)acrylimide molten film is loaded by being fed between a rotating or circulating first mirrored-surface body and a rotating or circulating second mirrored-surface body, and then the film is pressed. During these steps, (C) the surface temperature of the first mirrored-surface body is in the range 100-200° C., and (D) the surface temperature of the second mirrored-surface body is in the range 20-200° C.

First claim

The invention claimed is:

1. A method for producing a poly(meth)acrylimide film, comprising the steps of:
continuously extruding, with an apparatus equipped with an extruder and a T die, a molten film of a poly(meth)acrylimide from the T die;
feeding and pressing the molten film of the poly(meth)acrylimide between a first rotating or circulating mirror-finished body and a second rotating or circulating mirror-finished body wherein the first mirror-finished body is a rotating mirror-finished roll, and the second mirror-finished body is a mirror-finished belt circulating along an outer peripheral surface of the mirror-finished roll; and
delivering the molten film to a following transfer roll while making the molten film to be held on the first rotating or circulating mirror-finished body,
wherein the first rotating or circulating mirror-finished body has a surface temperature of 100° C. or higher and 200° C. or lower,
wherein the second rotating or circulating mirror-finished body has a surface temperature of 20° C. or higher and less than 200° C., and wherein the surface temperature of the first rotating or circulating mirror-finished body is higher than the surface temperature of the second rotating or circulating mirror-finished body.

2. A method for producing an easily-adhesive poly(meth)acrylimide film, the method comprising the steps of:
(1) producing a poly(meth)acrylimide film by the method according to claim 1 ;
(2) subjecting at least one surface of the poly(meth)acrylimide film obtained in the step (1) to a corona discharge treatment; and
(3) forming, as an easily-adhesive surface, an anchor coat comprising a silane coupling agent having an amino group on the treated surface of the poly(meth)acrylimide film having been subjected to the corona discharge treatment in the step (2).

3. The method according to claim 1 , wherein the surface temperature of the first rotating or circulating mirror-finished body is 20 to 100° C. higher than the surface temperature of the second rotating or circulating mirror-finished body.

4. The method according to claim 2 , wherein the surface temperature of the first rotating or circulating mirror-finished body is 20 to 100° C. higher than the surface temperature of the second rotating or circulating mirror-finished body.

5. The method according to claim 1 , wherein the poly(meth)acrylimide has a glass transition temperature of 150° C. or higher.

6. The method according to claim 2 , wherein the poly(meth)acrylimide has a glass transition temperature of 150° C. or higher.

7. A method for producing a hard coat-laminated film, comprising the steps of:
(1) producing a poly(meth)acrylimide film by the method according to claim 1 ; and
(2) forming a hard coat on at least one surface of the poly(meth)acrylimide film obtained in the step (1).

8. A method for producing a hard coat-laminated film, comprising the steps of:
(1) producing an easily-adhesive poly(meth)acrylimide film by the method according to claim 2 ; and
(2) forming a hard coat on the easily-adhesive surface of the easily-adhesive poly(meth)acrylimide film obtained in the step (1).

9. A method for producing an image display apparatus, which comprises using installing, as a member of the image display apparatus, a poly(meth)acrylimide film obtained by the method according to claim 1 into the image display apparatus.

10. A method for producing an image display apparatus, which comprises installing, as a member of the image display apparatus, an easily-adhesive poly(meth)acrylimide film obtained by the method according to claim 2 into the image display apparatus.

Assignees

• Riken Technos Corp

Inventors

• Nakashima Kohei
• Yamada Kazutaka
• Sugimoto Hidemasa
• Zennyoji Yoshihiro

Classifications

• B29C48/41

  Intermeshing counter-rotating screws · CPC title

• B29C48/405

  Intermeshing co-rotating screws · CPC title

• C08J2333/24

  Homopolymers or copolymers of amides or imides · CPC title

• B29C59/10

  by electric discharge treatment · CPC title

• B29C48/918

  characterized by differential heating or cooling · CPC title