Saponified ethylene-vinyl ester copolymer pellet and method for producing saponified ethylene-vinyl ester copolymer pellet

Patent metadata

Field	Value
Publication number	US-10450426-B2
Application number	US-201415104409-A
Country	US
Kind code	B2
Filing date	Dec 22, 2014
Priority date	Dec 24, 2013
Publication date	Oct 22, 2019
Grant date	Oct 22, 2019

Abstract

The invention provides a saponified ethylene-vinyl ester copolymer pellet which can be inhibited from cracking, chipping and generation of fine powder at the time of transport and is excellent in melt moldability. The saponified ethylene-vinyl ester copolymer pellet of the invention is a pellet which is obtained from a resin composition containing a saponified ethylene-vinyl ester copolymer resin and in which an amount of fine powder after an impact crushing test with ball mill is 400 ppm or less with respect to the saponified ethylene-vinyl ester copolymer pellet.

First claim

The invention claimed is:

1. A saponified ethylene-vinyl ester copolymer pellet comprising a resin composition containing a saponified ethylene-vinyl ester copolymer resin having an ethylene unit content of from 20 mol % to 35 mol % and in which an amount of fine powder after an impact crushing test with ball mill is 400 ppm or less with respect to the saponified ethylene-vinyl ester copolymer pellet,
wherein the impact crushing test with ball mill comprises:
charging an alumina pot ball mill with a capacity of 1 L and an outer diameter of 140 mm with 230 g of saponified ethylene-vinyl ester copolymer pellets and 95 pieces of 15 mm diameter alumina balls and
rotating the charged alumina pot at 75 revolutions per minute for 30 minutes at an initial temperature of 20° C.

2. The saponified ethylene-vinyl ester copolymer pellet according to claim 1 , which is obtainable by extruding a solution of the saponified ethylene-vinyl ester copolymer resin into a coagulating liquid of 2.0° C. or less to obtain a coagulated strand and then cutting the coagulated strand to obtain the saponified ethylene-vinyl ester copolymer pellet.

3. The saponified ethylene-vinyl ester copolymer pellet according to claim 1 , which is cylindrical and has a diameter of the bottom surface of from 1 to 6 mm and a length of from 1 to 6 mm.

4. The saponified ethylene-vinyl ester copolymer pellet according to claim 2 , wherein the solution of a saponified ethylene-vinyl ester copolymer resin is the solution in which a saponified ethylene-vinyl ester copolymer resin is dissolved in a mixed solution having a mixing weight ratio of water/solvent from 80/20 to 5/95.

5. The saponified ethylene-vinyl ester copolymer pellet according to claim 2 , wherein a temperature at the time of extrusion of the solution of a saponified ethylene-vinyl ester copolymer resin into a coagulating liquid is from 45 to 70° C.

6. The saponified ethylene-vinyl ester copolymer pellet according to claim 2 , wherein the coagulating liquid is a water/alcohol mixed solution.

7. The saponified ethylene-vinyl ester copolymer pellet according to claim 2 which is obtainable by retaining the extruded saponified ethylene-vinyl ester copolymer resin into the coagulating liquid for 50 to 400 seconds.

8. A method for producing a saponified ethylene-vinyl ester copolymer pellet comprising a resin composition containing a saponified ethylene-vinyl ester copolymer resin having an ethylene unit content of from 20 mol % to 35 mol % and in which an amount of fine powder after an impact crushing test with ball mill is 400 ppm or less with respect to the saponified ethylene-vinyl ester copolymer pellet,
wherein the impact crushing test with ball mill comprises:
charging an alumina pot ball mill with a capacity of 1 L and an outer diameter of 140 mm with 230 g of saponified ethylene-vinyl ester copolymer pellets and 95 pieces of 15 mm diameter alumina balls and
rotating the charged alumina pot at 75 revolutions per minute for 30 minutes at an initial temperature of 20° C.;

wherein the method comprises extruding a solution of the saponified ethylene-vinyl ester copolymer resin into a coagulating liquid having a temperature of 2.0° C. or less to obtain a coagulated strand and then cutting the coagulated strand to obtain the saponified ethylene-vinyl ester copolymer pellet.

9. The method for producing a saponified ethylene-vinyl ester copolymer pellet according to claim 8 , wherein a solution in which the saponified ethylene-vinyl ester copolymer resin is dissolved in a mixed solution having a mixing weight ratio of water/solvent from 80/20 to 5/95 is extruded into the coagulating liquid.

10. The method for producing a saponified ethylene-vinyl ester copolymer pellet according to claim 8 , wherein a temperature at the time of extrusion of the solution of a saponified ethylene-vinyl ester copolymer resin into a coagulating liquid is from 45 to 70° C.

11. The method for producing a saponified ethylene-vinyl ester copolymer pellet according to claim 8 , wherein the coagulating liquid is a water/alcohol mixed solution.

12. The method for producing a saponified ethylene-vinyl ester copolymer pellet according to claim 8 , wherein a retention time of the saponified ethylene-vinyl ester copolymer resin in the coagulating liquid is from 50 to 400 seconds.

Assignees

• Nippon Synthetic Chem Ind Co Ltd
• Mitsubishi Chem Corp

Inventors

• FUKUYAMA Shuuichi
• Ono Atsushi
• Yamada Kouji
• Tanaka Shinichi
• Nagao Yoshiharu
• Miyazumi Shinta
• Honda Seiichi

Classifications

• C08J3/14

  by precipitation from solutions {(C08J3/122 takes precedence)} · CPC title

• B29B9/065

  under-water, e.g. underwater pelletizers · CPC title

• C08F16/06

  Polyvinyl alcohol {; Vinyl alcohol} · CPC title

• C08F8/12

  Hydrolysis · CPC title

• C08J2323/08

  Copolymers of ethene (C08J2323/16 takes precedence) · CPC title