Process for producing dispersion of esterified cellulose ether

Patent metadata

Field	Value
Publication number	US-10450424-B2
Application number	US-201615746207-A
Country	US
Kind code	B2
Filing date	Jul 8, 2016
Priority date	Jul 28, 2015
Publication date	Oct 22, 2019
Grant date	Oct 22, 2019

Abstract

A process for producing an aqueous composition comprising a dispersed esterified cellulose ether comprises the steps of grinding, in the presence of an aqueous diluent an esterified cellulose ether comprising (i) groups of the formula —C(O)—R—COOA or (ii) a combination of aliphatic monovalent acyl groups and groups of the formula —C(O)—R—COOA, wherein R is a N divalent aliphatic or aromatic hydrocarbon group and A is hydrogen or a cation, blending a salt of a fatty acid with the esterified cellulose ether and choosing the amounts of aqueous diluent, esterified cellulose ether and salt of a fatty acid that the produced aqueous composition comprises at least 20 percent of the dispersed esterified cellulose ether and heating the aqueous composition to a temperature of from 37 to 80 C during or after the grinding step.

First claim

The invention claimed is:

1. A process for producing an aqueous composition comprising a dispersed esterified cellulose ether comprising the steps of
grinding, in the presence of an aqueous diluent, at least one esterified cellulose ether comprising (i) groups of the formula —C(O)—R—COOA or (ii) a combination of aliphatic monovalent acyl groups and groups of the formula —C(O)—R—COOA, wherein R is a divalent aliphatic or aromatic hydrocarbon group and A is hydrogen or a cation,
blending at least one salt of a fatty acid and optionally one or more adjuvants with the esterified cellulose ether before, during or after the grinding of the esterified cellulose ether and choosing the amounts of aqueous diluent, esterified cellulose ether, salt of a fatty acid, and optionally one or more adjuvants that the produced aqueous composition comprises at least 25 percent of the dispersed esterified cellulose ether, based on the total weight of the aqueous composition, and
heating the aqueous composition to a temperature of from 37 to 80° C. during or after the grinding step.

2. The process of claim 1 wherein additionally an anionic surfactant comprising a sulfate or sulfonate group is blended with the esterified cellulose ether before, during or after the grinding of the esterified cellulose ether.

3. The process of claim 1 wherein the aqueous composition is heated to a temperature of from 40 to 70° C.

4. The process of claim 3 wherein the aqueous composition is heated to a temperature of from 40 to 55° C.

5. The process of claim 1 , wherein the aqueous composition is heated during a time period of at least 30 minutes.

6. The process of claim 1 , wherein the median particle size, d50, of the dispersed esterified cellulose ether particles is up to 7 micrometers, the median particle size, d50, being the size at which 50 volume percent of the particles have a smaller equivalent diameter and 50 volume percent have a larger equivalent diameter.

7. The process of claim 1 wherein the aqueous composition comprises at least 30 weight percent of said at least one dispersed esterified cellulose ether, based on the total weight of the aqueous composition.

8. The process of claim 1 wherein the aliphatic monovalent acyl groups in the esterified cellulose ether are acetyl, propionyl or butyryl groups, and the groups of the formula —C(O)—R—COOA are —C(O)—CH2-CH2-COOA, —C(O)—CH═CH—COOA, or —C(O)—C6H4-COOA groups.

9. The process of claim 1 wherein the esterified cellulose ether is hydroxypropyl methyl cellulose acetate succinate.

10. The process of claim 1 wherein the amount of the salt of a fatty acid is from 0.05 to 20 percent, based on the weight of the esterified cellulose ether.

11. The process of claim 1 wherein the salt of a fatty acid is an alkali metal or alkaline earth metal salt of stearic acid.

12. The process of claim 1 wherein the anionic surfactant comprising a sulfate or sulfonate group is a dialkyl sulfosuccinate.

13. The process of claim 1 wherein a film forming aid is added to the aqueous composition after heating the aqueous composition to a temperature of from 37 to 80° C.

Assignees

• Dow Global Technologies Llc

Inventors

• Brackhagen Meinolf
• Fetner Neal J
• Knarr Matthias
• Zhao Jin

Classifications

• C08B13/00

  Preparation of cellulose ether-esters · CPC title

• A61K47/38

  Cellulose; Derivatives thereof · CPC title

• C08L1/32 Primary

  Cellulose ether-esters · CPC title

• C09D101/32

  Cellulose ether-esters · CPC title

• C08J2301/32

  Cellulose ether-esters · CPC title