Polymer powder and method for preparing same

Patent metadata

Field	Value
Publication number	US-10450409-B2
Application number	US-201515515583-A
Country	US
Kind code	B2
Filing date	Sep 25, 2015
Priority date	Sep 29, 2014
Publication date	Oct 22, 2019
Grant date	Oct 22, 2019

Abstract

Disclosed is a polymer powder having an average particle diameter of 20 μm to 300 μm, with a particle diameter of less than 10 μm of 10 mass % or less, and a particle diameter of greater than 300 μm of 10 mass % or less. Further, disclosed is a method for preparing a polymer powder, comprising: forming a melt of a polymer; introducing a supercritical fluid into the melt of the polymer to form a mixed composition; and spraying the mixed composition to prepare the polymer powder.

First claim

The invention claimed is:

1. A polylactic acid powder having an average particle diameter of 20 μm to 300 μm, with a particle diameter of less than 10 μm of 10 mass % or less, and a particle diameter of greater than 300 μm of 10 mass % or less,
wherein a weight average molecular weight (Mw) of the polylactic acid powder ranges from 10,000 to 300,000, and
wherein the polylactic acid powder has an angle of repose of less than 45 degrees.

2. A polylactic acid powder, wherein:
an average particle diameter of the polylactic acid powder ranges from 20 μm to 300 μm,
an amount of particles having a particle diameter of less than 10 μm in the polylactic acid powder is 10 mass % or less, and
an amount of particles having a particle diameter of greater than 300 μm in the polylactic acid powder is 10 mass % or less,
a weight average molecular weight (Mw) of the polylactic acid powder ranges from 10,000 to 300,000,
an angle of repose of the polylactic acid powder is less than 45 degrees, and
the polylactic acid powder is prepared by a method, comprising:
forming a melt of a polylactic acid;
introducing a supercritical fluid into the melt of the polylactic acid to form a mixed composition; and
spraying the mixed composition to prepare the polylactic acid powder,
wherein the step of forming the mixed composition comprises introducing the supercritical fluid into the melt of the polylactic acid, followed by pressurizing to disperse the supercritical fluid in the melt of the polylactic acid.

3. A method for preparing the polymer power according to claim 1 , comprising:
forming a melt of a polymer,
introducing a supercritical fluid into the melt of the polymer to form a mixed composition; and
spraying the mixed composition to prepare the polymer powder,
wherein forming the mixed composition comprises introducing the supercritical fluid into the melt of the polymer, and dispersing the supercritical fluid in the melt of the polymer by pressurizing the melt of the polymer and the supercritical fluid.

4. The method of claim 3 , wherein the melt of the polymer is formed by melting the polymer at 100° C. to 290° C.

5. The method of claim 3 , wherein the step of forming the mixed composition comprises introducing the supercritical fluid into the melt of the polymer and then pressurizing to a pressure of 50 bars to 500 bars.

6. The method of claim 3 , wherein the mixed composition is formed by introducing 5 to 15 parts by weight of the supercritical fluid based on 100 parts by weight of the melt of the polymer.

7. The method of claim 3 , wherein the supercritical fluid comprises at least one selected from the group consisting of carbon dioxide, helium, nitrogen, methane, ethane, propane, ethylene, propylene, methylene, and combinations thereof.

8. The method of claim 3 , wherein the mixed composition has a viscosity of 10 −3 Pa·s to 10 3 Pa·s.

9. The method of claim 3 , wherein the step of spraying the mixed composition to prepare a polymer powder comprises spraying the mixed composition through a nozzle having an average diameter of 0.01 to 3.0 mm.

10. The method of claim 3 , wherein the step of spraying the mixed composition to prepare a polymer powder comprises cooling the mixed composition at −30° C. to 30° C. simultaneously with spraying.

11. The method of claim 3 , wherein the difference in weight average molecular weight (Mw) between the polymer and the polymer powder is 200,000 or less.

12. The method of claim 3 , wherein the difference in thermal decomposition temperature between the polymer and the polymer powder is 50° C. or less.

13. The method of claim 3 , wherein introducing the supercritical fluid into the melt of the polymer comprises:
introducing the melt of the polylactic acid at a rate ranging from 2 to 100 rpm; and
injecting the supercritical fluid into the melt of the polylactic acid at a flow rate ranging from 0.01 to 40 g/L, and
wherein the method further comprises, prior to spraying the mixed composition, injecting air into the mixed composition, wherein a temperature of the injected air ranges from 200° C. to 500° C., a pressure of the injected air ranges from 100 psi to 1000 psi, and an injection rate of the air ranges from 10 m/s to 50 m/s.

Assignees

• Lg Hausys Ltd

Inventors

• Kang Kyoung-Min
• Kang Sung-Yong
• Shin Jun-Beom
• Hwang Deok-Ryul

Classifications

• C08J2367/04

  Polyesters derived from hydroxy carboxylic acids, e.g. lactones (C08J2367/06 takes precedence) · CPC title

• C08J3/122 Primary

  Pulverisation by spraying · CPC title

• C08J2300/22

  Thermoplastic resins · CPC title

• C08L101/00

  Compositions of unspecified macromolecular compounds · CPC title

• C08G63/88

  Post-polymerisation treatment · CPC title