Direct alkoxylation of bio-oil
US-2017355927-A1 · Dec 14, 2017 · US
US10450402B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10450402-B2 |
| Application number | US-201816007441-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 13, 2018 |
| Priority date | May 25, 2007 |
| Publication date | Oct 22, 2019 |
| Grant date | Oct 22, 2019 |
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An isocyanate reactive composition for making a polyurethane foam includes a tertiary amine urethane catalyst comprising a di(C1-C4)alkyl fatty alkyl amine and a polyester polyol. The use of one or more of fatty alkyl tertiary amine serves to reduce hydrolysis of the polyester polyol in the isocyanate reactive composition.
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The invention claimed is: 1. A method of making a polyurethane spray rigid foam, the method comprising combining a polyisocyanate and an isocyanate reactive composition comprising a polyester polyol, water and a urethane catalyst composition comprising 10 to 40 wt % pentamethyldiethylenetriamine, 20 to 80 wt % tris(dimethylaminopropyl) amine and 10 to 50 wt % dimethylhexadecyl amine. 2. The method of claim 1 , wherein the isocyanate reactive composition further comprises a fire retardant. 3. The method of claim 2 , wherein the isocyanate reactive composition further comprises a Mannich polyol. 4. The method of claim 3 , wherein the urethane catalyst composition comprises at least one other tertiary amine urethane catalyst. 5. The method of claim 3 , wherein the isocyanate reactive composition further comprises one or more blowing agents. 6. The method of claim 1 , wherein the isocyanate reactive composition further comprises at least one member selected from the group consisting of cell stabilizers, crosslinking agents, chain extenders, pigments, and fillers. 7. The method of claim 6 , wherein the chain extenders comprise at least one of ethylene glycol and 1,4-butanediol.
having alkylene polyamine groups · CPC title
containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 · CPC title
Oxyalkylated polycondensates of aldehydes · CPC title
containing secondary or tertiary amines or salts thereof · CPC title
Manufacture of cellular products · CPC title
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