Processes and systems for removing an alkyl iodide impurity from a recycle gas stream in the production of ethylene oxide

Patent metadata

Field	Value
Publication number	US-10450287-B2
Application number	US-201616061787-A
Country	US
Kind code	B2
Filing date	Dec 13, 2016
Priority date	Dec 15, 2015
Publication date	Oct 22, 2019
Grant date	Oct 22, 2019

Abstract

Processes for reducing the amount of a gaseous iodide-containing impurity present in a recycle gas stream used in the production of ethylene oxide, in particular an alkyl iodide impurity, are provided. Processes for producing ethylene oxide, ethylene carbonate and/or ethylene glycol, and associated reaction systems are similarly provided.

First claim

That which is claimed is:

1. A process comprising:
contacting at least a portion of a recycle gas stream comprising an alkyl iodide impurity with a guard bed material to yield a treated recycle gas stream, wherein the guard bed material comprises a spherical support material having a diameter of less than 2 mm, and deposited on the spherical support material, silver in an amount of from 2% to 10% by weight; and
contacting an epoxidation feed gas comprising ethylene, oxygen and at least a portion of the treated recycle gas stream with an epoxidation catalyst to yield an epoxidation reaction product comprising ethylene oxide.

2. The process of claim 1 , further comprising:
contacting at least a portion of the epoxidation reaction product comprising ethylene oxide with a lean absorbent in the presence of an iodide-containing carboxylation catalyst to yield a fat absorbent stream comprising ethylene carbonate and/or ethylene glycol and the recycle gas stream comprising the alkyl iodide impurity.

3. The process of claim 1 , wherein silver is present in the guard bed material in an amount of from 3% to 9% by weight.

4. The process of claim 1 , wherein silver is present in the guard bed material in an amount of from 4% to 8% by weight.

5. The process of claim 1 , wherein the guard bed material further comprises at least one metal selected from the group consisting of an alkali metal, an alkaline earth metal, and a combination thereof.

6. The process of claim 5 , wherein the at least one metal is an alkali metal selected from the group consisting of sodium, potassium, lithium, rubidium, cesium, and combinations thereof.

7. The process of claim 5 , wherein the alkali metal is present in the guard bed material in an amount of from 0.1% to 5% by weight.

8. The process of claim 1 , wherein the spherical support material comprises alumina.

9. The process of claim 1 , wherein the spherical support material has a diameter of from 0.25 mm to 1.5 mm.

10. The process of claim 1 , wherein the spherical support material has a surface area of at least 50 m 2 /g.

11. The process of claim 1 , wherein the treated recycle gas stream comprises no more than 6 ppbv of alkyl iodide.

12. The process of claim 1 , wherein the treated recycle gas stream comprises no more than 1 ppbv of alkyl iodide.

13. The process of claim 1 , wherein the treated recycle gas stream is supplied to a carbon dioxide absorber before being contacted with the epoxidation catalyst.

14. A reaction system for the production of ethylene carbonate and/or ethylene glycol comprising:
a recycle gas loop fluidly connected to a source of ethylene and oxygen;

an epoxidation reactor comprising an epoxidation catalyst, an inlet, and an outlet, wherein the inlet of the epoxidation reactor is fluidly connected to the recycle gas loop;
an ethylene oxide absorber comprising an iodide-containing carboxylation catalyst, an inlet, and an outlet, wherein the outlet of the epoxidation reactor is fluidly connected to the inlet of the ethylene oxide absorber, the outlet of the ethylene oxide absorber is fluidly connected to the recycle gas loop, and the ethylene oxide absorber is configured to produce a recycle gas stream comprising an alkyl iodide impurity and a fat absorbent stream comprising ethylene carbonate and/or ethylene glycol; and
a guard bed system comprising an inlet, an outlet, and one or more guard bed vessels comprising a guard bed material, wherein the guard bed material comprises a spherical support material having a diameter of less than 2 mm, and deposited on the spherical support material, silver in an amount of from 2% to 10% by weight, wherein the inlet and the outlet of the guard bed system is fluidly connected to the recycle gas loop, and the guard bed material is configured to remove at least a portion of the alkyl iodide impurity from at least a portion of the recycle gas stream.

15. The reaction system of claim 14 , further comprising a carbon dioxide absorber fluidly connected to the recycle gas loop.

16. The reaction system of claim 14 , wherein the guard bed system comprises two or more guard bed vessels.

Assignees

• Shell Oil Co

Inventors

• Evans Wayne Errol
• Black Jesse Raymond

Classifications

• C07C29/12

  of esters of mineral acids · CPC title

• C07C17/38

  Separation; Purification; Stabilisation; Use of additives · CPC title

• C07C17/389

  by adsorption on solids · CPC title

• C07D301/32 Primary

  Separation; Purification · CPC title

• C07D303/04

  containing only hydrogen and carbon atoms in addition to the ring oxygen atoms · CPC title