Process for the production of glycols

Patent metadata

Field	Value
Publication number	US-10450249-B2
Application number	US-201716322568-A
Country	US
Kind code	B2
Filing date	Aug 2, 2017
Priority date	Aug 4, 2016
Publication date	Oct 22, 2019
Grant date	Oct 22, 2019

Abstract

The invention provides a process for the preparation of glycols from a saccharide-containing feedstock in a reactor system, said process comprising: i) providing a first feed stream comprising said saccharide-containing feedstock in a first solvent at a N temperature of no more than 160° C.; ii) providing a second feed stream comprising a tungsten-based retro-aldol catalytic species and an alkali metal containing species in a second solvent at a temperature in the range of from 150 to 250° C.; iii) combining the first feed stream and the second feed stream, before they are provided to the reactor system, to form a combined feed stream; iv) providing the combined feed stream to the reactor system and operating the reactor at a temperature in the range of from 150° C. to 250° C.; and v) also contacting the combined feed stream with a hydrogenation catalytic species in the presence of hydrogen, wherein the molar ratio of alkali metal:tungsten in the combined feed stream is in the range of from 0.55 to 6.

First claim

The invention claimed is:

1. A process for the preparation of glycols from a saccharide-containing feedstock in a reactor system, said process comprising:
i) providing a first feed stream comprising said saccharide-containing feedstock in a first solvent at a temperature of no more than 160° C.;
i) providing a second feed stream comprising a tungsten-based retro-aldol catalytic species and an alkali metal containing species in a second solvent at a temperature in the range of from 150 to 250° C.;
iii) combining the first feed stream and the second feed stream, before they are provided to the reactor system, to form a combined feed stream;
iv) providing the combined feed stream to the reactor system and operating the reactor at a temperature in the range of from 150° C. to 250° C.; and
v) also contacting the combined feed stream with a hydrogenation catalytic species in the presence of hydrogen, wherein the molar ratio of alkali metal:tungsten in the combined feed stream is in the range of from 0.55 to 6.

2. The process as claimed in claim 1 , wherein the alkali metal in the alkali metal containing species is sodium.

3. The process as claimed in claim 1 , wherein the temperature of the first feed stream is maintained such that no more than 5 wt % of the saccharide contained therein undergoes any conversion, prior to the first feed stream being combined with the second feed stream.

4. The process as claimed in claim 1 , wherein the combined feed stream is maintained at a temperature such that, when the combined feed stream is provided to the reactor system, in the range of from 0.5 to 50 wt % of the saccharide has undergone conversion.

5. The process as claimed in claim 1 , wherein the molar ratio of alkali metal:tungsten in the combined feed stream is in the range of from 0.55 to 3.

6. The process as claimed in claim 1 , wherein a product stream is removed from the reactor system and said product stream is separated into at least a glycol product stream and a hydrocarbon heavies stream.

7. The process as claimed in claim 6 , wherein at least a portion of the hydrocarbon heavies stream is recycled to form at least a portion of the second feed stream.

8. The process as claimed in claim 1 , wherein the pH in the reactor system is at least 2.0 and at most 8.0 and is maintained by using a buffer.

9. The process as claimed in claim 1 , wherein the alkali metal containing species is present as or derived from the buffer and/or the tungsten-based retro-aldol catalytic species present in the reactor system.

10. The process as claimed in claim 1 , wherein hydrogen is provided to the reactor system and not to the first feed stream, the second feed stream or the combined feed stream.

Assignees

• Shell Oil Co

Inventors

• Van Der Heide Evert
• Huizenga Pieter
• De Vlieger Dionysius Jacobus Maria

Classifications

• C07C31/205

  1,3-Propanediol; 1,2-Propanediol · CPC title

• B01J23/04

  Alkali metals · CPC title

• C07C31/202

  Ethylene glycol · CPC title

• C07C29/76

  by physical treatment · CPC title

• C07C29/132 Primary

  by reduction of an oxygen containing functional group · CPC title