Process for preparing a composite material from an organic liquid and resulting material

Patent metadata

Field	Value
Publication number	US-10450231-B2
Application number	US-201314429751-A
Country	US
Kind code	B2
Filing date	Sep 19, 2013
Priority date	Sep 21, 2012
Publication date	Oct 22, 2019
Grant date	Oct 22, 2019

Abstract

The present invention relates to a method for preparing a composite material from an organic liquid, consisting of preparing a geopolymer by dissolution/polycondensation of an aluminosilicate source in an activation solution comprising said organic liquid. The present invention also relates to the thereby prepared composite material.

First claim

The invention claimed is:

1. A method for preparing a composite material from an organic liquid, comprising:
preparing a geopolymer by dissolution/polycondensation of at least one aluminosilicate source in an activation solution including said organic liquid,
said organic liquid representing 20% to 70% by volume based on a total volume of said composite material,
said organic liquid including at most 50% by mass of triglycerides based on a total dry mass of said organic liquid, and
wherein said preparing the geopolymer includes
a) preparing the activation solution including said organic liquid and at least one surfactant, said surfactant being present in a proportion of 1% to 10% based on a total volume of the activation solution,
b) adding the at least one aluminosilicate source to the activation solution in step (a) to obtain a mixture, and
c) subjecting the mixture in step (b) to conditions allowing hardening of the geopolymer,
wherein said composite material is a geopolymeric matrix in which at least one of microbeads and nanobeads of said organic fluid are trapped or coated, and
wherein said organic liquid comprises at least one compound selected from the group consisting of a commercial scintillator liquid, benzene, toluene, xylene, ethylbenzene, kerosene, hexane, cyclohexane, octane, ethylcyclohexane, dodecane, eicosane, phenol, dichloromethane, trichloroethane, dichlorobenzene, trichloroethylene, 2-octane, 4-dodecanone, tributyl phosphate (TBP), tetrahydrofurane (THF), and diethyl ether.

2. The method according to claim 1 , wherein said organic liquid is in a supported form.

3. The method according to claim 2 , wherein said supported form is earth, sand, clay, rubble, granulate, gravel, or one of their mixtures.

4. The method according to claim 1 , wherein said organic liquid comprises at least one of a heavy metal, a trace element, or a radioelement.

5. The method according to claim 1 , wherein said activation solution contains at least one silicate component selected from the group consisting of silica, colloidal silica, and glassy silica.

6. The method according to claim 1 ,
wherein the activation solution/MK mass ratio with an activation solution term representing the mass of activation solution containing the organic liquid (expressed in g) and MK representing the aluminosilicate source mass (expressed in g) used is between 0.6 and 2.

7. The method according to claim 1 ,
wherein the activation solution/MK mass ratio with an activation solution term representing the mass of activation solution containing the organic liquid (expressed in g) and MK representing the aluminosilicate source mass (expressed in g) used is between 1 and 1.5.

8. The method according to claim 6 ,
wherein the activation solution/MK mass ratio with the activation solution term representing the mass of activation solution containing the organic liquid and a surfactant (expressed in g) and MK representing the aluminosilicate source mass (expressed in g) used is between 1 and 1.5.

9. The method according to claim 1 , wherein, in addition to the at least one aluminosilicate source, sand, granulate, and/or fines are added to the activation solution during said step (b).

10. The method according to claim 1 , wherein the conditions allowing hardening during said step (c) comprise a curing step.

11. The method according to claim 10 , wherein the curing step is followed by a drying step.

12. A method for treatment and/or inertization of an organic liquid, comprising:
preparing the composite material from said organic liquid according to the method as defined in claim 1 .

Assignees

• Commissariat Energie Atomique

Inventors

• Lambertin David
• Rooses Adrien
• Frizon Fabien

Classifications

• C04B40/0039

  Premixtures of ingredients · CPC title

• C04B28/006 Primary

  containing mineral polymers, e.g. geopolymers of the Davidovits type · CPC title

• C04B40/0046

  characterised by their processing, e.g. sequence of mixing the ingredients when preparing the premixtures · CPC title

• C04B2111/00767

  for waste stabilisation purposes · CPC title

• Y02W30/91

  Use of waste materials as fillers for mortars or concrete · CPC title