Coated article with sequentially activated low-E coatings, and/or method of making the same

Patent metadata

Field	Value
Publication number	US-10450224-B2
Application number	US-201816021210-A
Country	US
Kind code	B2
Filing date	Jun 28, 2018
Priority date	Jun 19, 2015
Publication date	Oct 22, 2019
Grant date	Oct 22, 2019

Abstract

Certain example embodiments relate to coated articles with sequentially activated low-E coatings, and/or methods of making the same. In certain example embodiments, one or more infrared reflecting layers is/are activated via a non-equilibrium preconditioning activation that uses photons with specific frequencies/frequency ranges, followed by a more equilibrium thermal activation. The preconditioning activation aids in rearranging the silver atoms to energetically favorable positions, while helping to avoid their unwanted agglomeration. The more equilibrium thermal stage of activation aids in aligning the chemical potentials of the layers of the stack and in further densification of the preconditioned silver layer. Doing so, in turn, helps to reduce the likelihood of stresses building-up in the coating, the formation of point and dimensional defects, other unwanted efficiency-reducing phenomena, and/or the like. Advantageously, emissivity can be lowered to a value lower than that achievable using conventional thermal, flash, and laser scanning, approaches alone.

First claim

What is claimed is:

1. A method of making a coated article including a multilayer thin film low-emissivity (low-E) coating supported by a glass substrate, the method comprising:
forming the low-E coating on the substrate, the low-E coating including at least first and second infrared (IR) reflecting layers comprising silver, each of the first and second IR reflecting layers being sandwiched between one or more dielectric layers, the first IR reflecting layer being farther from the substrate than the second IR reflecting layer; and
activating each of the IR reflecting layers using a two-stage treatment,
the first stage in the treatment preconditioning the IR reflecting layers via flash light source exposure in at least first and second wavelength ranges, the first wavelength range preferentially transmitting energy to the first IR reflecting layer and the second wavelength range preferentially transmitting energy to the second IR reflecting layer, and
the second stage in the treatment being a thermal treatment that is performed after all of the IR reflecting layers have been deposited, directly or indirectly, on the substrate, the second stage following the first stage.

2. The method of claim 1 , wherein the first stage in the treatment includes photons with energies of 0.82-3.55 eV.

3. The method of claim 2 , wherein the second stage in the treatment includes a temperature of 400-650 degrees C.

4. The method of claim 1 , wherein the second stage in the treatment includes a temperature of 400-650 degrees C.

5. The method of claim 1 , wherein the emissivity of the coating, following the two-stage treatment, is 0.011 or lower.

6. The method of claim 1 , wherein:
first and second seed layers are provided below and contacting the first and second IR reflecting layers, respectively; and
first and second capping layers are provided over and contacting the first and second IR reflecting layers, respectively.

7. The method of claim 6 , wherein:
photons in the first wavelength range preferentially transmit energy to the first seed layer, the first IR reflecting layer, and/or the first capping layer; and
photons in the second wavelength range preferentially transmit energy to the second seed layer, the second IR reflecting layer, and/or the second capping layer.

8. The method of claim 6 , wherein:
light energy in the first wavelength range is preferentially absorbed by the first seed layer and/or the first capping layer, and is delivered via acoustic photons to the first IR reflecting layer; and
light energy in the second wavelength range is preferentially absorbed by the second seed layer and/or the capping layer, and is delivered via acoustic photons to the second IR reflecting layer.

9. The method of claim 6 , wherein the first and second seed layers each comprise Zn and the first and second capping layers each comprise Ni, Ti, and/or Cr.

10. The method of claim 1 , wherein:
the preconditioning includes rearranging silver atoms in the first and second IR reflecting layers to more energetically favorable positions; and
the thermal treatment aligns chemical potentials of at least some layers in the layer stack and further densities the preconditioned first and second IR reflecting layers.

11. The method of claim 1 , wherein the first stage is performed each time one of the IR reflecting layers is deposited, directly or indirectly, on the substrate, and prior to the subsequent IR reflecting layer being deposited.

12. The method of claim 11 , wherein the first and second wavelength ranges are the same.

13. The method of claim 11 , wherein the preconditioning of each of the IR reflecting layers is performed after the respective IR reflecting layer is covered with the one or more dielectric layers.

14. The method of claim 1 , wherein the first stage is performed after all of the IR reflecting layers are deposited, the first and second wavelength ranges being different from one another.

15. The method of claim 14 , wherein the first wavelength range has a maximum intensity in a first area proximate to a maximum absorptivity of the first IR reflecting layer and the second wavelength range has a maximum intensity in a second area that is remote from the first area and where the absorptivity of the first IR reflecting layer is less than one-half of its maximum.

16. The method of claim 14 , wherein the first wavelength range has a maximum intensity in the 700-900 nm spectral range and the second wavelength range has a maximum intensity in the 600-700 nm spectral range.

17. The method of claim 14 , wherein:
the low-E further includes a third IR reflecting layer comprising silver, the third IR reflecting layer also being sandwiched between one or more dielectric layers, the third IR reflecting layer being farther from the substrate than the first IR reflecting layer, and
the first stage further includes flash light source exposure with a third wavelength range that preferentially transmits energy to the third IR reflecting layer.

18. The method of claim 17 , wherein the first, second, and third wavelength ranges are all different from one another and have respective maximum intensities in the 600-700 nm, 400-600 nm, and 700-900 nm spectral ranges.

19. The method of claim 14 , wherein the flash light source exposures that generate the first and second wavelength ranges are formed by time-separated sub-pulses of different waveforms.

20. The method of claim 14 , wherein the flash light source exposures that generate the first and second wavelength ranges are formed by different flash bulbs.

21. The method of claim 1 , wherein the first stage is performed after all of the IR reflecting layers are deposited, and wherein the first IR reflecting layer is preconditioned using a first light source provided over the substrate and the second IR reflecting layer is preconditioned using a second light source provided under the substrate.

22. The method of claim 1 , wherein the low-E coating is formed in whole or in part by room temperature sputtering.

Assignees

• Guardian Glass Llc
• Guardian Europe Sarl

Inventors

• Krasnov Alexey
• Lage Herbert
• Lemmer Jean-Marc

Classifications

• C03C17/36 Primary

  at least one coating being a metal · CPC title

• C03C23/001

  by infrared light · CPC title

• C03C17/3652

  the coating stack containing at least one sacrificial layer to protect the metal from oxidation · CPC title

• C03C23/007

  by thermal treatment · CPC title

• C03C2218/154

  by sputtering · CPC title