Process and composition for preparation of cracking catalyst suitable for enhancing LPG

Patent metadata

Field	Value
Publication number	US-10449524-B2
Application number	US-201615237121-A
Country	US
Kind code	B2
Filing date	Aug 15, 2016
Priority date	Aug 24, 2015
Publication date	Oct 22, 2019
Grant date	Oct 22, 2019

Abstract

The present invention relates to a catalyst product for cracking of heavy hydrocarbon feed stocks predominantly in to light olefins and processes for preparing the catalyst. More specifically the present invention relates to a process of preparing Fluidic Catalytic Cracking (FCC) catalyst additive composition. The FCC catalyst additive composition of the present invention is a LPG selective catalyst particles comprising a medium pore zeolite bonded with clay-phosphate-silica-alumina binder. The catalyst of the present invention exhibits improved selectivity towards high value components like propylene and gasoline and suppressing low value components like dry gas and bottoms.

First claim

The invention claimed is:

1. A process for preparing a Fluidic Catalytic Cracking (FCC) catalyst additive composition for cracking heavy hydrocarbon, said process comprising the steps of:
(a) slurrying of an initial FCC catalyst additive in demineralised water at a temperature of 25° C. to 99° C. for 30 mins. to 2 hrs for solubilising excess phosphate present in the initial FCC catalyst additive; wherein the initial FCC catalyst additive comprises: (a) zeolite from 1 wt % to 65 wt %; (b) clay from 10 wt % to 75 wt %; (c) silica from 25 wt % to 80 wt %; (d) alumina from 20 wt % to 70 %; and (e) phosphate from 5 wt % to 25 wt %;
(b) filtering the slurry of step (a) and obtaining phosphate depleted FCC catalyst additive;
(c) drying and calcinating the FCC catalyst additive of step (b);
(d) dispersing the FCC catalyst additive of step (c) in a solution of bivalent metals selected from the group consisting of Group IIA or Group IB at a temperature of 60-80° C. for exchanging or replacing zeolite acid sites of said FCC catalyst additive by the bivalent metal, wherein the bivalent metal generates moderate acid sites on the FCC catalyst additive of step (c);
(e) filtering the additive from step (d);
(f) drying and calcinating the metal exchanged FCC catalyst additive of step (e); and
(g) obtaining the FCC catalyst additive composition.

2. The process as claimed in claim 1 , wherein step (a) is carried out at a temperature of 80° C. for 2 hrs.

3. The process as claimed in claim 1 , wherein the initial FCC catalyst additive is a pentasil family zeolite selected from ZSM-5, ZSM-11, ZSM-12, ZSM-23, ZSM-35, ZSM-38, ZSM-48, ZSM-57, Zeolite beta, and mordenite.

4. The process as claimed in claim 1 , wherein the FCC catalyst additive composition obtained in step (g) is:
(a) zeolite from 1 wt % to 65 wt %; (b) clay from 10 wt % to 75 wt %; (c) silica from 25 wt % to 80 wt %; (d) alumina from 20 wt % to 70 wt %; (e) phosphate from 4 wt % to 23 wt % ; and (f) Group-IIA or Group TB bivalent metals from 0.1 to 1 wt %.

5. The process as claimed in claim 1 , wherein in step (d) the concentration of bivalent metal exchanged on acid sites of zeolite sites of FCC catalyst additive is in the range of 0.1 to 1 wt % of bivalent metal.

Assignees

• Indian Oil Corp Ltd

Inventors

• Kuvettu Mohan Prabhu
• Kadgaonkar Mahesh
• Sarkar Biswanath
• Chidambaram Velusamy
• Karthikeyani Arumugam Velayutham
• PULIKOTTIL Alex
• Christopher Jayaraj
• Kumar Brijesh
• Das Biswapriya

Classifications

• B01J37/0045

  Drying a slurry, e.g. spray drying · CPC title

• B01J37/28

  Phosphorising · CPC title

• B01J2229/20

  to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself · CPC title

• B01J2229/186

  not in framework positions · CPC title

• B01J29/24

  Iron group metals or copper · CPC title