Method and system for core flood testing for reservoir souring studies

Patent metadata

Field	Value
Publication number	US-10443363-B2
Application number	US-201715685316-A
Country	US
Kind code	B2
Filing date	Aug 24, 2017
Priority date	Oct 31, 2016
Publication date	Oct 15, 2019
Grant date	Oct 15, 2019

Abstract

An apparatus and method for testing a core rock sample for reservoir souring. The apparatus includes first and second pumps, and a piston cell associated with each of the first and second pumps. Each piston cell has a first portion and a second portion divided by a movable piston such that the second portion is fluidly sealed from the first portion. Each piston cell is configured to receive fluid pumped by its respective pump into the first portion thereof. A core holder is sized to receive and maintain a core rock sample at a desired pressure and temperature. The second portions of each of the piston cells are fluidly connected to the core holder.

First claim

What is claimed is:

1. An apparatus for testing a core rock sample, comprising:
a first pump;
a first piston cell having a movable piston dividing the first piston cell into a first portion and a second portion that is fluidly sealed from the first portion, the first piston cell configured to receive fluid pumped by the first pump into the first portion thereof;
a second pump;
a second piston cell having a movable piston dividing the second piston cell into a first portion and a second portion that is fluidly sealed from the first portion, the second piston cell configured to receive fluid pumped by the second pump into the first portion thereof;
a core holder sized to receive and maintain a core rock sample at a desired pressure and temperature, wherein the second portion of the first piston cell and the second portion of the second piston cell are fluidly connected to the core holder; and
a filter disposed between the second portion of the first or second piston cells and the core holder.

2. The apparatus of claim 1 , wherein the fluid pumped by at least one of the first pump and second pump is water.

3. The apparatus of claim 1 , wherein the second portion of the first piston cell contains anoxic seawater.

4. The apparatus of claim 1 , wherein the second portion of the second piston cell contains bacteria or a reservoir souring mitigation treatment.

5. The apparatus of claim 1 , further comprising an overburden pump fluidly connected to the core holder and configured to apply a containment pressure to the core rock sample.

6. The apparatus of claim 1 , further comprising an oven in which the core holder is disposed, the oven configured to maintain the core rock sample at the desired temperature.

7. The apparatus of claim 6 , further comprising an extended length of tubing disposed inside the oven and fluidly connected at a first end to the second portions of the first and second piston cells and fluidly connected at a second end to the core holder.

8. The apparatus of claim 1 , further comprising a sampling port at an outlet of the core holder, the sampling port configured to permit collection and analysis of effluent exiting the core holder.

9. The apparatus of claim 1 , further comprising:
a third piston cell having a movable piston dividing the third piston cell into a first portion and a second portion that is fluidly sealed from the first portion, the third piston cell configured to receive fluid pumped by the first pump into the first portion of the third piston cell; and
a fourth piston cell having a movable piston dividing the fourth piston cell into a first portion and a second portion that is fluidly sealed from the first portion, the fourth piston cell configured to receive fluid pumped by the second pump into the first portion of the fourth piston cell;
wherein the second portion of the third piston cell and the second portion of the fourth piston cell are fluidly connected to the core holder; and
wherein the second portion of the third piston cell contains anoxic seawater, and the second portion of the fourth piston cell contains bacteria or a reservoir souring mitigation treatment.

10. A method of testing a core rock sample, comprising:
pumping a first fluid into a first compartment of a first piston cell to move a piston and thereby place pressure on a second fluid in a second compartment of the first piston cell;
pumping a third fluid into a first compartment of a second piston cell to move a piston and thereby place pressure on a fourth fluid in a second compartment of the second piston cell;
injecting the second fluid, under pressure from the first piston cell, into a core holder containing the core rock sample;
injecting the fourth fluid, under pressure from the second piston cell, into the core holder;
for a predetermined time, maintaining a pressure and temperature in the core holder similar to a pressure and temperature at a location from which the core rock sample was taken;
after the predetermined time, injecting the second fluid into the core holder, to thereby cause effluent to exit the core holder through an outlet;
testing the effluent for the presence of hydrogen sulfide;
if hydrogen sulfide is present in the effluent, injecting the second fluid into the core holder until steady levels of hydrogen sulfide are detected; and
maintaining the pressure and the temperature for an additional time if hydrogen sulfide is not present in the effluent.

11. The method of claim 10 , further comprising:
situating the core holder in an oven to maintain the temperature in the core holder similar to the temperature at the location from which the core rock sample was taken.

12. The method of claim 10 , further comprising:
sampling effluent exiting an outlet of the core holder for at least one of organic acids, hydrogen sulfide, bacteria population, and bacteria numbers.

13. The method of claim 10 , wherein the second fluid and the fourth fluid are injected into the core holder until the core rock sample is saturated with a combination of the second fluid and the fourth fluid.

14. The method of claim 10 , wherein the first fluid and the third fluid comprises distilled water.

15. The method of claim 10 , wherein the second fluid comprises anoxic seawater.

16. The method of claim 10 , wherein the fourth fluid comprises bacteria or a reservoir souring mitigation treatment.

17. The method of claim 10 , further comprising using an overburden pump to maintain the pressure in the core holder for the predetermined time.

18. The method of claim 10 , further comprising sampling the effluent within 30 centimeters of the outlet of the core holder.

19. The method of claim 10 , further comprising injecting the second fluid into the core holder if hydrogen sulfide is not present in the effluent.

20. A method of testing a core rock sample, comprising:
in each of a first plurality of piston cells, pumping a first fluid into a first compartment to move a piston therein and thereby place pressure on anoxic seawater in a second compartment;
in each of a second plurality of piston cells, pumping the first fluid into a first compartment to move a piston and thereby place pressure on a fluid comprising at least one of bacteria or a reservoir souring mitigation treatment in a second compartment;
injecting the anoxic seawater, under pressure from the first plurality of piston cells, into a core holder containing the core rock sample;
injecting the fluid comprising at least one of bacteria or a reservoir souring mitigation treatment, under pressure from the second plurality of piston cells, into the core holder;
for a predetermined time, maintaining a pressure and temperature in the core holder similar to a pressure and temperature at a location from which the core rock sample was taken;
after the predetermined time, injecting anoxic seawater into the core holder, to thereby cause effluent to exit the core holder through an outlet;
testing the effluent for the presence of hydrogen sulfide;
if hydrogen sulfide is present in the effluent, injecting the anoxic seawater into the core holder until steady levels of hydrogen sulfide are detected; and
maintaining the pressure and the temperature for an additional time if hydrogen sulfide is not present in the effluent.

21. The method of claim 20 , further comprising injecting the anoxic seawater if hydrogen sulfide is not present in the effluent.

Assignees

• Canalizo Hernandez Monica A
• Enning Dennis R
• Mcdonald Gary L
• Exxonmobil Upstream Res Co

Inventors

• Canalizo-Hernandez Monica A
• Enning Dennis R
• Mcdonald Gary L

Classifications

• E21B43/20 Primary

  Displacing by water · CPC title

• G01N2203/0222

  Temperature · CPC title

• G01N2203/023

  Pressure · CPC title

• G01N33/241 Primary

  for hydrocarbon content · CPC title

• E21B43/24

  using heat, e.g. steam injection · CPC title