Viscosity index improver, method for producing the same and lubricating oil composition

Patent metadata

Field	Value
Publication number	US-10443013-B2
Application number	US-201515503032-A
Country	US
Kind code	B2
Filing date	Sep 15, 2015
Priority date	Sep 17, 2014
Publication date	Oct 15, 2019
Grant date	Oct 15, 2019

Abstract

A viscosity index improver comprising a polymer which has a high viscosity index and good shear stability and which exhibits sufficient solubility in a lubricating base oil, a process for producing the same, and a lubricating oil composition containing the viscosity index improver are provided, wherein the viscosity index improver comprising a polymer satisfying the following (1) to (4): (1) weight-average molecular weight (Mw) of 200,000 or more and 600,000 or less; (2) number-average molecular weight (Mn) of 90,000 or more; (3) molecular weight distribution (Mw/Mn) of 4.0 or less; and (4) branching degree of 1.0 or more.

First claim

The invention claimed is:

1. A viscosity index improver comprising a polymer obtained by polymerizing a maleimide monomer (a) represented by the following formula (1), that is referred to as a “component (a)”:

wherein R 1 and R 2 independently represent a hydrogen atom or an alkyl group, and X represents a hydrogen atom, a linear, cyclic or branched alkyl group, which optionally has an aromatic ring, or an aryl group; an alkyl (meth)acrylate (b) having an aliphatic hydrocarbon group of 6 to 40 carbon atoms, that is referred to as a “component (b)”; and an alkyl (meth)acrylate (c) having an aliphatic hydrocarbon group of 1 to 5 carbon atoms, that is referred to as a “component (c)”; as essential components of a monomer component, in the presence of a tri- or higher functional mercaptan and/or a tri- or higher functional initiator-;
wherein
the polymer has a ring structure derived from the component (a) in a main chain, wherein the ring structure is represented by the following formula (4):

a content of the unit derived from the component (a) is 5 parts by mass or more and 30 parts by mass or less, relative to 100 parts by mass of the polymer, a content of the unit derived from the component (b) is 50 parts by mass or more and less than 95 parts by mass, relative to 100 parts by mass of the polymer, and a content of the unit derived from the component (c) is 2 parts by mass or more and less than 40 parts by mass, relative to 100 parts by mass of the polymer, and
the polymer satisfies the following (1) to (3):
(1) weight-average molecular weight (Mw) of 200,000 or more and 600,000 or less;
(2) number-average molecular weight (Mn) of 90,000 or more;
(3) molecular weight distribution (Mw/Mn) of 4.0 or less.

2. The viscosity index improver according to claim 1 , wherein the polymer satisfies the following (4):
(4) branching degree of 1.0 or more.

3. A lubricating oil composition comprising a lubricating base oil and the viscosity index improver according to claim 1 , wherein a content of the viscosity index improver is 0.01 mass % or more and 70 mass % or less.

4. A viscosity index improver comprising
a polymer having a branch unit derived from a tri- or higher functional mercaptan and/or a branch unit derived from a tri- or higher functional initiator,
a unit having a ring structure in a main chain of the polymer, wherein the ring structure is represented by the following formula (4):

wherein R 1 and R 2 independently represent a hydrogen atom or an alkyl group, and X represents a hydrogen atom, a linear, cyclic or branched alkyl group, which optionally has an aromatic ring, or an aryl group,
a unit derived from an alkyl (meth)acrylate having an aliphatic hydrocarbon group of 6 to 40 carbon atoms, and
a unit derived from an alkyl (meth)acrylate having an aliphatic hydrocarbon group of 1 to 5 carbon atoms, wherein
a content of the unit represented by the formula (4) is 5 parts by mass or more and 30 parts by mass or less, relative to 100 parts by mass of the polymer, a content of the unit derived from an alkyl (meth)acrylate having an aliphatic hydrocarbon group of 6 to 40 carbon atoms is 50 parts by mass or more and less than 95 parts by mass, relative to 100 parts by mass of the polymer, and a content of the unit derived from an alkyl (meth)acrylate having an aliphatic hydrocarbon group of 1 to 5 carbon atoms is 2 parts by mass or more and less than 40 parts by mass, relative to 100 parts by mass of the polymer, and
the polymer satisfies the following (1) to (3):
(1) weight-average molecular weight (Mw) of 200,000 or more and 600,000 or less;
(2) number-average molecular weight (Mn) of 90,000 or more;
(3) molecular weight distribution (Mw/Mn) of 4.0 or less.

5. The viscosity index improver according to claim 4 , wherein the polymer satisfies the following (4):
(4) branching degree of 1.0 or more.

6. A lubricating oil composition comprising a lubricating base oil and the viscosity index improver according to claim 4 , wherein a content of the viscosity index improver is 0.01 mass % or more and 70 mass % or less.

7. A method for producing a viscosity index improver comprising the step of polymerizing a maleimide monomer (a) represented by the following formula (1), that is referred to as a component (a):

wherein R 1 and R 2 independently represent a hydrogen atom or an alkyl group, and X represents a hydrogen atom, a linear, cyclic or branched alkyl group, which optionally has an aromatic ring, or an aryl group; an alkyl (meth)acrylate (b) having an aliphatic hydrocarbon group of 6 to 40 carbon atoms, that is referred to as a “component (b)”; and an alkyl (meth)acrylate (c) having an aliphatic hydrocarbon group of 1 to 5 carbon atoms, that is referred to as a “component (c)”; as essential components of a monomer component, in the presence of a tri- or higher functional mercaptan and/or a tri- or higher functional initiator, thereby obtaining a polymer having a ring structure derived from the component (a) in a main chain,
wherein
the ring structure is represented by the following formula (4):

a used amount of the component (a) is 5 parts by mass or more and 30 parts by mass or less, relative to 100 parts by mass of the monomer components, a used amount of the component (b) is 50 parts by mass or more and less than 95 parts by mass, relative to 100 parts by mass of the monomer components, and a used amount of the component (c) is 2 parts by mass or more and less than 40 parts by mass, relative to 100 parts by mass of the monomer components.

Assignees

• Nippon Catalytic Chem Ind

Inventors

• Ugamura Tadayoshi
• Yasumura Kazunari
• Izumi Keiko

Classifications

• C10N2040/25

  Internal-combustion engines · CPC title

• C10N2030/68

  Shear stability · CPC title

• C10N2020/04

  Molecular weight; Molecular weight distribution · CPC title

• C10N2070/00

  Specific manufacturing methods for lubricant compositions · CPC title

• C10N2030/02

  Pour-point; Viscosity index · CPC title