Aqueous low friction coating for telecommunication cables

Patent metadata

Field	Value
Publication number	US-10443009-B2
Application number	US-201816011132-A
Country	US
Kind code	B2
Filing date	Jun 18, 2018
Priority date	Dec 4, 2013
Publication date	Oct 15, 2019
Grant date	Oct 15, 2019

Abstract

A fluoropolymer coating composition comprises: fluorinated homopolymer particles dispersed in water, fluorinated copolymer particles dispersed in water, non-fluorinated polymer particles dispersed in water; and at least one aziridine compound comprising at least two aziridine groups. The composition is especially useful in low friction coating for telecommunication cables.

First claim

What is claimed is:

1. A method for coating an article, the method comprising:
applying an aqueous coating composition to an exposed polymer surface of the article, the aqueous coating composition comprising fluorinated homopolymer particles dispersed in water, fluorinated copolymer particles dispersed in water, non-fluorinated polymer particles dispersed in water, and at least one aziridine compound comprising at least two aziridine groups; and
drying the aqueous coating composition to remove water therefrom and yield a fluoropolymer coating over the exposed polymer surface of the article, wherein the fluorinated homopolymer particles, the fluorinated copolymer particles, and the non-fluorinated polymer particles remain in particle form, and an outer surface layer of the fluoropolymer coating has a greater concentration of fluorinated particles than a concentration of fluorinated particles in the aqueous coating composition;
wherein the exposed polymer surface comprises one of polyethylene, polyester, polyvinyl chloride, or a low surface energy plastic.

2. The method of claim 1 , wherein the applying of the aqueous coating composition is performed at a temperature of less than 50° C.

3. The method of claim 1 , wherein the drying of the aqueous coating composition comprises air drying at room temperature.

4. The method of claim 1 , wherein the drying of the aqueous coating composition comprises heating the aqueous coating composition to a temperature of at least about 50° C.

5. The method of claim 1 , wherein the non-fluorinated polymer particles comprise at least one of a polyurethane or an acrylic polymer.

6. The method of claim 1 , wherein the non-fluorinated polymer particles comprise an acrylic latex material or a polyurethane latex material.

7. The method of claim 1 , wherein the fluorinated homopolymer particles comprise polytetrafluoroethylene.

8. The method of claim 1 , wherein the aqueous coating composition further comprises inorganic oxide nanoparticles.

9. The method of claim 8 , wherein the inorganic oxide nanoparticles comprise nanoparticulate silica having an average particle size of less than 100 nm.

10. The method of claim 1 , wherein the fluorinated copolymer particles comprise a copolymer of tetrafluoroethylene, hexafluoropropylene, and vinylidene fluoride.

11. The method of claim 1 , wherein the fluoropolymer coating comprises 3 wt. % to about 35 wt. % non-fluorinated polymer, 15 wt. % to 75 wt. % fluorinated homopolymer, and 10 wt. % to 75 wt. % fluorinated copolymer after drying.

12. The method of claim 1 , wherein the fluoropolymer coating comprises a thickness in a range of from about 5 microns to about 100 microns.

13. The method of claim 1 , wherein the exposed polymer surface comprises a low surface energy plastic.

14. The method of claim 1 , wherein the exposed polymer surface comprises a material that is selected from the group consisting of polyethylene, polyester, and polyvinyl chloride.

15. The method of claim 1 , wherein the applying the aqueous coating composition comprises at least one of spray coating, dip coating, roll coating, curtain coating, knife coating, and gravure coating.

16. The method of claim 1 , wherein the article comprises a telecommunication cable.

17. The method of claim 16 , wherein the telecommunication cable comprises a low friction telecommunication cable including at least one optical fiber surrounded by a polymeric cable jacket, and the exposed polymer surface comprises an external surface of the polymeric cable jacket.

18. The method of claim 1 , wherein the article comprises a film substrate or sheet substrate.

19. The method of claim 1 , wherein the article comprises one of the following items (i) to (iv): (i) a polymer film, (ii) a polymer film comprising at least one metalized polymer surface, (iii) a material comprising a laminated polymer surface, or (iv) a material having a polymer coated surface.

20. The method of claim 1 , wherein the drying of the aqueous coating composition is performed at a temperature of up to about 80° C.

21. The method of claim 11 , wherein the fluorinated copolymer particles comprise a copolymer of tetrafluoroethylene, hexafluoropropylene, and vinylidene fluoride.

22. The method of claim 1 , wherein the fluorinated and non-fluorinated polymer particles do not form a continuous interpenetrating network.

Assignees

• Corning Res & Dev Corp

Inventors

• Yu Zhigang
• Wang Yaming
• Cai Wei
• Jing Naiyong

Classifications

• C10N2040/32

  Wires, ropes or cables lubricants · CPC title

• C10M133/38

  Heterocyclic nitrogen compounds · CPC title

• C09D7/67

  Particle size smaller than 100 nm · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C09D127/18

  Homopolymers or copolymers of tetrafluoroethene · CPC title