High polymer load polyolefin adhesive compositions

Patent metadata

Field	Value
Publication number	US-10442962-B2
Application number	US-201414902144-A
Country	US
Kind code	B2
Filing date	Oct 6, 2014
Priority date	Oct 18, 2013
Publication date	Oct 15, 2019
Grant date	Oct 15, 2019

Abstract

The present invention is related to adhesive compositions comprising about 50 to about 80 wt % of a polymer blend of at least two different propylene-based polymers, wherein the polymer blend has a melt viscosity of about 100 to about 6,000 cP and adhesive compositions comprising about 30 to about 60 wt % of a polymer blend of at least two different propylene-based polymers, wherein the polymer blend has a melt viscosity of about 6,000 cP to about 60,000 cP. When subjected to Temperature Rising Elution Fractionation, the polymer blend exhibits a first fraction that is soluble at −15° C. in xylene, the first fraction having an isotactic (mm) triad tacticity of about 70 mol % to about 90 mol %; and a second fraction that is insoluble or less soluble than the first fraction at −15° C. in xylene, the second fraction having an isotactic (mm) triad tacticity of about 85 mol % to about 98 mol %.

First claim

We claim:

1. An adhesive composition comprising:
(a) a polymer blend comprising
a first propylene-based polymer, wherein the first propylene-based polymer is a homopolymer of propylene or a copolymer of propylene and ethylene or a C 4 to C 10 alpha-olefin;
a second propylene-based polymer, wherein the second propylene-based polymer is a homopolymer of propylene or a copolymer of propylene and ethylene or a C 4 to C 10 alpha-olefin; wherein the second propylene-based polymer is different than the first propylene-based polymer;
wherein the polymer blend has a melt viscosity, measured at 190° C. of about 100 to about 6,000 cP and wherein, when subjected to Temperature Rising Elution Fractionation, the polymer blend exhibits: a first fraction that is soluble at −15° C. in xylene, the first fraction having an isotactic (mm) triad tacticity of about 70 mol % to about 90 mol %; and a second fraction that is insoluble at −15° C. in xylene, the second fraction having an isotactic (mm) triad tacticity of about 85 mol % to about 98 mol %;
wherein the polymer blend is present in the amount of about 50 to about 80 wt % of the adhesive composition; and

(b) a tackifier,
wherein the adhesive composition has a melt viscosity, measured at 140° C. of about 50 to about 5,500 cP,
wherein the adhesive composition has a peel strength, as determined by ASTM D-903, that does not vary by more than about 10% over an application temperature of about 110° C. to 190° C.; and
wherein the adhesive composition is free of plasticizer and wax.

2. The adhesive composition of claim 1 , wherein the tackifier has a softening point, as determined by ASTM E-28, of about 80 to about 145° C.

3. The adhesive composition of claim 1 , wherein the tackifier has an aromaticity of about 0 to about 15 mol % aromatic protons.

4. The adhesive composition of claim 1 , wherein the tackifier may be a single tackifier or a blend of one or more tackifiers.

5. The adhesive composition of claim 1 , further comprising an antioxidant.

6. The adhesive composition of claim 1 , further comprising one or more polymer additives having a lower total melt viscosity, measured at 190° C., and higher total crystallinity, as compared to the melt viscosity and crystallinity of the polymer blend.

7. The adhesive composition of claim 1 , wherein the polymer blend has a heat of fusion of between about 5 to about 30 J/g.

8. The adhesive composition of claim 1 , wherein the melt viscosity of the adhesive composition, measured at 180° C., does not vary by more than about 10% for up to about 48 hours.

9. An article comprising the adhesive composition of claim 1 .

10. An article of claim 9 , wherein the adhesive composition adheres one or more substrates, and wherein at least one of the one or more substrates comprises paper, cardboard, plastic, nonwoven, metal, wood, other natural fiber based material, or combinations thereof.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Schroeyers Jurgen J M
• Austin Jennifer J
• Mowry Shawn W
• Coffey James N

Classifications

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08K5/005

  Stabilisers against oxidation, heat, light, ozone · CPC title

• C08L23/142

  at least partially crystalline copolymers of propene with other olefins · CPC title

• C08K5/0016

  Plasticisers · CPC title

• C08L2314/06

  Metallocene or single site catalysts · CPC title