Method for purifying reclaimed polyethylene

Patent metadata

Field	Value
Publication number	US-10442912-B2
Application number	US-201715839911-A
Country	US
Kind code	B2
Filing date	Dec 13, 2017
Priority date	Dec 20, 2016
Publication date	Oct 15, 2019
Grant date	Oct 15, 2019

Abstract

A method for purifying a reclaimed polyethylene is provided. The method involves obtaining reclaimed polyethylene, contacting it with a first fluid solvent to produce an extracted reclaimed polyethylene then dissolving the extracted reclaimed polyethylene in a solvent to produce a first solution comprising polyethylene and suspended contaminants. The first solution is settled to produce a second solution comprising polyethylene and remaining contaminants. The second solution is purified by contacting the second solution with solid media to produce a third solution comprising purer polyethylene. Finally, the purer polyethylene is separated from the third solution.

First claim

What is claimed is:

1. A method for purifying reclaimed polyethylene comprising:
a. Obtaining the reclaimed polyethylene wherein said reclaimed polyethylene is selected from the group consisting of post-consumer use polymers, post-industrial use polymers, and combinations thereof;
b. Contacting the reclaimed polyethylene at a temperature from about 80° C. to about 220° C. and ata pressure from about 150 psig (1.03 MPa) to about 15,000 psig (103.42 MPa) with a first fluid solvent having a standard boiling point less than about 70° C., to produce an extracted reclaimed polyethylene;
c. Dissolving the extracted reclaimed polyethylene in a solvent selected from the group consisting of the first fluid solvent, a second fluid solvent, and mixtures thereof, at a temperature from about 90° C. to about 220° C. and a pressure from about 350 psig (2.41 MPa) to about 20,000 psig (137.90 MPa) to produce a first solution comprising polyethylene and suspended contaminants;
d. Settling said first solution comprising polyethylene and suspended contaminants at a temperature from about 90° C. to about 220° C. and at a pressure from about 350 psig (2.41 MPa) to about 20,000 psig (137.90 MPa) to produce a second solution comprising polyethylene and remaining contaminants;
e. Purifying said second solution at a temperature from about 90° C. to about 220° C. and at a pressure from about 350 psig (2.41 MPa) to about 20,000 psig (137.90 MPa) by contacting said second solution with solid media to produce a third solution comprising purer polyethylene; and
f. Separating said purer polyethylene from said third solution;

wherein said second fluid solvent has the same chemical composition or a different chemical composition as the first fluid solvent.

2. The method of claim 1 , wherein said polyethylene is separated from said third solution at a temperature from about 0° C. to about 220° C. and a pressure from about 0 psig (0 MPa) to 2,000 psig (13.79 MPa).

3. The method of claim 1 , wherein said reclaimed polyethylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration of at least 0.5%.

4. The method of claim 1 , wherein said reclaimed polyethylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration of at least 1%.

5. The method of claim 1 , wherein said reclaimed polyethylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration of at least 2%.

6. The method of claim 1 , wherein said reclaimed polyethylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration of at least 3%.

7. The method of claim 1 , wherein said reclaimed polyethylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration of at least 4%.

8. The method of claim 1 , wherein said reclaimed polyethylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration of at least 5%.

9. The method of claim 1 , wherein said reclaimed polyethylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration up to 20%.

10. The method of claim 1 , wherein said reclaimed polyethylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration up to 18%.

11. The method of claim 1 , wherein said reclaimed polyethylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration up to 16%.

12. The method of claim 1 , wherein said reclaimed polyethylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration up to 14%.

13. The method of claim 1 , wherein said reclaimed polyethylene is dissolved in the fluid solvent, or fluid solvent mixture, at a mass percent concentration up to 12%.

14. The method of claim 1 , wherein the reclaimed polyethylene is post-consumer recycle derived polyethylene.

15. The method of claim 1 , wherein said polyethylene is a polyethylene homopolymer or a primarily polyethylene copolymer.

16. The method of claim 1 , wherein said fluid solvent has a standard boiling point less than about 0° C. and greater than about −45° C. and a standard enthalpy change of vaporization of less than about +25 kJ/mol.

17. The method of claim 1 , wherein said fluid solvent is selected from the group consisting of olefinic hydrocarbons, aliphatic hydrocarbons, and mixtures thereof.

18. The method of claim 17 , wherein said aliphatic hydrocarbon is selected from the group consisting of C 1 -C 6 aliphatic hydrocarbons and mixtures thereof.

19. The method of claim 17 , wherein said aliphatic hydrocarbons and mixtures thereof is comprised of primarily C 4 aliphatic hydrocarbons.

20. The method of claim 17 , wherein said fluid solvent consists essentially of C 4 liquefied petroleum gas.

21. The method of claim 17 , wherein said fluid solvent is n-butane, butane isomers, or mixtures thereof.

22. The method of claim 1 , wherein said temperature in the contacting, dissolving, settling and purification steps is from about 110° C. to about 170° C.

23. The method of claim 1 , wherein said pressure in the contacting step is from about 1,100 psig (7.58 MPa) to about 5,500 psig (37.92 MPa).

24. The method of claim 1 , wherein said pressure in the contacting is less than about 1,100 psig (7.58 MPa).

25. The method of claim 1 , wherein said pressure in the dissolving, settling, and purification steps is greater than about 4,500 psig (31.03 MPa).

26. The method of claim 1 , wherein said pressure in the dissolving, settling, and purification steps is greater than about 5,500 psig (37.92 MPa).

27. The method of claim 1 , wherein said solid media is selected from the group consisting of inorganic substances, carbon-based substances, and mixtures thereof.

28. The method of claim 27 , wherein said inorganic substances are selected from the group consisting of oxides of silicon, oxides of aluminum, oxides of iron, aluminum silicates, amorphous volcanic glasses, and mixtures thereof.

29. The method of claim 27 , wherein said inorganic substances are selected from the group consisting of silica gel, diatomite, sand, quartz, alumina, perlite, fuller's earth, bentonite, and mixtures thereof.

30. The method of claim 27 , wherein said carbon-based substances are selected from the group consisting of anthracite coal, carbon black, coke, activated carbon, cellulose, and mixtures thereof.

31. The method of claim 1 , wherein said contacting of the polyethylene solution with said solid media is done in a packed bed of said solid media.

32. The method of claim 31 , where said packed bed is greater than 20 cm in length.

Assignees

• Procter & Gamble

Inventors

• Layman John Moncrief
• Collias Dimitris Ioannis
• Schonemann Hans
• Williams Kara

Classifications

• C08J2323/08

  Copolymers of ethene (C08J2323/16 takes precedence) · CPC title

• B29K2023/06

  PE, i.e. polyethylene · CPC title

• B29B2017/0293

  Dissolving the materials in gases or liquids · CPC title

• B29B17/02

  Separating plastics from other materials · CPC title

• C08J2323/06

  Polyethene · CPC title