Direct amination of hydrocarbons

Patent metadata

Field	Value
Publication number	US-10442753-B2
Application number	US-201615561708-A
Country	US
Kind code	B2
Filing date	Feb 23, 2016
Priority date	Apr 2, 2015
Publication date	Oct 15, 2019
Grant date	Oct 15, 2019

Abstract

Process for preparing aminated aromatic hydrocarbons that may be substituted comprising the steps of reacting an aromatic hydrocarbon with ammonia in the presence of a catalyst having a crystalline microporous structure wherein the catalyst comprises vanadium aluminophosphate molecular sieve (VAPO) and/or aluminophosphate molecular sieve (AlPO) and wherein the catalyst is preferably impregnated with nickel and/or copper, and wherein the aromatic hydrocarbon may be substituted.

First claim

The invention claimed is:

1. A process for preparing aminated aromatic hydrocarbons comprising the steps of reacting an aromatic hydrocarbon with ammonia in the presence of a catalyst having a crystalline microporous structure wherein the catalyst comprises vanadium aluminophosphate molecular sieve (VAPO) and wherein the catalyst is impregnated with nickel and copper in amounts such that the nickel content is between 1 wt % and 30 wt % and the copper content is between 1 wt % and 30 wt %, based on the total weight of the catalyst.

2. The process according to claim 1 , wherein the catalyst is treated by reduction or calcination.

3. The process according to claim 2 , wherein the catalyst is reduced in the presence of molecular hydrogen.

4. The process according to claim 2 , wherein the reduction with molecular hydrogen occurs at a temperature between 100 and 300° C.

5. The process according to claims 2 , wherein the reduction with molecular hydrogen occurs during between 50 and 100 minutes.

6. The process according to claim 2 , wherein the calcination with air occurs at a temperature between 400 and 700° C.

7. The process according to claim 1 , wherein the catalyst has a framework type code provided by the International Zeolite Association selected from the group consisting of AFI, AEL, ATO, AEI, AET, AFN, AFO, AFT, ATV, CHA, ERI, LEV, SOD, and VFI.

8. The process according to claim 1 , wherein the aromatic hydrocarbon is benzene.

9. The process according to claim 1 , wherein the catalysts are treated at a temperature between 350 and 700° C.

10. The process according to claim 1 , wherein the amination occurs at a temperature between 400 and 700° C.

11. The process according to claim 1 , wherein the amination occurs at a pressure between 50 and 150 bar.

12. The process according to claim 1 , wherein the aromatic hydrocarbon is substituted.

Assignees

• Huntsman Int Llc

Inventors

• Corma Canos Avelino
• Concepcion Heydorn Patricia

Classifications

• B01J29/83

  Aluminophosphates [APO compounds] · CPC title

• B01J37/14

  with gases containing free oxygen · CPC title

• B01J2229/186

  not in framework positions · CPC title

• B01J29/84 Primary

  Aluminophosphates containing other elements, e.g. metals, boron · CPC title

• C07C211/46

  Aniline · CPC title