Polysaccharide agents and methods of their use for removing solids from water

Patent metadata

Field	Value
Publication number	US-10442710-B2
Application number	US-201815949925-A
Country	US
Kind code	B2
Filing date	Apr 10, 2018
Priority date	Nov 27, 2013
Publication date	Oct 15, 2019
Grant date	Oct 15, 2019

Abstract

Polysaccharide agents for removing solids from an aqueous suspension and methods for using the polysaccharide agents to remove solids from an aqueous suspension.

First claim

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:

1. A method for removing solids from an aqueous suspension of solids, comprising,
contacting an aqueous suspension of solids with a quantity of a plant polysaccharide agent for a period of time sufficient to flocculate a portion of the solids to provide a suspension comprising flocculated solids, wherein the plant polysaccharide agent is an extract of two or more of cactus, okra, fenugreek, aloe, chia, psyllium, or tamarind extracts, and
mechanically dewatering the suspension comprising flocculated solids to provide separated solids and an aqueous supernate.

2. The method of claim 1 , wherein the plant polysaccharide agent comprises fenugreek extract.

3. The method of claim 1 , wherein the quantity of the plant polysaccharide agent is from about 0.005 g agent/L aqueous suspension to about 1 g agent/L aqueous suspension.

4. The method of claim 1 , wherein the quantity of plant polysaccharide agent is about 0.5 g agent/L aqueous suspension.

5. The method of claim 1 , wherein the plant polysaccharide agent comprises tamarind gum.

6. The method of claim 1 , wherein the aqueous suspension is tannery waste, municipal wastewater, sewage, textile waste, drinking water, electrochemical waste, biodigestate waste, agricultural waste, brewery waste, dairy waste, surface water, ground water, storm water runoff, or anaerobic digestate.

7. The method of claim 1 , wherein the separated solids comprise suspended solids or total dissolved solids.

8. The method of claim 1 , wherein the separated solids comprise metals.

9. The method of claim 1 , wherein the separated solids comprise one or more of a phosphate, a nitrate, a sulfate, or an ammonium nutrient.

10. The method of claim 1 , wherein the separated solids comprise microorganisms.

11. The method of claim 1 , wherein the plant polysaccharide agent comprises:
(a) a polysaccharide isolated from fenugreek seeds by ethanol extraction of a filtrate or a solution derived from fenugreek seeds; and
(b) one or more of the remaining plant polysaccharide extracts,
wherein the ratio of the polysaccharide from fenugreek seeds to the one or more remaining plant polysaccharide extracts is from 0.5 to 2.0 based on dry weight.

12. The method of claim 11 , wherein the polysaccharide isolated from fenugreek seeds comprises 4,6-linked β-Manp and terminally linked α-Galp in 1:1 ratio.

13. A method for removing solids from an aqueous suspension of solids, comprising:
contacting an aqueous suspension of solids having a first concentration of suspended solids with a quantity of a plant polysaccharide agent for a period of time sufficient to flocculate at least a portion of the solids to provide a suspension comprising flocculated solids, wherein the plant polysaccharide agent is an extract selected from fenugreek, cactus, okra, aloe, chia, psyllium, or tamarind extracts, and wherein the plant polysaccharide agent is a combination of two or more extracts including fenugreek extract; and
removing at least a portion of the flocculated solids from the suspension comprising flocculated solids to provide an aqueous medium having a second concentration of suspended solids, wherein the first concentration is greater than the second concentration.

14. The method of claim 13 , wherein contacting an aqueous suspension of solids with a quantity of a plant polysaccharide agent further comprises contacting with tamarind gum.

15. The method of claim 13 , wherein the polysaccharide agent comprises:
(a) a polysaccharide isolated from fenugreek seeds by ethanol extraction of a filtrate or a solution derived from fenugreek seeds; and
(b) one or more plant polysaccharide extracts,
wherein the ratio of the polysaccharide from fenugreek seeds to the one or more plant polysaccharide extracts is from 0.5 to 2.0 based on dry weight.

16. The method of claim 15 , wherein the polysaccharide isolated from fenugreek seeds comprises 4,6-linked β-Manp and terminally linked α-Galp in 1:1 ratio.

17. A method for removing solids from an aqueous suspension of solids, comprising:
contacting an aqueous suspension of solids having a first concentration of suspended solids with a quantity of a plant polysaccharide agent for a period of time sufficient to flocculate at least a portion of the solids to provide a suspension comprising flocculated solids, wherein the plant polysaccharide agent is an extract selected from fenugreek, cactus, okra, aloe, chia, psyllium, or tamarind extracts, wherein the polysaccharide agent comprises:
(a) a polysaccharide isolated from fenugreek seeds by ethanol extraction of a filtrate or a solution derived from fenugreek seeds; and
(b) one or more of the remaining plant polysaccharide extracts,
wherein the ratio of the polysaccharide from fenugreek seeds to the one or more remaining plant polysaccharide extracts is from 0.5 to 2.0 based on dry weight; and

removing at least a portion of the flocculated solids from the suspension comprising flocculated solids to provide an aqueous medium having a second concentration of suspended solids, wherein the first concentration is greater than the second concentration.

Assignees

• Texas A & M Univ Sys
• Pristina Water LLC
• Pristana Water Llc

Inventors

• Srinivasan Rajani
• Mishra Anuradha
• Mckinney John

Classifications

• C02F2103/34

  from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 · CPC title

• C02F1/5263 Primary

  using natural chemical compounds · CPC title

• C02F2103/06

  Contaminated groundwater or leachate · CPC title

• C02F2101/10

  Inorganic compounds · CPC title

• C02F2103/02

  Non-contaminated water, e.g. for industrial water supply · CPC title