Hydrogel object and method of manufacturing hydrogel object

Patent metadata

Field	Value
Publication number	US-10442181-B2
Application number	US-201615209268-A
Country	US
Kind code	B2
Filing date	Jul 13, 2016
Priority date	Jul 22, 2015
Publication date	Oct 15, 2019
Grant date	Oct 15, 2019

Abstract

A hydrogel object includes a polymer and water, wherein the rate of mass loss is not greater than 20 percent by mass when the hydrogel object is left undone for one week at 25 degrees C. and relative humidity of 50 percent.

First claim

What is claimed is:

1. A method of manufacturing a hydrogel object comprising:
(a) providing multiple hydrogel liquid precursors comprising a monomer and water, wherein each of said hydrogel liquid precursors have a different composition;
(b) distributing said hydrogel liquid precursors to a predetermined position and in a predetermined amount such that the areas corresponding to each of said hydrogel liquid precursors have different post-curing compression stress values or post-curing modulus of elasticity values;
(c) curing said hydrogel liquid precursors; and
repeating (b) and (c) to form a hydrogel object of a predetermined three-dimensional shape,
wherein the method further comprises, after said hydrogel object of a predetermined three-dimensional shape is formed, forming a film of a material different from said hydrogel on a surface of the hydrogel object.

2. The method according to claim 1 , wherein one or more of the hydrogel liquid precursors includes a mineral.

3. The method according to claim 1 , wherein water vapor transmission rate of the film is not greater than 500 g/m 2 ·d or oxygen transmission rate of the film is not greater than 100,000 cc/m 2 /hr/atm.

4. The method according to claim 1 , wherein a difference of Young's modulus between the hydrogel object before the film is formed and the hydrogel object after the film is formed is not less than 0.01 MPa.

5. The method according to claim 1 , wherein said film is formed on the hydrogel structure by application, lamination, or a 3D printer.

6. The method according to claim 1 , wherein said film covers the entire surface of the hydrogel structure.

7. The method according to claim 1 , wherein one or more of the hydrogel liquid precursors comprises a humectant.

8. The method according to claim 1 , wherein said method further comprises imparting a humectant to one or more of the hydrogel liquid precursors.

Assignees

• Iwata Hiroshi
• Niimi Tatsuya
• Norikane Yoshihiro
• Matsumura Takashi
• Ricoh Co Ltd

Inventors

• Iwata Hiroshi
• Niimi Tatsuya
• Norikane Yoshihiro
• Matsumura Takashi

Classifications

• C08K5/053

  Polyhydroxylic alcohols · CPC title

• C08K5/05

  Alcohols; Metal alcoholates · CPC title

• B29C64/40

  Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof · CPC title

• B29C64/112

  using individual droplets, e.g. from jetting heads · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title