Multilayer interlayer film having infrared ray reflection layer and thermoplastic resin, and laminated glass having such film

Patent metadata

Field	Value
Publication number	US-10442163-B2
Application number	US-201414898107-A
Country	US
Kind code	B2
Filing date	Jun 13, 2014
Priority date	Jun 14, 2013
Publication date	Oct 15, 2019
Grant date	Oct 15, 2019

Abstract

There is provided an interlayer film for laminated glass with which the visible light transmittance and the heat resistance of the laminated glass can be heightened. The interlayer film for laminated glass according to the present invention includes an organic coloring matter containing a transition element, a metal element which is different from a metal element contained in a metal oxide particle and different from a transition element, a thermoplastic resin and a plasticizer.

First claim

The invention claimed is:

1. A multilayer interlayer film for laminated glass, comprising an infrared ray reflection layer reflecting infrared rays, a first resin layer containing a thermoplastic resin, and a second resin layer containing a thermoplastic resin,
wherein the first resin layer is arranged on a first surface side of the infrared ray reflection layer,
the second resin layer is arranged on a second surface side opposite to the first surface side of the infrared ray reflection layer, and
at least the first resin layer among the first resin layer and the second resin layer is an interlayer film for laminated glass which contains an organic coloring matter containing a transition element, a metal element different from a transition element, the thermoplastic resin, a plasticizer, and metal oxide particles,
the transition element in the organic coloring matter containing a transition element is copper or vanadium, and
the organic coloring matter containing a transition element is a phthalocyanine compound or a naphthalocyanine compound, and
wherein the organic coloring matter and the metal oxide particles are dispersed throughout an entirety of the thickness of the first resin layer.

2. The multilayer interlayer film for laminated glass according to claim 1 ,
wherein the metal element is a polyvalent metal element.

3. The multilayer interlayer film for laminated glass according to claim 1 ,
wherein the content of the metal element is greater than or equal to 20 ppm and less than or equal to 200 ppm in the interlayer film for laminated glass.

4. The multilayer interlayer film for laminated glass according to claim 1 ,
wherein the metal element different from the transition element is magnesium, and the metal element different from the transition element is added as magnesium acetate or magnesium 2-ethylbutyrate to be contained in the interlayer film for laminated glass.

5. The multilayer interlayer film for laminated glass according to claim 1 ,
wherein the maximum absorption wavelength of the organic coloring matter containing a transition element is greater than or equal to 550 nm and less than or equal to 750 nm.

6. The multilayer interlayer film for laminated glass according to claim 1 ,
wherein the metal oxide particles are tin-doped indium oxide particles or tungsten oxide particles.

7. The multilayer interlayer film for laminated glass according to claim 1 ,
wherein the thermoplastic resin contained in the interlayer film for laminated glass is a polyvinyl acetal resin.

8. The multilayer interlayer film for laminated glass according to claim 1 ,
wherein the infrared ray reflection layer has a characteristic having, the infrared ray transmittance of 50% or less at one or more wavelength within the range of 780 to 2100 mm.

9. The multilayer interlayer film for laminated glass according to claim 1 ,
wherein the infrared ray reflection layer is a resin film with metal foil, a multilayer laminated film in which a metal layer and a dielectric layer are formed on a resin layer, a multilayer resin film or a liquid crystal film.

10. The multilayer interlayer film for laminated glass according to claim 1 ,
wherein the first resin layer contains an ultraviolet ray shielding agent.

11. The multilayer interlayer film for laminated glass according to claim 10 , wherein the ultraviolet ray shielding agent is a metal oxide-based ultraviolet ray shielding agent that is coated with an insulating metal oxide, the insulating metal oxide comprising zirconia.

12. The multilayer interlayer film for laminated glass according to claim 1 ,
wherein the infrared ray transmittance in the wavelength range of 780 to 2100 nm of the first resin layer is higher than the infrared ray transmittance in the wavelength range of 780 to 2100 nm of the second resin layer.

13. The multilayer interlayer film for laminated glass according to claim 1 ,
wherein the thermoplastic resin contained in the second resin layer is a polyvinyl acetal resin.

14. The multilayer interlayer film for laminated glass according to claim 1 ,
wherein the second resin layer contains a plasticizer.

15. The multilayer interlayer film for laminated glass according to claim 1 ,
wherein the first resin layer contains an ultraviolet ray shielding agent and the second resin layer contains an ultraviolet ray shielding agent.

16. Laminated glass, comprising a first laminated glass member, a second laminated glass member and a multilayer interlayer film for laminated glass according to claim 1 ,
wherein the multilayer interlayer film for laminated glass is arranged between the first laminated glass member and the second laminated glass member.

17. The multilayer interlayer film for laminated glass according to claim 1 , further comprising a layer containing polyethylene terephthalate, the layer containing polyethylene terephthalate being arranged between the first resin layer and the infrared ray reflection layer, or between the infrared ray reflection layer and the second resin layer.

Assignees

• Sekisui Chemical Co Ltd

Inventors

• Tsunoda Ryuta
• Izu Yasuyuki

Classifications

• B32B17/10339

  Specific parts of the laminated safety glass or glazing being colored or tinted (tinted glass sheet B32B17/1011; tinted interlayer B32B17/10651) · CPC title

• G02B5/208

  for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation · CPC title

• C08K5/56

  Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond · CPC title

• B32B17/10651

  comprising colorants, e.g. dyes or pigments · CPC title

• B32B2307/558

  Impact strength, toughness · CPC title