Process for producing a catalyst and catalyst article

Patent metadata

Field	Value
Publication number	US-10441918-B2
Application number	US-201515500548-A
Country	US
Kind code	B2
Filing date	Jul 24, 2015
Priority date	Jul 31, 2014
Publication date	Oct 15, 2019
Grant date	Oct 15, 2019

Abstract

A process for producing a ceramic catalyst involves the steps of:
a) providing functional particles having a catalytically inactive pore former as a support surrounded by a layer of a catalytically active material, b) processing the functional particles with inorganic particles to form a catalytic composition, c) treating the catalytic composition thermally to form a ceramic catalyst, wherein the ceramic catalyst comprises at least porous catalytically inactive cells
which are formed by the pore formers in the functional particles, which are embedded in a matrix comprising the inorganic particles, which form a porous structure and which are at least partly surrounded by an active interface layer comprising the catalytically active material of the layer of the functional particles.

An SCR catalyst produced in by this method has an improved NO x conversion rate compared to a conventionally produced SCR catalyst.

First claim

The invention claimed is:

1. A process for producing a ceramic catalyst, the process comprising:
a) processing functional particles with inorganic particles to form a catalytic composition, the functional particles having a catalytically inactive pore former as a support surrounded by a layer of a catalytically active material; and
b) calcining the catalytic composition to form a ceramic catalyst, wherein the ceramic catalyst comprises at least porous catalytically inactive cells
which are formed by the pore formers in the functional particles,
which are embedded in a matrix comprising the inorganic particles,
which form a porous structure and
which are at least partly surrounded by an active interface layer comprising the catalytically active material of the layer of the functional particles.

2. The process of claim 1 , wherein the pore formers consist of an organic material comprising thermoplastics or elastomers.

3. The process of claim 1 , wherein the pore formers consist of an inorganic porous material having at least mesoporosity.

4. The process of claim 3 , wherein the inorganic material is selected from a clay mineral, diatomaceous earth, silica gel, and porous glass.

5. The process of claim 3 , wherein the pore formers consist of an inorganic porous material having macroporosity.

6. The process of claim 1 , wherein powder particles of the catalytically active material have been applied to the pore former.

7. The process of claim 1 , wherein the layer is formed by converting an outer layer of the catalytically inactive pore formers to the catalytically active layer.

8. The process of claim 1 , wherein the pore formers have a particle size in the range of from 10 μm to 200 μm.

9. The process of claim 1 , wherein the inorganic particles comprise a binder component wherein, after the treatment in step b), the binder component forms a ceramic matrix.

10. The process of claim 1 , further comprising forming a shaped body from the catalytic composition by extrusion and then thermally treating the shaped body.

11. The process of claim 1 , wherein the catalytic composition is applied as a washcoat to a monolithic support and the coated support is then treated thermally.

12. The process of claim 1 , wherein the application of the layer to the pore former for formation of the functional particles and the processing of the catalytic composition are conducted in a single process step.

13. The process of claim 1 , wherein the pore formers account for a proportion in the range of from 40% by volume to 80% by volume, based on the dry catalytic composition.

14. The process of claim 1 , wherein catalytically active materials used are any one or more of:
a crystalline molecular sieve;
a tungsten/cerium-based catalytic system;
a metal oxide or mixed oxide comprising one or more titanium oxide, vanadium oxide, tungsten oxide, or a combination thereof; or
a platinum group metal-based system.

15. The process of claim 14 , wherein the crystalline molecular sieve is present as individual crystallites.

16. The process of claim 14 , wherein the crystalline molecular sieve has at least mesoporosity as defined by the IUPAC definition in addition to their inherent microporosity.

17. The process of claim 14 , wherein the metal oxide or mixed metal oxide of the catalytically active material comprises a titanium-vanadium-tungsten system, a titanium-vanadium-tungsten-silicon system, a titanium-vanadium-silicon system, a titanium-vanadium-tungsten-iron system, a titanium-vanadium-tungsten-silicon-iron system, a titanium-vanadium-silicon-iron system, an iron vanadate system and/or and an iron aluminum vanadate system.

18. The process of claim 1 , further comprising introducing particles of another catalytically active material into the catalytic composition in step a).

19. The process of claim 1 , wherein the pore formers have differing particle size distribution.

20. The process of claim 1 , wherein the catalytic composition comprises two or more different functional particles which differ in terms of the catalytically active material used for the layer, wherein:
a mixture of two or more different catalytically active materials is used for the layer; and/or
a different catalytically active material is applied to each of the individual pore formers,
and where first and second functional particles are obtained and mixed to form the catalytic composition.

21. A catalyst article comprising a catalyst having a composite structure having a porous structure embedded into an inorganic matrix, wherein the porous structure is formed from catalytically inactive, at least porous cells at least partly surrounded by an active interface layer comprising a catalytically active material, wherein said catalyst article is any of:
an extruded catalyst article consisting of the catalyst,
a honeycomb consisting of the catalyst,
a plate catalytic converter consisting of the catalyst,
pellets consisting of the catalyst,
a monolithic support body coated with a washcoat consisting of the catalyst,
a wall-flow filter comprising a honeycomb, wherein the honeycomb consists of the catalyst and/or the honeycomb has been coated with a washcoat composed of the catalyst.

22. The catalyst article of claim 21 , wherein the ceramic matrix is at least substantially free of catalytically active material.

23. The catalyst article of claim 21 , having two or more different catalytically active materials, wherein
the catalytically active material in an active interface layer that bounds a first cell is different from the catalytically active material in an active interface layer that bounds a second cell and/or
an active interface layer that bounds a particular cell contains two or more different catalytically active materials.

24. The catalyst article of claim 21 , wherein the catalytically active material is selected from
a crystalline molecular sieve;
a tungsten/cerium-based catalytic system;
a metal oxide or mixed oxide comprising one or more titanium oxide, vanadium oxide, tungsten oxide, or a combination thereof; or
a platinum group metal-based system.

25. The catalytic article of claim 24 , wherein the metal oxide or mixed metal oxide of the catalytically active material comprises a titanium-vanadium-tungsten system, a titanium-vanadium-tungsten-silicon system, a titanium-vanadium-silicon system, a titanium-vanadium-tungsten-iron system, a titanium-vanadium-tungsten-silicon-iron system, a titanium-vanadium-silicon-iron system, an iron vanadate system and/or and an iron aluminum vanadate system.

26. Functional particles which comprise a pore former which takes the form of a support surrounded by a layer of a catalytically active material, wherein the pore former consists of an organic material comprising thermoplastics or elastomers, or wherein the pore former consists of an inorganic porous material having at least mesoporosity.

Assignees

• Johnson Matthey Plc

Inventors

• Bauer Juergen

Classifications

• B01J37/082

  Decomposition and pyrolysis · CPC title

• F01N3/2828

  Ceramic multi-channel monoliths, e.g. honeycombs · CPC title

• B01J23/00

  Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 (B01J21/16 takes precedence) · CPC title

• B01J37/0219

  the coating containing organic compounds · CPC title

• B01D2255/2065

  Cerium · CPC title