Pre-lithiation of multiple battery pouches

Patent metadata

Field	Value
Publication number	US-10439254-B2
Application number	US-201916248213-A
Country	US
Kind code	B2
Filing date	Jan 15, 2019
Priority date	Sep 18, 2017
Publication date	Oct 8, 2019
Grant date	Oct 8, 2019

Abstract

Systems and methods are provided, in which the level of metal ions in cells stacks and lithium ion batteries is regulated in situ, with the electrodes of the cell stack(s) in the respective pouches. Regulation of metal ions may be carried out electrochemically by metal ion sources in the pouches, electrically connected to the electrodes. The position and shape of the metal ion sources may be optimized to create uniform metal ion movements to the electrode surfaces and favorable SEI formation. The metal ion sources may be removable, or comprise a lithium source for lithiating the anodes or cathodes during operation of the battery according to SoH parameters. Regulation of metal ions may be carried out from metal ion sources in separate electrolyte reservoir(s), with circulation of the metal-ion-containing electrolyte through the cell stacks in the pouches prior or during the formation.

First claim

The invention claimed is:

1. A system for regulating a level of metal ions in electrodes of multiple lithium-ion cell stacks, the system comprising:
a plurality of lithium-ion cell stacks, each cell stack comprising at least one anode, at least one separator and at least one cathode which are packaged in a pouch cover, the plurality of cell stacks packaged in a corresponding plurality of pouch covers,
at least one electrolyte reservoir having an electrolyte fluid with at least one metal ion source, wherein the at least one electrolyte reservoir is in fluid communication with the plurality of pouch covers,
at least one pump configured to maintain a circulating flow of the electrolyte fluid between the cell stacks after their packaging in the respective pouch covers and the at least one electrolyte reservoir, and
circuitry configured to apply a predetermined voltage between electrodes of the cell stacks and the metal ion source in the at least one electrolyte reservoir, to regulate a level of the metal ions in the electrodes.

2. The system of claim 1 , wherein the at least one metal ion source comprises lithium and/or magnesium.

3. The system of claim 1 , wherein the level of metal ions is regulated in the anodes, the at least one metal ion source comprises lithium and the circuitry is configured to pre-lithiate the anodes during a formation process of the cell stacks.

4. The system of claim 1 , wherein the level of metal ions is regulated in the cathodes, the at least one metal ion source comprises lithium, and the circuitry is configured to pre-lithiate the cathodes during a formation process of the cell stacks.

5. The system of claim 1 , wherein the level of metal ions is regulated in the cathodes, the at least one metal ion source comprises lithium, and the system is configured to lithiate the cathodes following a formation process of the cell stacks.

6. The system of claim 1 , wherein the pouch covers are maintained during operation of the cell stacks.

7. The system of claim 1 , comprising at least two electrolyte reservoirs, of which at least one is configured to provide the metal ions during a formation process of the cell stacks, and at least another one is configured to load the pouch covers with electrolyte fluid after the formation process, for operation of the cell stacks.

8. A method of regulating a level of metal ions in electrodes of multiple lithium ion cell stacks, wherein each cell stack comprises at least one anode, associated at least one cathode and at least one separator packaged in a respective pouch cover, the method comprising:
connecting at least one electrolyte reservoir, having a metal ion source therein, in fluid communication with the cell stacks in the respective pouch covers,
maintaining circulating flow of electrolyte fluid between the cell stacks after their packaging in the respective pouch covers and the at least one electrolyte reservoir, and
applying specified voltage between the electrodes of the cell stacks and the metal ion source in the at least one electrolyte reservoir, to regulate a level of the metal ions in the electrodes.

9. The method of claim 8 , wherein the metal ion source comprises at least one metal electrode comprising at least one of lithium, magnesium and sodium in the at least one electrolyte reservoir.

10. The method of claim 8 , comprising connecting at least two electrolyte reservoirs, of which at least one electrolyte reservoir is configured to provide the metal ions during a formation process of the cell stacks and at least another electrolyte reservoir is configured to load the pouch covers with electrolyte for operation of the lithium ion cell stacks the formation process.

11. The method of claim 8 , comprising applying a specified voltage simultaneously to the multiple cell stacks, wherein the at least one electrolyte reservoir is used commonly for all the cell stacks.

Assignees

• Storedot Ltd

Inventors

• Paz Ron
• Kedem Nir
• Burshtain Doron
• Baram Nir
• Pour Nir
• Aronov Daniel

Classifications

• H01M10/0445

  Multimode batteries, e.g. containing auxiliary cells or electrodes switchable in parallel or series connections · CPC title

• H01M10/446

  Initial charging measures · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/0461 Primary

  Electrochemical alloying · CPC title

• H01M10/4257 Primary

  Smart batteries, e.g. electronic circuits inside the housing of the cells or batteries · CPC title