Sulfur-carbon composite comprising micro-porous carbon nanosheets for lithium-sulfur batteries and process for preparing the same

Patent metadata

Field	Value
Publication number	US-10439201-B2
Application number	US-201515579642-A
Country	US
Kind code	B2
Filing date	Jun 5, 2015
Priority date	Jun 5, 2015
Publication date	Oct 8, 2019
Grant date	Oct 8, 2019

Abstract

A sulfur-carbon composite includes micro-porous carbon nanosheets and sulfur. The sulfur is loaded into the micropores of the micro-porous carbon nanosheets. The sulfur-carbon composite can be included in an electrode material. The sulfur-carbon composite can be included in a lithium-sulfur battery. A process for preparing the sulfur-carbon composite includes carbonization-activation of carbonaceous precursor, purification, and loading of sulfur into micro-porous carbon nanosheets.

First claim

The invention claimed is:

1. A sulfur-carbon composite, comprising:
micro-porous carbon nanosheets; and
sulfur, wherein the sulfur is loaded into micropores of the micro-porous carbon nanosheets.

2. The sulfur-carbon composite according to claim 1 , wherein a ratio of a length of the micro-porous carbon nanosheets to a thickness of the micro-porous carbon nanosheets is in a range of 500 nm:200 nm to 50 μm:10 μm.

3. The sulfur-carbon composite according to claim 1 , wherein the micro-porous carbon nanosheets have an average micropore diameter of 0.2-1.0 nm.

4. The sulfur-carbon composite according to claim 1 , wherein pore volumes of the micropores of the micro-porous carbon nanosheets are no less than 75% of total pore volumes of the micropores and of mesopores.

5. The sulfur-carbon composite according to claim 1 , wherein the micro-porous carbon nanosheets have a BET specific surface area in a range of 300 to 4500 m 2 /g.

6. The sulfur-carbon composite according to claim 1 , wherein the micro-porous carbon nanosheets have a pore volume of 0.1-3.0 cm 3 /g.

7. The sulfur-carbon composite according to claim 1 , wherein the micro-porous carbon nanosheets have a sulfur load amount of 10-85 wt % based on total weight of the sulfur-carbon composite.

8. The sulfur-carbon composite according to claim 1 , wherein the micro-porous carbon nanosheets are optionally doped with one of N, P, B, or any combination of N, P, and B.

9. The sulfur-carbon composite of claim 1 , wherein the sulfur-carbon composite is included in a lithium-sulfur battery.

10. An electrode material, comprising:
a sulfur-carbon composite, including:
micro-porous carbon nanosheets; and
sulfur,

wherein the sulfur is loaded into micropores of the micro-porous carbon nanosheets.

11. A process for preparing a sulfur-carbon composite, the process comprising:
(1) carbonization-activation of carbonaceous precursor in an inert-gas flow at a temperature of 500-850° C. for a period of 30 minutes to 10 hours, wherein the carbonaceous precursor is optionally mixed with dopants containing one of N, P, B, or any combination of N, P, and B;
(2) purification of the product obtained by the carbonization-activation of carbonaceous precursor, followed by washing with acid solution, and drying to obtain micro-porous carbon nanosheets;
(3) loading of sulfur into the obtained micro-porous carbon nanosheets.

12. The process according to claim 11 , wherein the carbonaceous precursor is one or more selected from the group consisting of organic salts of alkali metal and organic salts of alkaline earth metal.

13. The process according to claim 11 , wherein loading of sulfur into the micro-porous carbon nanosheets includes mixing homogeneously sulfur with the micro-porous carbon nanosheets obtained in step (2), followed by heating the mixture so as to obtain the sulfur-carbon composite.

14. The process according to claim 13 , wherein loading of sulfur into the micro-porous carbon nanosheets includes dissolving sulfur completely in an organic solvent, followed by adding the micro-porous carbon nanosheets obtained in step (2) into the above prepared sulfur solution; after mixing homogeneously and evaporating the solvent completely, heating the mixture so as to obtain the sulfur-carbon composite.

Assignees

• Bosch Gmbh Robert
• Inst Chemistry Cas

Inventors

• Guo Yuguo
• Zhang Shuaifeng
• Yin Yaxia
• Chen Yunhua
• Zhao Nahong

Classifications

• C01B32/15

  Nano-sized carbon materials · CPC title

• H01M4/13

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title

• H01M4/80

  Porous plates, e.g. sintered carriers · CPC title

• H01M4/38

  of elements or alloys · CPC title

• H01M4/36 Primary

  Selection of substances as active materials, active masses, active liquids · CPC title