Insulating film

Patent metadata

Field	Value
Publication number	US-10438746-B2
Application number	US-201013512515-A
Country	US
Kind code	B2
Filing date	Nov 26, 2010
Priority date	Nov 30, 2009
Publication date	Oct 8, 2019
Grant date	Oct 8, 2019

Abstract

Provided is a highly insulating film having excellent electrical characteristics (breakdown voltage), heat resistance, and handling properties such as windability and processability. The highly insulating film is a biaxially stretched film made of a styrene polymer having a syndiotactic structure as a main component. The highly insulating film contains specific inert fine particles A, antioxidant, and polymer Y having a glass transition temperature Tg by DSC of 130° C. or more each in a specific amount, and has a refractive index in the thickness direction of 1.5750 or more and 1.6350 or less.

First claim

The invention claimed is:

1. An insulating film comprising a biaxially stretched film made of a styrene polymer having a syndiotactic structure as a main component,
the biaxially stretched film containing:
inert fine particles A having an average particle size of 0.05 μm or more and 1.5 μm or less with a relative standard deviation in particle size of 0.5 or less in an amount of 0.05 mass % or more and 2.0 mass % or less;
an antioxidant in an amount of 0.1 mass % or more and 8 mass % or less; and
a polymer Y having a glass transition temperature Tg by DSC of 130° C. or more in an amount of 20 mass % or more and 48 mass % or less, wherein the polymer Y is polyphenylene ether represented by the following formula (1):

the biaxially stretched film having a breakdown voltage (BDV) at 120° C. of 350 V/μm or more, and a refractive index in the thickness direction of 1.5750 or more and 1.6040 or less.

2. The insulating film according to claim 1 , wherein the content ratio of the polymer Y to the antioxidant (polymer Y content/antioxidant content) is 1 to 100.

3. The insulating film according to claim 1 , having:
a loss modulus (E″) peak temperature of 120° C. or more and 150° C. or less as measured by dynamic viscoelasticity measurement at an oscillation frequency of 10 Hz; and
a dielectric loss tangent (tan δ) at 120° C. of 0.0015 or less at a frequency of 1 kHz.

4. The insulating film according to claim 1 , having a heat shrinkage rate at 200° C.×10 minutes of 6% or less in longitudinal and transverse directions thereof.

5. The insulating film according to claim 1 , having a storage modulus (E′) at 120° C. of 600 MPa or more as measured by dynamic viscoelasticity measurement at an oscillation frequency of 10 Hz.

6. The insulating film according to claim 1 , having a film thickness of 0.4 μm or more and less than 6.5 μm.

7. The insulating film according to claim 1 , containing inert fine particles B having an average particle size of 0.5 μm or more and 3.0 μm or less with a relative standard deviation in particle size of 0.5 or less in an amount of 0.01 mass % or more and 1.5 mass % or less, with the average particle size of the inert fine particles B being at least 0.2 μm larger than the average particle size of the inert fine particles A.

8. The insulating film according to claim 7 , wherein the inert fine particles B are spherical polymer resin particles having a particle size ratio of 1.0 or more and 1.3 or less.

9. The insulating film according to claim 1 , wherein the inert fine particles A are spherical particles having a particle size ratio of 1.0 or more and 1.3 or less.

10. The insulating film according to claim 9 , wherein the inert fine particles A are spherical polymer resin particles.

11. The insulating film according to claim 9 , wherein the inert fine particles A are spherical silicone resin particles.

12. The insulating film according to claim 1 , wherein the antioxidant has a thermal decomposition temperature of 250° C. or more.

13. The insulating film according to claim 1 , wherein the antioxidant in an amount of 0.5 mass % or more and 3 mass % or less.

14. A capacitor made using the insulating film according to claim 1 .

Assignees

• Masuda Shigeyoshi
• Nakagawa Dai
• Hasegawa Kinji
• Nishiyama Masanori
• Teijin Ltd

Inventors

• Masuda Shigeyoshi
• Nakagawa Dai
• Hasegawa Kinji
• Nishiyama Masanori

Classifications

• H01G4/18 Primary

  of synthetic material, e.g. derivatives of cellulose (H01G4/16 takes precedence) · CPC title

• C08L83/04

  Polysiloxanes · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C08J2325/04

  Homopolymers or copolymers of styrene · CPC title

• H01B3/44

  vinyl resins; acrylic resins (silicones H01B3/46) · CPC title