Multilayer film, interlayer film comprising the multilayer film and laminated glass and sound-insulating glass laminate comprising the interlayer film

Patent metadata

Field	Value
Publication number	US-10438575-B2
Application number	US-201816176670-A
Country	US
Kind code	B2
Filing date	Oct 31, 2018
Priority date	Nov 20, 2017
Publication date	Oct 8, 2019
Grant date	Oct 8, 2019

Abstract

The present invention relates to a multilayer film. In various embodiments the multilayer film is an interlayer film for laminated glass. The present invention also relates to an interlayer film for laminated glass, wherein the laminated glass has excellent sound insulating properties. The present invention also relates to a laminated glass that is obtained using this interlayer film. The present invention can effectively improve the compatibility of the resin film (B) with the plasticizer so that the intermediate layer (i.e., the resin film (B)) allows to add more plasticizer(s) to achieve the effect of enhancing sound-insulating. Furthermore, the intermediate layer of the multilayer film uses different plasticizer from the non-intermediate layer of the multilayer film so as to prevent the migration of plasticizers between different layers and the multilayer film has little or no plasticizer bleed-out.

First claim

What is claimed is:

1. A multilayer film, comprising:
a resin film (A) comprising a polyvinyl acetal resin (a1) and a plasticizer (a2);
a resin film (B) comprising a polyvinyl acetal resin (b1) and a plasticizer (b2); and
a resin film (C) comprising a polyvinyl acetal resin (c1) and a plasticizer (c2), wherein the resin film (B) is positioned between the resin film (A) and the resin film (C);
wherein the polyvinyl acetal resin (a1), the polyvinyl acetal resin (b1), and the polyvinyl acetal resin (c1) each independently have a hydroxyl group content ratio; and the hydroxyl group content ratio of the polyvinyl acetal resin (b1) is greater than each of the hydroxyl group content ratio of the polyvinyl acetal resin (a1) and the polyvinyl acetal resin (c1); and the polyvinyl acetal resin (b1) has a degree of acetalization of less than 60 mol %.

2. The multilayer film of claim 1 , wherein the polyvinyl acetal resin (a1) and the polyvinyl acetal resin (c1) each independently have a degree of acetalization; and the degree of acetalization of the polyvinyl acetal resin (b1) is less than the degree of acetalization of the polyvinyl acetal resin (a1) and the polyvinyl acetal resin (c1).

3. The multilayer film of claim 1 , wherein the polyvinyl acetal resin (a1), the polyvinyl acetal resin (b1), and the polyvinyl acetal resin (c1) each independently have a degree of acetylation; and the degree of acetylation of the polyvinyl acetal resin (b1) is greater than the degree of acetylation of the polyvinyl acetal resin (a1) and the polyvinyl acetal resin (c1).

4. The multilayer film of claim 1 , wherein a difference between the hydroxyl group content ratio of the polyvinyl acetal resin (b1) and the hydroxyl group content ratio of the polyvinyl acetal resin (a1) is greater than 5; and a difference between the hydroxyl group content ratio of the polyvinyl acetal resin (b1) and the hydroxyl group content ratio of the polyvinyl acetal resin (c1) is greater than 5.

5. The multilayer film of claim 2 , wherein a difference between the degree of acetalization of the polyvinyl acetal resin (b1) and the degree of acetalization of the polyvinyl acetal resin (a1) is greater than 5; and a difference between the degree of acetalization of the polyvinyl acetal resin (b1) and the degree of acetalization of the polyvinyl acetal resin (c1) is greater than 5.

6. The multilayer film of claim 1 , wherein the plasticizer (b2) is different from the plasticizer (a2) and the plasticizer (c2).

7. The multilayer film of claim 1 , wherein the plasticizer (b2) has a solubility parameter (calculated from Fedors' equation) of greater than or equal to 9.06.

8. The multilayer film of claim 7 , wherein the plasticizer (a2) and the plasticizer (c2) each independently have a solubility parameter; and the solubility parameter of the plasticizer (b2) is greater than the solubility parameter of the plasticizer (a2) and the plasticizer (c2).

9. The multilayer film of claim 2 , wherein the degree of acetalization of the polyvinyl acetal resin (a1) is greater than 65 mol %.

10. The multilayer film of claim 2 , wherein the degree of acetalization of the polyvinyl acetal resin (c1) is greater than 65 mol %.

11. The multilayer film of claim 3 , wherein the degree of acetylation of the polyvinyl acetal resin (b1) is greater than 5 mol %; and the hydroxyl group content ratio of the polyvinyl acetal resin (b1) is greater than 35 mol %.

12. The multilayer film of claim 3 , wherein the acetylation degree of the polyvinyl acetal resin (a1) is less than 5 mol %; and the hydroxyl group content ratio of the polyvinyl acetal resin (a1) is less than 30 mol %.

13. The multilayer film of claim 3 , wherein the acetylation degree of the polyvinyl acetal resin (c1) is less than 5 mol %; and the hydroxyl group content ratio of the polyvinyl acetal resin (c1) is less than 30 mol %.

14. The multilayer film of claim 1 , wherein the plasticizer (b2) is selected from the group consisting of dihexyl adipate (DHA), tetraethylene glycol di-2-ethylhexanoate (4GO), triethylene glycol di-2-ethylbutyrate (3GH), tetraethylene glycol di-2-ethylbutyrate (4GH), tetraethylene glycol di-n-heptanoate (4G7), triethylene glycol di-n-heptanoate (3G7), glycerol, ethylene glycol, 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate (Texanol), dipentaerythritol hexaoctoate, and bis[2-(2-butoxyethoxy)ethyl] adipate (D600), diethylene glycol dibenzonate, dipropylene glycol dibenzonate, and combinations thereof.

15. The multilayer film of claim 1 , wherein the amount of the plasticizer (b2) is from 50 PHR to 90 PHR, wherein PHR is the weight parts of the plasticizer (b2) per 100 weight parts of the polyvinyl acetal resin (b1).

16. An interlayer film for laminated glass, comprising the multilayer film of claim 1 .

17. A laminated glass, comprising the interlayer film of claim 16 , wherein the interlayer film is interposed between two transparent sheets of glass.

18. The laminated glass of claim 17 , wherein the laminated glass has a loss factor of greater than or equal to 0.250 as measured according to ISO 16940-2008.

19. The laminated glass of claim 17 , wherein the laminated glass has little or no plasticizer bleed-out.

20. The laminated glass of claim 18 , wherein the laminated glass has little or no plasticizer bleed-out.

21. A sound-insulating glass laminate, comprising the interlayer film of claim 16 , wherein the interlayer film is interposed between two transparent sheets of glass.

Assignees

• Chang Chun Petrochemical Co Ltd

Inventors

• Wang Cheng-Fan
• Chang Chin-Yen

Classifications

• G10K11/168 Primary

  Plural layers of different materials, e.g. sandwiches · CPC title

• B60J1/001

  Double glazing for vehicles · CPC title

• B32B17/10165

  Functional features of the laminated safety glass or glazing · CPC title

• B32B17/10761

  containing vinyl acetal · CPC title

• B32B17/10036 Primary

  comprising two outer glass sheets · CPC title