Apparatus and method for the non-destructive measurement of hydrogen diffusivity

Patent metadata

Field	Value
Publication number	US-10436741-B2
Application number	US-201715530683-A
Country	US
Kind code	B2
Filing date	Apr 28, 2017
Priority date	Apr 28, 2017
Publication date	Oct 8, 2019
Grant date	Oct 8, 2019

Abstract

A method of measuring a hydrogen diffusivity of a metal structure is provided. The method includes providing a hydrogen charging surface at a first location on an external surface of the structure, and a hydrogen oxidation surface at a second location adjacent to the first location on the external surface of the structure. A hydrogen flux is generated and directed into the metal surface at the charging surface. At least a portion of the hydrogen flux generated by the charging surface and diverted back toward the surface is detected, and a transient of the diverted hydrogen flux is measured. The hydrogen diffusivity of the metal structure is then determined based on the measured transient.

First claim

What is claimed is:

1. A method of measuring a hydrogen diffusivity of a metal structure, comprising:
providing a hydrogen charging surface at a first location on an external surface of the structure;
providing a hydrogen oxidation surface at a second location adjacent to the first location on the external surface of the structure;
generating a hydrogen flux directed into the metal surface at the charging surface;
detecting at least a portion of the hydrogen flux generated by the charging surface diverted back toward the surface;
measuring a transient of the diverted hydrogen flux;
determining the hydrogen diffusivity of the metal structure based on the measured transient; and
positioning a hydrogen flux sensor between the charging surface and the oxidation surface so as to receive the diverted hydrogen flux.

2. The method of claim 1 , wherein the hydrogen flux sensor measures a pressure of the received hydrogen flux.

3. The method of claim 1 , wherein the hydrogen flux sensor includes an ion pump.

4. A method of measuring a hydrogen diffusivity of a metal structure, comprising:
providing a hydrogen charging surface at a first location on an external surface of the structure;
providing a hydrogen oxidation surface at a second location adjacent to the first location on the external surface of the structure;
generating a hydrogen flux directed into the metal surface at the charging surface;
detecting at least a portion of the hydrogen flux generated by the charging surface diverted back toward the surface;
measuring a transient of the diverted hydrogen flux; and
determining the hydrogen diffusivity of the metal structure based on the measured transient,
wherein the hydrogen diffusivity is determined from the measured transient using a simulated master graph for a particular experimental apparatus design, the simulated master graph being independent of geometric dimensions, and experimental parameters.

5. The method of claim 4 , further comprising:
performing sensitivity analysis on each parameter to determine an influence of the parameter on a normalized transient curve; and
identifying the curve as a master curve, with respect to a parameter, if the curve is invariant to changes in the parameter.

6. The method of claim 5 , wherein the parameters include hydrogen charging concentration, hydrogen diffusivity of the metal structure, and metal structure thickness.

7. The method of claim 6 , wherein the parameters further include a radius of the charging surface, a width of the oxidation surface and a wall thickness of the charging cell.

8. An apparatus for measuring a hydrogen diffusivity of a metal structure comprising:
a first chamber positioned on an external surface of the metal structure, the first chamber including a hydrogen flux sensor; and
a second chamber separated by a wall from and adjacent to the first chamber and positioned on the external surface of the metal structure, the second chamber including a hydrogen charging cell for generating hydrogen and induces a hydrogen flux into the external surface of the metal structure;
wherein a portion of the hydrogen flux is diverted out of the metal surface toward the inner first chamber, where the hydrogen flux is measurable by the hydrogen flux sensor.

9. The apparatus of claim 8 , wherein the first chamber includes an electrolyte solution in contact with the external surface of the metal structure, and a counter electrode.

10. The apparatus of claim 9 , further comprising an electric power supply coupled to the external surface of the metal structure, the counter electrode and the reference electrode, the power supply being operative to provide a constant current between the counter electrode and the external surface of the metal structure to provide cathodic polarization of the metal surface.

11. The apparatus of claim 9 , wherein the first chamber is an inner chamber enclosed by an inner casing and the second chamber is an outer chamber position between the inner casing and an outer casing, the outer casing surrounding the inner casing.

12. The apparatus of claim 11 , wherein the inner casing and the outer casing are cylindrical and concentric with respect to each other.

13. The apparatus of claim 12 , further comprising an alignment element positioned between the inner casing and the outer casing to ensure that the inner chamber is concentric within the outer chamber.

14. The apparatus of claim 11 , further comprising a sealing element for securing a bottom of the outer casing to the external surface of the metal structure to prevent leakage of the electrolyte solution.

15. The apparatus of claim 14 , wherein the sealing element comprises a magnet.

16. The apparatus of claim 8 , wherein the hydrogen flux sensor is a hydrogen pressure sensor.

17. The apparatus of claim 8 , wherein the hydrogen flux sensor includes an ion pump.

Assignees

• Saudi Arabian Oil Co

Inventors

• Mohamed Shibly Kaamil Ur Rahman
• Traidia Abderrazak
• Enezi Abdullah

Classifications

• G01L7/02

  in the form of elastically-deformable gauges · CPC title

• G01N15/0826

  and measuring fluid flow rate, i.e. permeation rate or pressure change · CPC title

• G01N2013/003

  Diffusion; diffusivity between liquids · CPC title

• G01N33/20

  Metals · CPC title

• G01N13/00 Primary

  Investigating surface or boundary effects, e.g. wetting power; Investigating diffusion effects; Analysing materials by determining surface, boundary, or diffusion effects (scanning-probe techniques or apparatus G01Q) · CPC title