Hydrocracking process and apparatus with heavy polynuclear aromatics removal from a reboiled column

Patent metadata

Field	Value
Publication number	US-10435635-B2
Application number	US-201715476543-A
Country	US
Kind code	B2
Filing date	Mar 31, 2017
Priority date	Mar 31, 2017
Publication date	Oct 8, 2019
Grant date	Oct 8, 2019

Abstract

A process and apparatus removes HPNA's from a fractionated bottoms stream from a reboiled product fractionation column that obtains heat from a reboiler. HPNA's are removed from the fractionated bottoms stream by stripping it with an inert gas. The HPNA lean stream may be fed back to the reboiled product fractionation column at the same elevation as the feed stream to the column.

First claim

The invention claimed is:

1. A process for hydrocracking, comprising:
hydrocracking a hydrocarbon feed stream over a hydrocracking catalyst in the presence of hydrogen to provide a hydrocracked stream;
separating the hydrocracked stream to provide a liquid hydrocracked stream;
feeding said liquid hydrocracked stream to a fractionation column;
fractionating the liquid hydrocracked stream to provide a fractionated bottoms stream;
splitting said fractionated bottoms stream into at least a first portion and a second portion;
reboiling said first portion of the bottoms stream to provide a reboiled stream;
returning said reboiled stream to said fractionation column;
stripping said second portion of the fractionated bottom stream with a steam stream to provide a stripped stream rich in HPNA's and a stream lean in HPNA's; and
feeding the stream lean in HPNA's and the steam stream to the fractionation column at the same elevation as the liquid hydrocracked stream.

2. The process according to claim 1 , further comprising feeding said liquid hydrocracked stream to said fractionation column in a fractionation feed stream and wherein said stream lean in HPNA's is added to said liquid hydrocracked stream in said fractionation feed stream.

3. The process according to claim 1 , further comprising recycling a third portion of said fractionated bottom stream to said hydrocracking step.

4. The process according to claim 1 , wherein the stream lean in HPNA's is an overhead stream from a stripping column.

5. The process according to claim 1 , wherein separating the hydrocracked stream provides a separated liquid hydrocracked stream and further comprising stripping said separated liquid hydrocracked stream to provide said liquid hydrocracked stream.

6. The process according to claim 5 , further comprising feeding said liquid hydrocracked stream to said fractionation column in a fractionation feed stream at a temperature no more than 100° C. greater than the temperature of the liquid hydrocracked stream exiting a stripping column.

7. The process according to claim 5 , further comprising feeding said liquid hydrocracked stream to said fractionation column in a fractionation feed stream from a stripping column without heating said fractionation feed stream.

8. The process according to claim 1 , further comprising stripping volatiles from the fractionation feed stream over stripping trays downstream of a fractionation feed inlet for feeding said liquid hydrocracked stream to said fractionation column to provide said fractionated bottoms stream.

9. The process according to claim 8 , wherein said volatiles are stripped from the fractionation feed stream over stripping trays that are located in a stub stripping column downstream of said product fractionation column.

10. A process for hydrocracking, comprising:
hydrocracking a hydrocarbon feed stream over a hydrocracking catalyst in the presence of hydrogen to provide a hydrocracked stream;
separating the hydrocracked stream to provide a separated liquid hydrocracked stream;
stripping said separated liquid hydrocracked stream to provide a fractionation feed stream;
feeding said fractionation feed stream to a fractionation column;
fractionating the fractionation feed stream to provide a fractionated bottoms stream;
splitting said fractionated bottoms stream into at least a first portion and a second portion;
stripping said first portion of the fractionated bottom stream with a steam stream to provide a stripped stream rich in HPNA's and a stream lean in HPNA's;
adding the stream lean in HPNA's and the steam stream to said fractionation feed stream;
reboiling said second portion of the bottoms stream to provide a reboiled stream; and
returning said reboiled stream to said fractionation column.

11. The process according to claim 10 , further comprising recycling a third portion of said fractionated bottom stream to said hydrocracking step.

12. The process according to claim 10 , wherein the stream lean in HPNA's is an overhead stream from a stripping column.

13. The process according to claim 10 , further comprising feeding said fractionation feed stream at a temperature no lower than the temperature of the fractionation feed stream exiting a stripping column.

14. The process according to claim 10 , further comprising feeding said fractionation feed stream to said fractionation column from a stripping column without heating said fractionation feed stream.

Assignees

• Uop Llc

Inventors

• Hoehn Richard K
• Eizenga Donald A

Classifications

• C10G49/22 Primary

  Separation of effluents · CPC title

• C10G67/02

  plural serial stages only · CPC title

• C10G47/00

  Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions (C10G15/00 takes precedence; destructive hydrogenation of non-melting solid carbonaceous or similar materials C10G1/06) · CPC title

• C10G47/36

  Controlling or regulating · CPC title

• C10G2400/30

  Aromatics · CPC title