Polymer composition by continuous filler slurry extrusion

Patent metadata

Field	Value
Publication number	US-10435521-B2
Application number	US-201415038620-A
Country	US
Kind code	B2
Filing date	Dec 17, 2014
Priority date	Dec 23, 2013
Publication date	Oct 8, 2019
Grant date	Oct 8, 2019

Abstract

An inventive process for the production of a polymer composition is provided, said process comprising the incorporation of a filler into a polymer material, wherein said polymer material during incorporation of the filler is in at least partially molten state and wherein said filler is incorporated as a slurry.

First claim

The invention claimed is:

1. A process for producing a polymer composition, the process comprising the steps of:
(a) providing a calcium carbonate containing mineral filler having a weight medium particle size d 50 in the range from 0.1 to 50 μm;
(b) providing a polymer material; and
(c) mixing the filler of step (a) and the polymer material of step (b) in an extruder to form a polymer composition comprising the filler of step (a) and the polymer material of step (b);
wherein in the mixing of step (c), the polymer material is in at least a partially molten state and the filler is in a form of a slurry having a solids content in the range from 10 to 90 wt. %, based on the total weight of the filler slurry, the mixing takes place at a pressure above the vapour pressure of liquid in the filler slurry at the processing temperature the mixing takes place, and after mixing, liquid of the filler slurry vaporizes through one or more atmospheric or vacuum vents before discharge of the polymer composition from the extruder.

2. The process according to claim 1 , wherein the filler slurry has a solids content in the range from 15 to 88.5 wt.-%, based on the total weight of the filler slurry.

3. The process according to claim 1 , wherein the filler slurry has a solids content in the range from 20 to 78 wt.-%, based on the total weight of the filler slurry.

4. The process according to claim 1 , wherein the filler is present in the polymer composition is an amount from 30 to 90 wt.-%, based on the total weight of the polymer composition.

5. The process according to claim 1 , wherein the filler is present in the polymer composition is an amount from 5 to 85 wt.-%, based on the total weight of the polymer composition.

6. The process according to claim 1 , wherein the filler is present in the polymer composition is an amount from 20 to 75 wt.-%, based on the total weight of the polymer composition.

7. The process according to claim 1 , wherein the filler provided in step (a) comprises calcium carbonate and one or more of dolomite, barium sulfate, talc, kaolin, clay, mica, and titanium dioxide.

8. The process according to claim 1 , wherein the filler provided in step (a) is calcium carbonate obtained from one or more of chalk, limestone and marble.

9. The process according to claim 1 , wherein the filler provided in step (a) is a ground calcium carbonate (GCC), a precipitated calcium carbonate (PCC), a modified calcium carbonate (MCC), or any mixture thereof.

10. The process according to claim 1 , wherein the filler provided in step (a) is precipitated calcium carbonate (PCC) that is ground prior to incorporation into the polymer material.

11. The process according to claim 1 , wherein the filler provided in step (a) comprises a coated filler, an uncoated filler, or a mixture thereof.

12. The process according to claim 1 , wherein the filler provided in step (a) comprises an uncoated filler.

13. The process according to claim 1 , wherein the filler provided in step (a) comprises an uncoated calcium carbonate containing mineral filler.

14. The process according to claim 1 , wherein the filler provided in step (a) has a weight median particle size d 50 in the range from 0.05 to 10 μm.

15. The process according to claim 1 , wherein the filler provided in step (a) has a weight median particle size d 50 in the range from 0.07 to 5 μm.

16. The process according to claim 1 , wherein the filler provided in step (a) has a weight median particle size d 50 in the range from 0.1 to 2.5 μm.

17. The process according to claim 1 , wherein the filler provided in step (a) has a particle top cut d 98 in the range from 0.25 to 50 μm.

18. The process according to claim 1 , wherein the filler provided in step (a) has a particle top cut d 98 in the range from 0.35 to 30 μm.

19. The process according to claim 1 , wherein the filler provided in step (a) has a particle top cut d 98 in the range from 0.4 to 15 μm.

20. The process according to claim 1 , wherein the polymer material provided in step (b) comprises a thermoplastic resin.

21. The process according to claim 1 , wherein the polymer material provided in step (b) comprises a thermoplastic resin comprising a polyolefin.

22. The process according to claim 21 , wherein the polyolefin is selected from the group consisting of homo- and/or copolymers of polyethylene, homo- and/or copolymers of polypropylene, homo- and/or copolymers of polybutylene, and any mixture thereof.

23. The process according to claim 1 , wherein the extruder is a twin-screw extruder.

24. The process according to claim 1 , wherein the extruder is a twin-screw extruder comprising screws that are co-rotating.

25. The process according to claim 1 , wherein the extruder is a twin-screw extruder comprising screws that are counter-rotating.

26. The process according to claim 1 , which is continuous.

Assignees

• Omya Int Ag
• Fraunhofer Ges Forschung
• Fraunhofer Ges Zur Forderung Der

Inventors

• Tinkl Michael
• Brunner Martin
• Burkhalter René
• Fornera Tazio
• Schirosi Giuseppe
• Pfaendner Rudolf
• Barth Jan
• Dillmann Bernd
• Dörr Harald

Classifications

• B29C48/0018

  combined with shaping by orienting, stretching or shrinking, e.g. film blowing (B29C48/0017 takes precedence) · CPC title

• C08K3/26

  Carbonates; Bicarbonates · CPC title

• B29K2509/00

  Use of inorganic materials not provided for in groups {B29K2503/00 - B29K2507/00,} as filler · CPC title

• C08J3/2056 Primary

  the polymer being pre-melted · CPC title

• B29B9/065

  under-water, e.g. underwater pelletizers · CPC title