Polymer-hybrid carbon filler composite and method for preparing the same

Patent metadata

Field	Value
Publication number	US-10435520-B2
Application number	US-201715833446-A
Country	US
Kind code	B2
Filing date	Dec 6, 2017
Priority date	Oct 19, 2017
Publication date	Oct 8, 2019
Grant date	Oct 8, 2019

Abstract

A polyamide/hybrid carbon filler composite is disclosed. The composite includes a polyamide as a matrix and a hybrid carbon filler dispersed in and bonded to the polyamide matrix. The hybrid carbon filler is composed of a nano carbon and a carbon fiber. Also disclosed is a method for preparing the polyamide/hybrid carbon filler. The method includes simultaneously subjecting a mixture of a polyamide and a hybrid carbon filler to mechanofusion and plasma treatments.

First claim

What is claimed is:

1. A method for preparing a polyamide-carbon filler composite, comprising simultaneously subjecting a mixture of a polyamide and a carbon filler to mechanofusion and plasma treatments wherein the mechanofusion treatment is performed by rotating the mixture of polyamide and carbon filler at lower than atmospheric pressure.

2. The method according to claim 1 , wherein the plasma treatment is performed by applying a voltage to a chamber for the mechanofusion treatment.

3. The method according to claim 2 , wherein the pressure is from 100 to 1,000 Pa, the mixture is rotated at a speed from 100 to 5,000 rpm, the voltage is from 0.5 to 5 kV, and the mechanofusion and plasma treatments are performed for 5 to 30 min.

4. The method according to claim 3 , wherein the mechanofusion and plasma treatments are performed in an atmosphere of a gas selected from nitrogen, air, argon, oxygen, and mixed gases thereof.

5. The method according to claim 4 , wherein the carbon filler is selected from a carbon fiber alone or a mixture of a carbon fiber and a nano carbon.

6. The method according to claim 5 , wherein the polyamide, the carbon fiber, and the nano carbon are present in amounts of 46 to 94% by weight, 5 to 50% by weight, and 0.1 to 5% by weight, respectively.

7. The method according to claim 6 , wherein the polyamide, the carbon fiber, and the nano carbon are present in amounts of 59 to 89% by weight, 10 to 40% by weight, and 0.5 to 1.5% by weight, respectively.

8. The method according to claim 7 , wherein the polyamide, the carbon fiber, and the nano carbon are present in amounts of 59 to 74% by weight, 25 to 40% by weight, and 0.5 to 1.5% by weight, respectively.

9. The method according to claim 8 , wherein the polyamide, the carbon fiber, and the nano carbon are present in amounts of 66 to 72% by weight, 27 to 33% by weight, and 0.5 to 1.5% by weight, respectively.

10. The method according to claim 5 , wherein the pressure is from 300 to 1,000 Pa, the rotational speed is from 1,000 to 5,000 rpm, and the voltage is from 0.8 to 2.5 kV, the mechanofusion treatment and the plasma treatment are performed in a nitrogen atmosphere, the carbon filler is a mixture of a carbon fiber and a nano carbon, and the polyamide, the carbon fiber, and the nano carbon are mixed in amounts of 59 to 74% by weight, 25 to 40% by weight, and 0.5 to 1.5% by weight, respectively.

Assignees

• Korea Inst Sci & Tech

Inventors

• Park Jong Hyuk
• Park Min
• Lee Sang-Soo
• Kim Heesuk
• Son Jeong Gon
• Lee Phillip
• You Ji-won
• Lee Young Mo

Classifications

• C08K3/041

  Carbon nanotubes · CPC title

• C08J2377/06

  Polyamides derived from polyamines and polycarboxylic acids (C08J2377/10 takes precedence) · CPC title

• B29B7/90

  Fillers or reinforcements {, e.g. fibres} · CPC title

• C08J3/28

  Treatment by wave energy or particle radiation · CPC title

• B29B7/86

  for working at sub- or superatmospheric pressure {(B01F33/70 takes precedence)} · CPC title