Prepolymerized catalyst components for the polymerization of olefins

Patent metadata

Field	Value
Publication number	US-10435490-B2
Application number	US-201615750391-A
Country	US
Kind code	B2
Filing date	Jul 14, 2016
Priority date	Aug 4, 2015
Publication date	Oct 8, 2019
Grant date	Oct 8, 2019

Abstract

A Prepolymerized catalyst component for the polymerization of olefins comprising a solid catalyst component which comprises Mg, Ti, and chlorine atoms and an electron donor (ID) said prepolymerized catalyst component being characterized by the fact that:
the electron donor (ID) is constituted by at least 80% mol of 1,3 diethers with respect to the total molar amount of electron donor compounds; the prepolymerized catalyst has a porosity due to pores with diameters up to 1 μm of less than 0.2 cm3/g; it contains an amount of ethylene prepolymer of less than 45% with respect to the total weight of prepolymerized catalyst.

First claim

What is claimed is:

1. A prepolymerized catalyst component for the polymerization of olefins comprising a solid catalyst component which comprises Mg, Ti, and chlorine atoms and an electron donor (ID), said prepolymerized catalyst component being characterized by:
the electron donor (ID) comprises at least 80% mol of 1,3-diethers with respect to the total molar amount of electron donor compounds;
the prepolymerized catalyst has a porosity due to pores with diameters up to 1 μm of less than 0.2 cm 3 /g; and
the said prepolymerized catalysts component comprises an amount of ethylene prepolymer of less than 45% with respect to the total weight of prepolymerized catalyst.

2. The prepolymerized catalyst component according to claim 1 , wherein the ID/Mg molar ratio ranges from 0.030 to 0.20.

3. The prepolymerized catalyst component according to claim 1 , wherein the ID/Mg molar ratio ranges from 0.035 to 0.15.

4. The prepolymerized catalyst component according to claim 1 , wherein the Mg/Ti molar ratio ranges from 4 to 10.

5. The prepolymerized catalyst component according to claim 1 , in which the amount of ethylene pre-polymer is less than 40% wt based on the total weight of pre-polymerized solid catalyst component.

6. The prepolymerized catalyst component according to claim 4 , in which the amount of ethylene pre-polymer ranges from 15 to 35% wt based on the total weight of pre-polymerized solid catalyst component.

7. The prepolymerized catalyst component according to claim 1 , having an average particle size ranging from 20 to 100 μm.

8. The prepolymerized catalyst component according to claim 1 , in which the porosity is less than 0.15 cm 3 /g.

9. The prepolymerized catalyst component according to claim 1 , in which the porosity ranges from 0.05 to 010 cm 3 /g.

10. The prepolymerized catalyst component according to claim 1 , in which the electron donor compound (ID) is selected from the compounds of formula (I)

where R I and R II are the same or different and are hydrogen or linear or branched C 1 -C 18 hydrocarbon groups which can also form one or more cyclic structures; the R III groups, equal or different from each other, are hydrogen or C 1 -C 18 hydrocarbon groups; the R IV groups equal or different from each other, have the same meaning of R III except that they cannot be hydrogen; and each of the R I to R IV groups optionally contains heteroatoms selected from halogens, N, O, S and Si.

11. The prepolymerized catalyst component according to claim 1 , wherein the electron donor (ID) is selected among 1,3-diethers of formula (III):

where the R III and R IV radicals have the same meaning defined in formula (I), R VI radicals equal or different are hydrogen; halogens, selected from C 1 -C 20 alkyl radicals, linear or branched; C 3 -C 20 cycloalkyl, C 6 -C 20 aryl, C 7 -C 20 alkylaryl and C 7 -C 20 aralkyl radicals, optionally containing one or more heteroatoms selected from the group consisting of N, O, S, P, Si, Cl and F, as substitutes for carbon or hydrogen atoms, or both.

12. The pre-polymerized catalyst according to claim 1 , comprising a Ti-halogen bond and a Mg halide.

13. A catalyst system for the polymerization of olefins CH 2 ═CHR, in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising the product of the reaction between:
(i) the prepolymerized solid catalyst component according to claim 1 ,
(ii) an alkylaluminum compound and optionally
(iii) an external electron donor compound.

14. A catalyst system according to claim 13 , in which the external electron donor is selected from silicon compounds of formula Ra 5 Rb 6 Si(OR 7 )c, where a and b are integer from 0 to 2, c is an integer from 1 to 3 and the sum (a+b+c) is 4; R 5 , R 6 , and R 7 , are alkyl, cycloalkyl or aryl radicals with 1-18 carbon atoms optionally containing heteroatoms selected from N, O, halogen and P.

15. A gas-phase process for the polymerization of olefins CH 2 ═CHR, wherein R is hydrogen or a C 1 -C 12 hydrocarbyl group, comprising contacting the olefins with the catalyst system according to claim 13 .

Assignees

• Basell Poliolefine Italia Srl

Inventors

• Algozzini Giuseppina Maria
• Brita Diego
• Cenci Massimo
• Collina Gianni
• DALL'OCCO Tiziano
• Di Diego Maria
• Gaddi Benedetta
• Fusco Ofelia
• Morini Giampiero
• Pedriali Lorella

Classifications

• C08F110/02

  Ethene · CPC title

• C08F10/06

  Propene · CPC title

• C08F4/6543

  halides of magnesium · CPC title

• C08F4/6492

  containing aliphatic unsaturation · CPC title

• C08F4/6465

  containing silicium · CPC title