Method for producing nickel powder

Patent metadata

Field	Value
Publication number	US-10434577-B2
Application number	US-201515127816-A
Country	US
Kind code	B2
Filing date	Mar 24, 2015
Priority date	Mar 26, 2014
Publication date	Oct 8, 2019
Grant date	Oct 8, 2019

Abstract

Provided is nickel powder obtained by adding seed crystals to a nickel ammine complex solution and performing hydrogen reduction reaction under high temperatures and high pressures, wherein the nickel powder does not produce dust during handling, and a container can be efficiently filled with the nickel powder. The method for producing nickel powder includes: adding seed crystals and a surfactant having a nonionic or anionic functional group to a solution containing a nickel ammine complex to forma mixed slurry; and subjecting the mixed slurry to hydrogen reduction under high temperature and high pressure conditions in a pressure vessel to obtain nickel powder from the mixed slurry.

First claim

The invention claimed is:

1. A method for producing nickel powder, by adding, in order, seed crystals and a surfactant having a nonionic or anionic functional group to a solution containing a nickel ammine complex to form nickel powder, the seed crystals of nickel powder having voids, the method sequentially comprising:
(1) a complexing step of adding ammonia gas or aqueous ammonia (NH 4 OH) to a nickel sulfate (NiSO 4 ) solution to form an ammine complex of nickel to obtain a nickel ammine sulfate complex solution;
(2) a seed crystal and surfactant addition step of adding, to the nickel ammine sulfate complex solution obtained in the complexing step (1), a seed crystal slurry containing nickel powder serving as the seed crystals having voids, and then adding thereto a surfactant to form a mixed slurry;
(3) a reduction step of blowing hydrogen gas into the mixed slurry obtained in the seed crystal and surfactant addition step (2) to reduce nickel in the mixed slurry to precipitate the nickel into the voids of the seed crystals to form a reduced slurry containing reduced nickel powder, and then subjecting the reduced slurry to solid-liquid separation treatment by washing and filtration to recover the reduced nickel powder as a washed and reduced nickel powder; and
(4) a growing step of adding the washed and reduced nickel powder recovered in the reduction step (3) to the nickel ammine sulfate complex solution obtained in the complexing step (1) as the seed crystals in the seed crystal and surfactant addition step to form a nickel complex slurry containing nickel powder, feeding the nickel complex slurry containing nickel powder to the reduction step (3) as a mixed slurry used in the reduction step (3), and subjecting the mixed slurry to reduction treatment by hydrogen gas to grow the nickel powder in the nickel complex slurry containing nickel powder, wherein the growing step is performed at least twice to produce product nickel powder.

2. The method for producing nickel powder according to claim 1 , wherein the surfactant having a nonionic functional group is either polyethylene glycol or polyvinyl alcohol.

3. The method for producing nickel powder according to claim 1 , wherein the surfactant having an anionic functional group is sodium polyacrylate.

4. The method for producing nickel powder according to claim 3 , wherein the surfactant having a nonionic or anionic functional group is added in an amount of 1 to 20% by weight of the seed crystals added to the solution containing the nickel ammine complex.

5. The method for producing nickel powder according to claim 1 , wherein the surfactant having a nonionic or anionic functional group is added in an amount of 1 to 20% by weight of the seed crystals added to the solution containing the nickel ammine complex.

Assignees

• Kochi Univ National Univ Corporation
• Sumitomo Metal Mining Co

Inventors

• Yanagisawa Kazumichi
• Zhang Junhao
• Takaishi Kazuyuki
• Yoneyama Tomoaki
• HEGURI Shin-ichi
• Ohara Hideki
• Ikeda Osamu
• Kudo Yohei
• Ozaki Yoshitomo

Classifications

• B22F2009/245

  Reduction reaction in an Ionic Liquid [IL] · CPC title

• B22F9/24 Primary

  starting from liquid metal compounds, e.g. solutions · CPC title

• H01M10/30

  Nickel accumulators (H01M10/34 takes precedence) · CPC title

• B22F9/26 Primary

  using gaseous reductors · CPC title

• B22F2999/00

  Aspects linked to processes or compositions used in powder metallurgy · CPC title