Azeotropic and azeotrope-like compositions of z-1-chloro-3,3,3-trifluoropropene
US-2018043199-A1 · Feb 15, 2018 · US
US10434349B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10434349-B2 |
| Application number | US-201916286857-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 27, 2019 |
| Priority date | Aug 12, 2014 |
| Publication date | Oct 8, 2019 |
| Grant date | Oct 8, 2019 |
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Azeotropic or azeotrope-like compositions are disclosed. The azeotropic or azeotrope-like compositions are mixtures of HFO-E-1,3,4,4,4-pentafluoro-3-trifluoromethyl-1-butene with a second compound selected from the group consisting of methyl formate and HFO-E-1,1,1,4,4,4-hexafluoro-2-butene. Also disclosed are processes of preparing a thermoplastic or thermoset foam by using such azeotropic or azeotrope-like compositions as blowing agents; of producing refrigeration by using such azeotropic or azeotrope-like compositions; of producing cooling; of producing heating; of using such azeotropic or azeotrope-like compositions as solvents; of producing an aerosol product by using such azeotropic or azeotrope-like compositions; of using such azeotropic or azeotrope-like compositions as heat transfer media; of extinguishing or suppressing a fire by using such azeotropic or azeotrope-like compositions; and of using such azeotropic or azeotrope-like compositions as dielectrics.
Opening claim text (preview).
What is claimed is: 1. A process comprising using an azeotropic or azeotrope-like composition as a power cycle working fluid, wherein said azeotropic or azeotrope-like composition consists essentially of HFO-E-1,3,4,4,4-pentafluoro-3-trifluoromethyl-1-butene and a second compound selected from the group consisting of methyl formate and HFO-E-1,1,1,4,4,4-hexafluoro-2-butene. 2. The process of claim 1 , wherein the second compound is methyl formate. 3. The process of claim 1 , wherein the second compound is HFO-E-1,1,1,4,4,4-hexafluoro-2-butene. 4. The process of claim 1 , wherein the second compound is present in an effective amount to form an azeotropic combination with the HFO-E-1,3,4,4,4-pentafluoro-3-trifluoromethyl-1-butene. 5. The process of claim 1 , wherein the second compound is present in an effective amount to form an azeotrope-like combination with the HFO-E-1,3,4,4,4-pentafluoro-3-trifluoromethyl-1-butene. 6. The process of claim 1 , wherein the azeotropic or azeotrope-like composition consists essentially of: (a) from about 11.2 mole percent to about 46.5 mole percent of HFO-E-1,3,4,4,4-pentafluoro-3-trifluoromethyl-1-butene; and (b) from about 53.5 mole percent to about 88.8 mole percent of methyl formate. 7. The process of claim 1 , wherein the azeotropic or azeotrope-like composition consists essentially of: (a) about 42.1 mole percent of HFO-E-1,3,4,4,4-pentafluoro-3-trifluoromethyl-1-butene; and (b) about 57.9 mole percent of methyl formate. 8. The process of claim 1 , wherein the azeotropic or azeotrope-like composition consists essentially of: (a) from about 1 to 99 mole percent of HFO-E-1,3,4,4,4-pentafluoro-3-trifluoromethyl-1-butene; and (b) from about 1 to 99mole percent of methyl formate. 9. The process of claim 1 , wherein the azeotropic or azeotrope-like composition consists essentially of: (a) from about 1 to 9 mole percent of HFO-E-1,3,4,4,4-pentafluoro-3-trifluoromethyl-1-butene; and (b) from about 91 to 99 mole percent of methyl formate. 10. The process of claim 1 , wherein the azeotropic or azeotrope-like composition consists essentially of: (a) from about 1 to 6 mole percent of HFO-E-1,3,4,4,4-pentafluoro-3-trifluoromethyl-1-butene; and (b) from about 94 to 99 mole percent of methyl formate.
The mixture being azeotropic · CPC title
Fire-extinguishing compositions; Use of chemical substances in extinguishing fires (fireproof paints C09D5/18; fireproofing materials C09K21/00) · CPC title
only fluorine as halogen atoms · CPC title
Compounds containing oxygen but no halogen atom · CPC title
Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143 · CPC title
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