Antibacterial liquid, antibacterial film, and wet wipe

Patent metadata

Field	Value
Publication number	US-10433541-B2
Application number	US-201715801909-A
Country	US
Kind code	B2
Filing date	Nov 2, 2017
Priority date	May 15, 2015
Publication date	Oct 8, 2019
Grant date	Oct 8, 2019

Abstract

Provided are an antibacterial liquid having excellent sedimentation resistance, an antibacterial film formed using the antibacterial liquid, and a wet wipe produced using the antibacterial liquid. The antibacterial liquid is an antibacterial liquid including antibacterial microparticles, a binder, and a solvent, in which the antibacterial microparticles contain a silver-supporting inorganic oxide, the average particle size of the antibacterial microparticles is 1.0 μm or less, the binder includes at least one silane compound, the solvent includes an alcohol and water, and the content of the alcohol with respect to the total mass of the antibacterial liquid is 10% by mass or more.

First claim

What is claimed is:

1. An antibacterial liquid comprising: an antibacterial microparticle; a binder; and a solvent,
wherein the antibacterial microparticle contains a silver-supporting inorganic oxide,
the average particle size of the antibacterial microparticles is 0.5 μm to 1.0 μm,
the binder includes at least one silane compound,
the solvent includes an alcohol and water,
the content of the alcohol is 10% by mass or more with respect to the total mass of the antibacterial liquid,
the alcohol is selected from the group consisting of methanol, ethanol, n-propanol, isopropanol, n-butanol, 2-butanol, i-butanol, t-butanol, n-pentanol, t-amyl alcohol, and n-hexanol, and
the silane compound is a siloxane compound represented by General Formula (1′):

in General Formula (1′), R a , R b , R c , and R d each independently represent a hydrogen atom or an organic group, R a to R d may be respectively identical with or different from each other, and R a to R d may be bonded to each other and form a ring, and
m represents an integer from 1 to 100.

2. The antibacterial liquid according to claim 1 , wherein the average particle size of the antibacterial microparticles is 0.5 μm to 0.7 μm.

3. The antibacterial liquid according to claim 1 , wherein the silver-supporting inorganic oxide is silver-supporting glass.

4. The antibacterial liquid according to claim 1 , wherein the content of the alcohol is 50% by mass or more with respect to the total mass of the antibacterial liquid.

5. The antibacterial liquid according to claim 1 , wherein the content of the antibacterial microparticles is, as solid content, 1.0% by mass or less with respect to the total mass of the antibacterial liquid.

6. The antibacterial liquid according to claim 1 , wherein the content of the antibacterial microparticles is, as solid content, 0.2% by mass or less with respect to the total mass of the antibacterial liquid.

7. The antibacterial liquid according to claim 1 , wherein the content of the antibacterial microparticles is, as solid content, 20% by mass or less with respect to the total solid content mass of the antibacterial liquid.

8. The antibacterial liquid according to claim 1 , wherein the viscosity at 25° C. is 0.5 to 5 cP.

9. The antibacterial liquid according to claim 1 , wherein the turbidity is 100 ppm or less.

10. The antibacterial liquid according to claim 1 , further comprising an anionic dispersant.

11. The antibacterial liquid according to claim 10 , wherein the content of the anionic dispersant is 50% by mass or more with respect to the content of the antibacterial microparticles.

12. The antibacterial liquid according to claim 1 , wherein in a case in which the antibacterial liquid is stored for 500 hours in a low-temperature environment at a temperature of 5° C., the amount of change in the viscosity at 25° C. is 2 cP or less, and the amount of change in the turbidity is 10 ppm or less.

13. The antibacterial liquid according to claim 1 , wherein in a case in which the antibacterial liquid is stored for 500 hours in a high-temperature environment at a temperature of 40° C. and a relative humidity of 80%, the amount of change in the viscosity at 25° C. is 2 cP or less, and the amount of change in the turbidity is 20 ppm or less.

14. The antibacterial liquid according to claim 1 , wherein the antibacterial liquid is configured to be applied to a base material as a first bacterial film, and is configured to be applied to the first bacterial film as a second bacterial film, such that an absolute value of the difference between the water contact angle X of the first antibacterial film and the water contact angle Y of the second antibacterial film, |X−Y|, is 10° or less.

15. The antibacterial liquid according to claim 1 , wherein the antibacterial liquid has a pH of 6 or lower.

16. An antibacterial film formed using the antibacterial liquid according to claim 1 .

17. The antibacterial film according to claim 16 , wherein the antibacterial film has a water contact angle of 60° or less.

18. The antibacterial film according to claim 16 , wherein the ratio B/A of the average particle size B of the antibacterial microparticles with respect to the film thickness A is 1 or greater.

19. The antibacterial film according to claim 16 , wherein the antibacterial film has a film thickness of 1.0 μm or less.

20. A wet wipe comprising a base fabric impregnated with the antibacterial liquid according to claim 1 .

21. The antibacterial liquid according to claim 1 , wherein the antibacterial liquid further comprises silica particles.

22. The antibacterial liquid according to claim 1 , wherein the content of the binder with respect to the total mass of the antibacterial liquid is 10% by mass or less.

23. The antibacterial liquid according to claim 1 , wherein the content of the binder with respect to the total mass of the antibacterial liquid is 3% by mass or less.

Assignees

• Fujifilm Corp

Inventors

• Hamano Mitsumasa
• Matsunaga Naohiro
• Hatanaka Yusuke

Classifications

• A01N59/16

  Heavy metals; Compounds thereof · CPC title

• A01N25/04 Primary

  Dispersions, {emulsions, suspoemulsions, suspension concentrates} or gels (foams A01N25/16) · CPC title

• A01N25/34

  Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group · CPC title

• A47L13/17

  containing cleaning agents (A47L13/19 takes precedence {; chemical compositions C11D17/049}) · CPC title

• A01N31/02 Primary

  Acyclic compounds · CPC title