Separator including a polysulfide barrier layer for a battery cell, and battery cell

Patent metadata

Field	Value
Publication number	US-10431797-B2
Application number	US-201515512403-A
Country	US
Kind code	B2
Filing date	Sep 1, 2015
Priority date	Sep 18, 2014
Publication date	Oct 1, 2019
Grant date	Oct 1, 2019

Abstract

A vehicle traction battery includes a battery cell, the battery cell including a cathode, and anode, and a separator the anode and cathode. The separator includes at least one protective layer that is impermeable to polysulfides and at least one ion-conducting conductive layer whose composition is different than that of the protective layer and that is designed as a copolymer which includes a stabilizing phase and an ionically conductive phase, the protective layer including an inorganic substance.

First claim

What is claimed is:

1. A separator for separating an anode and a cathode in a battery cell, comprising:
a copolymer ion-conducting conductive layer that includes a stabilizing phase and an ionically conductive phase, wherein the stabilizing phase effectuates a mechanical strength of the separator, and wherein the ionically conductive phase of the separator is used to conduct ions through the separator; and
a protective layer whose composition is different than a composition of the conductive layer, that is impermeable to polysulfides, and includes an inorganic substance;
wherein the conductive layer transitions into the protective layer,
wherein the protective layer includes a copolymer and has a mechanically stabilizing phase and an ionically conductive phase, wherein chemically reactive particles are embedded in the ionically conductive phase and the chemically reactive particles are distributed at a distance from each other in the ionically conductive phase, so that clearances remain between the chemically reactive particles to provide ion conduction through the ionically conductive phase of the protective layer and through the separator.

2. The separator of claim 1 , wherein the inorganic substance of the protective layer includes the chemically reactive particles that react with polysulfides.

3. The separator of claim 2 , wherein the chemically reactive particles consist of an alkali metal or an alkali metal compound.

4. The separator of claim 2 , wherein the chemically reactive particles contain an alkaline earth metal or an alkaline earth metal compound.

5. The separator of claim 2 , wherein the chemically reactive particles consist of an alkaline earth metal or an alkaline earth metal compound.

6. The separator of claim 2 , wherein the chemically reactive particles are situated at a distance from each other, with clearances remaining between the chemically reactive particles.

7. The separator of claim 1 , wherein the inorganic substance of the protective layer includes composite particles that are arranged close together; and wherein a plurality of the composite particles are in contact with each other.

8. The separator of claim 7 , wherein the composite particles contain an ion-conducting ceramic.

9. The separator of claim 7 , wherein the composite particles consist of an ion-conducting ceramic.

10. The separator of claim 7 , wherein the composite particles contain an argyrodite.

11. The separator of claim 7 , wherein the composite particles consist of an argyrodite.

12. The separator of claim 1 , wherein the ionically conductive phase contains acrylates.

13. The separator of claim 1 , wherein composite particles contain an inorganic substance, including at least one of an oxide, a ceramic, a garnet, a garnet-like material of Li 7 La 3 Zr 2 O 12 (LLZO), a glass-ceramic membrane (LISICON), a non-oxidic ion conductor, an argyrodite, or a lithium argyrodite.

14. A separator for separating an anode and a cathode in a battery cell, comprising:
a copolymer ion-conducting conductive layer that includes a stabilizing phase and an ionically conductive phase; and
a protective layer whose composition is different than a composition of the conductive layer, that is impermeable to polysulfides, and includes an inorganic substance;
wherein the inorganic substance of the protective layer includes chemically reactive particles that react with polysulfides, and
wherein the chemically reactive particles contain an alkali metal or an alkali metal compound.

15. A battery cell, comprising:
an anode;
a cathode;
a separator that separates the anode and the cathode from each other and that includes: a copolymer ion-conducting conductive layer that includes a stabilizing phase and an ionically conductive phase, wherein the stabilizing phase effectuates a mechanical strength of the separator, and wherein the ionically conductive phase of the separator is used to conduct ions through the separator; and
a protective layer whose composition is different than a composition of the conductive layer, that is impermeable to polysulfides, and includes an inorganic substance;
wherein the conductive layer transitions into the protective layer,
wherein the protective layer includes a copolymer and has a mechanically stabilizing phase and an ionically conductive phase, wherein chemically reactive particles are embedded in the ionically conductive phase and the chemically reactive particles are distributed at a distance from each other in the ionically conductive phase, so that clearances remain between the chemically reactive particles to provide ion conduction through the ionically conductive phase of the protective layer and through the separator.

16. The battery cell of claim 15 , wherein composite particles contain an inorganic substance, including at least one of an oxide, a ceramic, a garnet, a garnet-like material of Li 7 La 3 Zr 2 O 12 (LLZO), a glass-ceramic membrane (LISICON), a non-oxidic ion conductor, an argyrodite, or a lithium argyrodite.

Assignees

• Bosch Gmbh Robert

Inventors

• Schumann Bernd
• Fanous Jean

Classifications

• H01M4/38 Primary

  of elements or alloys · CPC title

• H01M2220/20

  Batteries in motive systems, e.g. vehicle, ship, plane · CPC title

• H01M10/4235

  Safety or regulating additives or arrangements in electrodes, separators or electrolyte (H01M10/4242 takes precedence) · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M50/497

  Ionic conductivity · CPC title