Spectrometric measuring device

Patent metadata

Field	Value
Publication number	US-10429307-B2
Application number	US-201715655992-A
Country	US
Kind code	B2
Filing date	Jul 21, 2017
Priority date	Jul 27, 2016
Publication date	Oct 1, 2019
Grant date	Oct 1, 2019

Abstract

The present disclosure relates to a spectrometric measuring device for a process measuring point including a housing, a radiation source arranged in the housing, a coupling and decoupling optical system to direct radiation from the radiation source into a measuring region and to couple measuring radiation from the measuring region into the housing, a spectrograph arranged in the housing and aligned such that the measuring radiation is detected by the spectrograph with a detector, an electronic device arranged in the housing and connected to the detector and configured to detect a spectrum from the spectrograph and to process it to determine a concentration of an analyte in the measuring medium or a value derived therefrom, and a connection connected to the housing for connecting the housing to a process container, wherein the measuring region is located within a volume of the process container, said volume containing the measuring medium.

First claim

The invention claimed is:

1. A spectrometric measuring device for a process measuring point, comprising:
a housing;
a radiation source disposed in the housing;
a coupling and decoupling optical system structured to decouple radiation of the radiation source from the housing and direct the radiation into a measuring medium in a measuring region external to the housing, and to couple measuring radiation from the measuring region into the housing;
a spectrograph disposed in the housing and aligned in relation to the coupling and decoupling optical system such that the measuring radiation coupled into the housing from the measuring region is detected by the spectrograph, wherein the spectrograph is configured to disperse the measuring radiation into a spectrum and to register the spectrum using a detector;
an electronic device disposed in the housing and connected to the detector, the electronic device configured to detect and process the registered spectrum to determine, based upon the spectrum, a measurand correlated to the concentration of at least one analyte in the measuring medium; and
a process connection connected to the housing, the connection structured to enable connecting the housing to a process container containing the measuring medium, wherein the measuring region is located within a volume area of the process container, said volume area containing the measuring medium,
wherein the coupling and decoupling optical system includes a first wave guide that transmits radiation from the radiation source to the measuring medium and/or a second wave guide that transmits the measuring radiation from the measuring medium to the spectrograph, and
wherein the connection includes a process connection structured to affix to a complementary connection of the process container, wherein the process container is a pipe carrying the measuring medium or a reaction container containing the measuring medium.

2. The spectrometric measuring device of claim 1 , the spectrometric measuring device further comprising a power supply unit disposed in the housing and configured to supply power to the radiation source and the electronic device.

3. The spectrometric measuring device of claim 1 , wherein the connection includes a flow-through cell or a spool piece having flanges on two opposite ends and structured to affix to the process container.

4. The spectrometric measuring device of claim 1 , wherein the electronic device includes a microprocessor and a non-volatile memory, in which a computer program is stored that provides functionalities of the spectrometric measuring device and can be executed by the microprocessor,
wherein the computer program serves to control the spectrometric measuring device, including the radiation source, controllable parts of the coupling and decoupling optical system, the detector and/or the power supply unit, and to register and process the spectrum.

5. The spectrometric measuring device of claim 4 , wherein the spectrograph and the electronic device are configured to register and process a Raman spectrum formed by Stokes scattering and/or anti-Stokes scattering.

6. The spectrometric measuring device of claim 1 , wherein the radiation source includes a substantially monochromatic radiation source, and wherein the measuring radiation coupled into the housing from the measuring region is generated by Raman scattering of the radiation of the radiation source directed into the measuring region.

7. The spectrometric measuring device of claim 6 , wherein the spectrograph includes an optical filter structured to remove a portion of the measuring radiation generated by Rayleigh scattering.

8. The spectrometric measuring device of claim 1 , wherein the coupling and decoupling optical system includes a window arranged in a wall of the housing and transparent to the radiation of the radiation source and to the measuring radiation.

9. The spectrometric measuring device of claim 8 , the spectrometric measuring device further comprising an ultrasound source arranged outside of the housing at or near the window, the ultrasound source configured to clean the window.

10. The spectrometric measuring device of claim 1 , wherein the housing is explosion-proof according to requirements for pressure-tight encapsulation as defined by a protection class Ex-d industry standard.

11. The spectrometric measuring device of claim 1 , wherein the electronic device has an interface for wireless or wired communication with a control unit arranged outside the housing.

12. The spectrometric measuring device of claim 1 , wherein the electronic device has a communication interface configured to send signals wirelessly to an operator unit and to receive signals wirelessly from the operator unit.

13. The spectrometric measuring device of claim 1 , wherein the electronic device and/or the control unit and/or the operator unit have a processor and a non-volatile memory, in which a computer program is stored that can be executed by the processor, the computer program configured to determine from the registered spectrum a concentration of the analyte in the measuring medium or a value derived therefrom.

14. The spectrometric measuring device of claim 13 , wherein the analyte is glucose.

15. The spectrometric measuring device of claim 1 , wherein the radiation source emits radiation of a wavelength in the infrared range.

16. The spectrometric measuring device of claim 1 , the spectrometric measuring device further comprising a mirror device that deflects incoming measuring radiation toward the detector.

17. The spectrometric measuring device of claim 16 , wherein the mirror device includes a first mirror and a second mirror structured to be tilted independently of each other at least between a first position and a second position, wherein when in the first position the first mirror and the second mirror deflect the measuring radiation toward the detector.

18. The spectrometric measuring device of claim 17 , the spectrometric measuring device further comprising a dispersion element structured to split the measuring radiation into measuring radiation of at least a first wavelength and a second wavelength, wherein the first mirror deflects the measuring radiation of the first wavelength toward the detector, and the second mirror deflects the measuring radiation of the second wavelength toward the detector.

19. The spectrometric measuring device of claim 1 , wherein the detector is a single-point detector.

20. A process measuring point comprising:
at least one spectrometric measuring device comprising:
a housing;
a radiation source disposed in the housing;
a coupling and decoupling optical system structured to decouple radiation of the radiation source from the housing and direct the radiation into a measuring medium in a measuring region external to the housing, and to couple measuring radiation from the measuring region into the housing;
a spectrograph disposed in the housing and aligned in relation to the coupling and decoupling optical system such that the measuring radiation coupled into the housing from the measuring region is detected by the spectrograph, wherein the spectrograph is configured to disperse the measuring radiation into a spectrum and to register the spectrum using a detector, and wherein the coupling and decoupling optical system includes a first wave guide that transmits radiation from the radiation source to the measuring medium and/or a second wave guide that transmits the measuring radiation from the measuring medium to the

Assignees

• Endress Hauser Conducta Gmbh Co Kg

Inventors

• Jagiella Manfred
• Weiss Michael

Classifications

• G01N2201/022

  Casings · CPC title

• G01J3/4406

  Fluorescence spectrometry · CPC title

• G01J3/0264

  Electrical interface; User interface · CPC title

• G01J3/0229

  using masks, aperture plates, spatial light modulators or spatial filters, e.g. reflective filters · CPC title

• G01J3/12

  Generating the spectrum; Monochromators · CPC title